Abstract
The electrodeposition of Fe(II) in ZnCl2-2NaCl melt at 450°C was studied at molybdenum and tungsten electrodes and the results are compared with those obtained at glassy carbon in previous work. The kinetics of the electrodeposition and electrocrystallization of iron were studied, showing that the process is quasireversible, and the values of the kinetic parameters κ° and α were obtained. Mass transport towards the electrode is a simple diffusion process and the diffusion coefficient was obtained by applying different electrochemical techniques. Potential step measurements indicate that instantaneous nucleation and growth phenomena play a part in the overall process.
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References
D. Inman and S. H. White, International Symposium ‘Molten Salt Electrolysis in Metal Production’, Grenoble, IMM (1977) p. 51.
D. Inman, R. S. Sethi and R. Spencer, J. Electroanal. Chem. 29 (1971) 137.
A. D. Graves and D. Inman, in ‘Electromotive Force Measurements in High Temperature Systems’ (edited by C. B. Alcock), IMM, London (1968) p. 187.
S. Senderoff, Metall. Rev. 11 (1966) 97.
S. M. Selis, J. Phys. Chem. 72 (1968) 1442.
G. J. Hills, D. J. Schiffrin and J. Thompson, Electrochim. Acta 19 (1974) 657.
C. Decroly, C. Mukhtar and R. Winand, J. Electrochem. Soc. 115 (1968) 905.
A. D. Graves and D. Inman, J. Electroanal Chem. 25 (1970) 357.
Y. Castrillejo, A. M. Martinez, M. Vega, E. Barrado and G. Picard, ibid. 397 (1995) 139.
A. K. Vijh, Corros. Sci. (1971) 161.
J. C. Gabriel, J. Bouteillon, J. C. Poignet and J. M. Roman, J. Electrochem. Soc. 141 (9) (1994) 2286.
I. Barin and O. Knacke, ‘Thermochemical Properties of Inorganic Substances’, Springer-Verlag, Berlin (1973) p. 876.
A. J. Bard and L. R. Faulkner, ‘Electrochemical Methods: Fundamentals and Applications’, Wiley, New York (1980).
D. D. McDonald, ‘Transient Techniques in Electrochemistry’, Plenum Press, New York (1977).
J. C. Imbeaux and J. M. Saveant, J. Electroanal. Chem. 44 (1973) 169.
J. M. Saveant and D. Tessier, ibid. 61 (1975) 251.
Idem, ibid., 65 (1975) 57.
K. B. Oldhman, Anal. Chem. 44 (1972) 196.
D. Shuzhen, P. Dudley and D. Inman, J. Electroanal. Chem. 142 (1982) 215.
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Castrillejo, Y., Martinez, A.M., Vega, M. et al. Electrochemical reduction of Fe(ii) ions on different solid electrodes in fused ZnCl2-2NaCl mixture. J Appl Electrochem 26, 1279–1285 (1996). https://doi.org/10.1007/BF00249931
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DOI: https://doi.org/10.1007/BF00249931