Skip to main content
Log in

A polarized neutron study on synthetic Mn2SiO4

  • Published:
Physics and Chemistry of Minerals Aims and scope Submit manuscript

Abstract

The magnetization density of Mn2SiO4 was determined by diffraction with polarized neutrons at 20 K (antiferromagnetic spin state) in an applied magnetic field of 4.62 Tesla. A unique data set of 199 flipping-ratios was registered up to sin Θ/gl=9.0/nm, and the magnetic moments for the different sites were derived (μ(M1)=2.56(2) μ B, μ(M2)=4.33(2) μ B) after correction of field-induced ferromagnetic moments and antiphase domains. Fourier inversion of the magnetic structure factors produced the magnetization density in the unit cell with small contributions close to those oxygens involved in superexchange.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Ballet O, Fuess H, Wacker K, Untersteller E, Treutmann W, Hellner E, Hosoya S (1989) Magnetization measurements of olivine single crystals A2SiO4 with A=Mn, Fe or Co. J Phys 1:4955–4970

    Google Scholar 

  • Bonnet M, Delapalme A, Fuess H, Becker P (1979) Polarized neutron study of covalency effects in yttrium iron garnet. J Phys Chem Solid 40:863–876

    Google Scholar 

  • Fujino K, Sasaki S, Takéuchi Y, Sadanaga K (1981) X-ray determination of electron distributions in forsterite, fayalite and tephroite. Acta Crystallogr B37:513–518

    Google Scholar 

  • Lottermoser W, Müller R, Fuess H (1986) Antiferromagnetism in synthetic olivines. J Magn Mag Mat 54–57:1005–1006

    Google Scholar 

  • Lottermoser W, Fuess H (1988) Neutron diffraction measurements on single crystals of Mn2SiO4 and Co2SiO4. Phys Status Solidi (a) 109:589–595

    Google Scholar 

  • Müller R (1985) Magnetische Eigenschaften von Kobaltvanadat und Eisensilikat. Thesis, Frankfurt am Main

  • Santoro RP, Newnham RE, Nomura S (1966) Magnetic properties of Mn2SiO4 and Fe2SiO4. J Phys Chem Solid 27:655–666

    Google Scholar 

  • Treutmann W (1986) (private communication)

  • Watson R, Freeman AJ (1961) Hartree-Fock atomic scattering factors for the iron-transition series. Acta Crystallogr 14:27–37

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lottermoser, W., Fuess, H. A polarized neutron study on synthetic Mn2SiO4 . Phys Chem Minerals 19, 46–51 (1992). https://doi.org/10.1007/BF00206799

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00206799

Keywords

Navigation