Abstract
Earlier research, on the photoreactivity of some organics with aqueous NO − x extended to systems comprising codissolved chlorides. It is found that concentrations of NO3 − bear a determining role on the transfer of Cl from the aqueous into the organic phase and that rates of this transfer also depend on Cl− concentration as well as on the intensity of UV light. A simple overall mechanism is postulated for the process studied in the laboratory and the experimentation is thereafter extended to conditions of sunlight illumination where the reaction is found to occur along similar lines but with larger quantum yields.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Barger, W. R. and Garrett, W. D.: 1976, J. Geophys. Res. 81, 3151.
Berg, W. N. and Winchester, J. W.: 1977, J. Geophys. Res. 82, 5945.
Cicerone, R. J., Stolarski, R. S. and Walters, S.: 1974, Science 185, 1165.
Cox, R. A., Dervent, R. G., Eggleton, A. E. J., and Lovelock, J. E.: 1976, Atmos. Envir. 10, 305.
Cronn, D. R., Rasmussen, R. A., Robinson, E., and Harsch, D. E.: 1977, J. Geophys. Res. 82, 5935.
Duce, R. A. and Hoffman, E. J.: 1976, Ann. Rev. Earth and Planet. Sci. 4, 187.
Grimsrud, E. P. and Rasmussen, R. A.: 1975, Atmos. Envir. 9, 1014.
Hidy, G. M., Mueller, P. K., Wang, H. H., Karney, J., Twiss, S., Imada, M., and Alcocer, A.: 1974, J. Appl. Meteorol. 13, 96.
John, W., Kaifer, R., Rahn, K., and Wesolowski, J. J.: 1973, Atmos. Envir. 7, 107.
Ketseridis, G., Hahn, J., Jaenicke, R., and Junge, C.: 1976, Atmos. Envir. 10, 603.
King, W. D. and Maher, C. T.: 1976, Tellus 28, 1976.
Lazrus, A. L., Gandrud, B. W., Woodard, R. N., and Sedlacek, W. A.: 1976, J. Geophys. Res. 81, 1067.
Lunde, G., Gether, J., Gjos, N., and Stobet Laude, M. B.: 1977, Atmos. Envir. 11, 1007.
Macalady, D. L., Carpenter, J. H., and Moore, C. A.: 1977, Science 195, 1335.
McClure, V. E.:1976, Envir. Sci. Technol. 10, 1223.
Molina, M. J. and Rowland, R. S.: 1974, Nature 249, 810.
Neuwirth, O. S.: 1960, in Photochemistry in the Liquid and Solid State, p. 16. Wiley, New York.
Ohta, T., Morita, M., and Mizoguchi, I.: 1976, Atmos. Envir. 10, 557.
Papee, H. M. and Montefinale, A. C.: 1960, Nature 187, 1103.
Petriconi, G. L. and Papee, H. M.: 1972, Water, Air, Soil Pollut. 1, 117.
Petriconi, G. L. and Papee, H. M.: 1977a, Water, Air, Soil Pollut. 8, 217.
Petriconi, G. L. and Papee, H. M.: 1977b, Water, Air, Soil Pollut. 8, 225.
Petriconi, G. L., Rafanelli, C. E., and Papee, H. M.: 1977, Riv. Ital. Geofis. e Sci. Aff. 4, 252.
Rafanelli, C. E., Petriconi, G. L., and Papee, H. M.: 1978, Water, Air, Soil Pollut. in this issue.
Robbins, D. E.: 1976, Geophys. Res. Lett. 3, 213.
Robbins, J. A. and Snitz, F. L.: 1972, Envir. Sci. Technol. 6, 165.
Takacs, G. A. and Glass, G. P.: 1973, J. Phys. Chem. 77, 1948.
Wubbels, G. G., Jordan, J. F., and Mills, N. S.: 1973, J. Amer. Chem. Soc. 95, 1281.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Rafanelli, C.E., Petriconi, G.L. & Papee, H.M. Photochlorination of organics by aqueous Cl− codissolved with anionic NO Emphasis>/− x . Water Air Soil Pollut 10, 403–412 (1978). https://doi.org/10.1007/BF00250006
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00250006