Abstract
Freshwater surface sediments from 11 sites on the river Derwent (Derbyshire, UK) were sampled monthly during the period of June 1987 to May 1988. Samples were extracted and separated and the Polycyclic Aromatic Hydrocarbon (PAH) extract was analyzed using High Performance Liquid chromatography with a fluorescence detector. Identity of the peaks was confirmed by co-injection and Gas Chromatograph — Mass Spectrometry (GC-MS). Changes in total levels of nine parent PAH compounds were compared with rainfall data obtained for the study area. The time lag between PAH incorporation into sediments and preceding storm events varied between a minimum of 4 and a maximum of 30 days. All sites were found to be affected by diffuse PAH pollution. At certain sites and at times of heavy rainfall this contamination is overlayed by a greater input of PAH to the sediment from point sources. Road runoff was identified as a major diffuse source underlying atmospheric and point sources at particular sites. Small industrial areas had a greater influence on sediment PAH levels than the larger commercial or residential areas. Pyrene and fluoranthene were the dominant parent compounds and this is explained in terms of their availability and relative solubility.
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Abdul, A. S., and Gibson, T. L.: 1986, Hazardous Waste and Hazardous Materials 3, 125.
Boehm, P. D., and Farrington, J. W.: 1984, Environ. Sci. Technol. 18, 840.
Borneff, J., and Kunte, H.: 1983, in: Bjorseth A. (Ed.): Handbook of PAH's Vol. 1. Marcel Dekker, Inc. New York.
Catalo, W. J., and Gambrell, R. P.: 1987, Chemosphere 16, 1053.
Dunn, B. P.: in Bjorseth, A., and Dennis, A. J. (Eds.), 1980, PAH's — Chemistry & Biological Effects, 4th International Symposium. Battelle Press, Columbus, Ohio.
Eadie, B. J., Faust, W., Gardner, W. S., and Nalepa, T.: 1982, Chemosphere 11, 185.
Eganhouse, R. P., Simoneit, B. R. T., and Kaplan, I. R.: 1981, Environ. Sci. Technol. 15, 315.
Enzminger, J. D., and Ahlert, R. C.: 1987, Environ. Technol. Lett. 8, 269.
Garrigues, P., Soclo, H. H., Marniesse, M. P., and Ewald, M.: 1987, Int. J. Environ. Anal. Chem. 28, 121.
Gavens, A., Revitt, D. M., and Ellis, J. B.: 1982, Hydrobiologia 91, 285.
Giger, W., and Schaffner, C.: 1978, Anal. Chem. 50, 245.
Grimmer, G., and Bohnke, H. (1975), Cancer Lett. 1, 75.
Grimmer, G., Naujack, K. W., and Schneider, D., 1980, in Bjorseth, A., and Dennis, A. J. (eds.). Polynuclear Aromatic Hydrocarbons, Chemistry & Biological Effects, Battelle Press, Columbus, Ohio.
Hall, K. J., Gujral, V. K., Parkinson, P. and Ma, T.: 1987, Can. Tech. Rep. Fish. Aquat. Sci., 1480, 201.
Harrison, R. M., Perry, R., and Wellings, R. A.: 1975, Water Res., 9, 331.
Herrmann, R.: 1981, Water, Air, and Soil Pollut. 16, 445.
Hoffman, E. J., Mills, G. L., Latimer, J. S., and Quinn, J. G.: 1984, Environ. Sci. Technol. 18, 580.
Hoffman, E. J., Latimer, J. S., Hunt, C. D., Mills, G. L., and Quinn, J. G.: 1985, Water, Air, and Soil Pollut. 25, 349.
Karickhoff, S. W., Brown, D. S., and Scott, T. A.: 1979, Water Res. 13, 241.
Kawamura, K., and Kaplan, I. R.: 1986, Atmos. Environ. 20, 115.
Macko, S. A., Winters, J. K., and Parker, P. L.: 1987, Mar. Environ. Res. 21, 3.
Mills, G. L., and Norton, D. M.: 1987, Abstr. Pap. Am. Chem. Soc. 193 (Envy. 47).
O'Conner, D. J., and Connolly, J. P.: 1980, Water Res. 14, 1517.
Pavoni, B., Sfriso, A., and Marcomini, A.: 1987, Mar. Chem. 21, 25.
Payne, J. F., and Martins, I.: 1978, Science 200, 329.
Plowchalk, D. R., and Zagorski, S. J.: 1986, Proceedings of the Pennsylvania Academy of Science, 60, 174.
Readman, J. W., Mantoura, R. F. C., and Rhead, M. M.: 1984a, in Parker, W. R. and Kinsman, D. J. J. (eds.), Transfer Processes in Cohesive Sediment Systems, Plenum Press. N. York and London.
Readman, J. W., Mantoura, R. F. C., and Rhead, M. M.: 1984b, Fresenius Z. Anal. Chem. 319, 126.
Reichart, J., Kunte, H., Engelhardt, K., and Borneff, J.: 1971, Arch. Hyg. Bakt. 155, 18.
Rogers, I. H., Birtwell, I. K., and Kruzynski, G. M.: 1986, Wat. Pollut. Res. J. Canada 21, 187.
Simmleit, N. and Herrmann, R.: 1987a, Water, Air, and Soil Pollut. 34, 79.
Simmleit, N. and Herrmann, R.: 1987b, Water, Air, and Soil Pollut. 34, 97.
Strand, J. W. and Andren, A. W.: 1980, in Bjorseth, A., and Dennis, A. J. (eds.), PAH's: Chemistry and Biological Effects, Fourth International Symposium. Battelle Press. Columbus, Ohio.
Stotz, G.: 1987, Sci. Total. Environ. 59, 329.
Thompson, S. and Eglington, G.: 1987, Mar. Pollut. Bull. 9, 133.
Voice, T. C., Rice, C. P., and Weber, W. J. Jr.: 1983, Environ. Sci. Technol. 17, 513.
Wakeham, S. G., Schaffner, C., and Giger, W.: 1980a, Geochim. Cosmochim. Acta. 44, 403.
Wakeham, S. G., Schaffner, C., and Giger, W.: 1980b, Geochim. Cosmochim. Acta. 44, 415.
Whipple, W. Jr.: 1980, Journal of the Technical Councils ASCA. Proc. Paper 15632, 106. (TC1), 101.
Whipple, W. Jr., Hunter, J. V., and Shaw, L.: 1976, in Sources, Effects and Sinks of Hydrocarbons in the Aquatic Environment, Proc. Symp.
Youngblood, W. W. and Blumer, M.: 1975, Geochim. Cosmochim. Acta. 39, 1303.
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Evans, K.M., Gill, R.A. & Robotham, P.W.J. The source, composition and flux of polycyclic aromatic hydrocarbons in sediments of the river Derwent, Derbyshire, U.K.. Water Air Soil Pollut 51, 1–12 (1990). https://doi.org/10.1007/BF00211499
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DOI: https://doi.org/10.1007/BF00211499