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Adsorption of mercury compounds by tropical soils III. Adsorption isotherms

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Abstract

Isotherms for sorption of 2-methoxyethylmercury chloride (Aretan) and HgCl2 showed that all three soils investigated had a large capacity to adsorb these Hg compounds, the order being Morogoro > Arusha > Dar es Salaam. For all soils, surface horizons adsorbed more Hg at any given concentration of Hg in solution as compared to subsurface horizons. Adsorption isotherms of Aretan, especially at lower equilibrium concentration in soil solution, were much steeper in all horizons and in all profiles. The Freundlich equation described the adsorption of HgCl2 better than that of Aretan. The adsorption isotherms for Aretan and HgCl2 showed different forms, implying probably that different adsorption mechanisms were involved.

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References

  • Barrow, N. J.: 1978, J. Soil Sci. 29, 447.

    Google Scholar 

  • Fang, S. C.: 1978, Environ. Sci. Technol. 12, 285.

    Google Scholar 

  • Farrah, H. and Pickering, W. F.: 1978, Water, Air, and Soil Pollut. 9, 23.

    Google Scholar 

  • Feick, G., Johanson, E. E., and Yeaple, D. S.: 1972, ‘Control of Mercury Contamination in Fresh Water Sediments’, Environ. Prot. Technol Ser., EPA-R2–72–077, Office of Research and Monitoring, U.S. Environmental Protection Agency, Washington, D.C.

    Google Scholar 

  • Ginzburg, I.I.: 1960, Principles of Geochemical Prospecting: Techniques of Prospecting for Non-Ferrous Ores and Rare Minerals, Pergamon Press, London, p. 155.

    Google Scholar 

  • Goodnight, J. H.: 1979, ‘NLIN (Non-Linear Regression) Procedure’, in SAS Users Guide, 1979 edition, SAS Institute Inc., Cary, North Carolina, pp. 317–329.

    Google Scholar 

  • Hogg, T. J., Stewart, J. W. B., and Bettany, J. R.: 1978, J. Environ. Qual. 7, 440.

    Google Scholar 

  • Inoue, K. and Aomine, S.: 1969; Soil Sci. Plant Nutr. (Tokyo) 15, 86.

    Google Scholar 

  • Khalid, R. A., Gabrell, R. P., and Patrick Jr., W. H.: 1977, ‘Sorption and Release of Mercury by Mississippi River Sediment as Affected by pH and Redox Potential’, in H. Drucker and R. E. Wildung (eds.), Biological Implications of Metals in the Environment, Proceedings of the 15th Annual Hanford Life Science Symposium, Richland, Washington, September 29–October 1, 1975, pp. 297–314.

  • Klusman, R. W. and Matoske, C. P.: 1983, Environ. Sci. Technol. 17, 251.

    Google Scholar 

  • Landa, E. R.: 1978, Geochim. Cosmochim. Acta 42, 1407.

    Google Scholar 

  • Lockwood, R. A. and Chen, K. Y.: 1973, Environ. Sci. Technol. 7, 1028.

    Google Scholar 

  • Mead, R. and Pike, D. J.: 1975, Biometrics 31, 803.

    Google Scholar 

  • Semu, E., Singh, B. R., and Selmer-Olsen, A. R.: 1986, Water, Air, and Soil Pollut. 27, 19.

    Google Scholar 

  • Semu, E., Singh, B. R., and Selmer-Olsen, A. R.: 1987, Water, Air, and Soil Pollut. 32, 1 (this volume).

    Google Scholar 

  • Singh, B. R.: 1984, Soil Sci. 138, 189.

    Google Scholar 

  • Trost, P. B. and Bisque, R. E.: 1972, ‘Distribution of Mercury in Residual Soils’, in R. Hartung and B. D. Dinman (eds.), Environmental Mercury Contamination, Ann Arbor Science Publishers, Ann Arbor, Mich. pp. 178–196.

    Google Scholar 

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Semu, E., Singh, B.R. & Selmer-Olsen, A.R. Adsorption of mercury compounds by tropical soils III. Adsorption isotherms. Water Air Soil Pollut 32, 11–16 (1987). https://doi.org/10.1007/BF00227679

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  • DOI: https://doi.org/10.1007/BF00227679

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