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Highly active MgO-supported TiCl4 catalyst for the ethylene polymerization

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Summary

The MgO-supported TiCl4 catalysts prepared by heating MgO with TiCl4 showed a high activity for the ethylene polymerization in combination with Et3Al or i-Bu3Al. In these highly active catalysts, it has been shown that MgCl2 is formed in the MgO-TiCl4 reaction and is considered to contribute to the enhancement of the activity of the catalysts.

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References

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Authors and Affiliations

  1. Research Center, Mitsui Petrochemical Industries, Ltd., Waki-cho, Kuga-gun, 740, Yamaguchi-ken, Japan

    Norio Kashiwa & Toshiyuki Tsutsui

Authors
  1. Norio Kashiwa
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  2. Toshiyuki Tsutsui
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Kashiwa, N., Tsutsui, T. Highly active MgO-supported TiCl4 catalyst for the ethylene polymerization. Polymer Bulletin 11, 313–317 (1984). https://doi.org/10.1007/BF00254266

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  • DOI: https://doi.org/10.1007/BF00254266

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