Advertisement

Journal of Applied Electrochemistry

, Volume 24, Issue 2, pp 126–130 | Cite as

Recycling of carbon dioxide using a proton conductor as a solid electrolyte

  • T. Hibino
  • S. Hamakawa
  • T. Suzuki
  • H. Iwahara
Papers

Abstract

Using a proton conductor based on SrZrO3 or CaZrO3 as a solid electrolyte, three attempts have been made to react CH4 with CO2 efficiently. When the mixture of CH4 and CO2 was used as a fuel gas for a SOFC, the cell provided stable electric power. Furthermore, the electrochemical hydrogen pump accelerated both the reforming of CH4 with CO2 and the oxidative coupling of CH4 with CO2.

Keywords

Hydrogen Physical Chemistry Dioxide Carbon Dioxide Electric Power 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    T. Sodesawa, A. Dobashi, and F. Nozaki, React. Kinet. Catal. Lett. 12 (1979) 107.Google Scholar
  2. [2]
    Y. Sakai, H. Sato, T. Sodesawa, and F. Nozaki, ibid 24 (1984) 253.Google Scholar
  3. [3]
    M. Masai, H. Kado, A. Miyake, S. Nishiyama, and S. Tsuruya, Stud. Surf. Sci. Catal. 36 (1988) 67.Google Scholar
  4. [4]
    H. Iwahara, H. Uchida, and N. Maeda, J. Power Sources 7 (1982) 293.Google Scholar
  5. [5]
    K. Kanamura, S. Yoshioka, and Z. Takehara, J. Electrochem. Soc. 138 (1991) 2165.Google Scholar
  6. [6]
    T. Hibino, S. Hamakawa, and H. Iwahara, Chem. Lett. (1992) 1715;Google Scholar
  7. [6a]
    S. Hamakawa, T. Hibino, and H. Iwahara, J. Electrochem. Soc. 140 (1993) 459.Google Scholar
  8. [7]
    K. Aika and T. Nishiyama, J. Chem. Soc., Chem. Commun. (1988) 70.Google Scholar
  9. [8]
    K. Asami, T. Shikada, and K. Fujimoto, Bull. Chem. Soc. Jpn. 64 (1991) 266.Google Scholar
  10. [9]
    P. Chiang, D. Eng. and M. Stoukides, J. Electrochem. Soc. 138 (1991) L11.Google Scholar
  11. [10]
    L. S. Woldman and V. D. Sokolovskii, Catal. Lett. 8 (1991) 61.Google Scholar
  12. [11]
    T. Yajima, H. Suzuki, T. Yogo and H. Iwahara, Solid State Ionics 51 (1992) 101.Google Scholar
  13. [12]
    T. Yajima, H. Kazeoka, T. Yogo, and H. Iwahara, ibid. 47 (1991) 271.Google Scholar

Copyright information

© Chapman & Hall 1994

Authors and Affiliations

  • T. Hibino
    • 1
  • S. Hamakawa
    • 1
  • T. Suzuki
    • 1
  • H. Iwahara
    • 1
  1. 1.Synthetic Crystal Research Laboratory, School of EngineeringNagoya UniversityNagoyaJapan

Personalised recommendations