Skip to main content
Log in

A contribution to the ore genesis of the magnesite deposit of Eugui, Navarra (Spain)

  • Published:
Mineralium Deposita Aims and scope Submit manuscript

Abstract

In the area of the magnesite deposits of Eugui (Navarra, Spain) studies on illite crystallinity, the degree of graphitization of carbonaceous material, measurements of vitrinite reflectivity, and fluid inclusions have been carried out on dolomites, magnesites, schists, and carbonaceous matter. These rocks have suffered metamorphism of very low to low grade.

The magnesite appears generally concordant with the Namurian dolomitic rocks showing a typically banded structure. The genetic model proposed involves an early Mg concentration during sedimentation (syndiagenetic dolomitization), lateral circulation of saline solutions, and formation of diagenetically crystallized rhythmites (DCR), and final compaction. The formation of magnesite took place under the conditions of low pressure and temperatures close to 150°C, very similar to all strata-bound ore deposits. Deformation and regional metamorphism only caused minor removal, recrystallization, and transformation of the clay minerals and carbonaceous matter.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Arce, R., Olmedo, F., Pesquera, A., Velasco, F.: Metamorfismo de grado bajo y muy bajo en la mitad occidental del macizo de Aldudes (Navarra). I Congr. Esp. Geol. T-II, 15–25 (1984)

  • Boast, A.M., Swainbank, I.G., Coleman, M.L., Halls, C.: Lead isotopic variation in the Tynagh, Silvermines and Navan base-metal deposits, Ireland, Trans. Inst. Min. Metall. (Sect. B: Appl. Earth Sci.) 90:115–119 (1918)

    Google Scholar 

  • Bodnar, R.J., Bethe, P.M.: Systematics of stretching of fluid inclusions. I: Fluorite and sphalerite at 1 atmosphere confining pressure. Econ. Geol. 79:141–161 (1984)

    Google Scholar 

  • Boet, H.V., Krause, H.F., Mohr, K., Müller, R., Pilger, A., Requart, H.: La région de magnesite d'Eugui dans les Pyrénées Occidentales. Pirineos (C:S:I:C:) 111:21–39 (1974)

    Google Scholar 

  • Bone, Y.: Interpretation of magnesites at Rum Jungle, N.T., using fluid inclusions. J. Geol. Soc. Australia 30:375–381 (1983)

    Google Scholar 

  • Burrus, R.C.: Hydrocarbon fluid inclusions in studies of sedimentary diagenesis. Mineral. Assoc. Canada. Short Course Handbook, 6:138–156 (1981)

    Google Scholar 

  • Clar, E.: Über parallel Schräg- und Kreuzbänderung in Spatlagerstätten. Tsch. Min. Petr. Mitt. 4:55–64 (1954)

    Google Scholar 

  • Destombes, J.P.: Origine métasomatique et age des magnesites (giobertites) des Pyrénées Occidentales. C.R. Acad. Sci. (Paris), Sér. D. 240:1117–1119 (1955)

    Google Scholar 

  • Destombes, J.P.: Magnésites (giobertites) des Pyrénées Occidentales. Bull. Soc. Géol. France, Sér. 6e 6:461–476 (1956)

    Google Scholar 

  • Dunoyer, G., Heddebaut, C.: Paleozoique anchimetamorphique à illite, chlorite, pyrophyllite, allevardite et paragonite dans les Pyrénées Basques. Bull. Serv. Carte Géol. Als. Lorr., 24–4. 277–290 (1971)

  • Fairbridge, R.W.: Syndiagenesis, anadiagenesis, epidiagenesis: phases in lithogenesis. In: Diagenesis in Sediments and Sedimentary Rocks, G., Larsen & G.V. Chilingar, Ed., pp. 17–114. Amsterdam: Elsevier (1983)

    Google Scholar 

  • Fontboté, L.: Strata-bound Zn-Pb-F-Ba deposits in carbonate rocks: new aspects of paleogeographic location, facies factors and diagenetic evolution. Inaugural Diss. Ruprecht-Karl-Universität, pp. 192 (1981)

  • Fontboté, L., Amstutz, G.C.: New observations on diagenetic crystallization rhythmites in the carbonate facies of the Triassic of the Alpujarrides (Betic Cordillera, Southern Spain). I Symp. Diagenesis. Barcelona. Rev. Inst. Inv. Geol. 34 (1980)

  • Gomez de Llarena, J.: La diagénesis en la dolomita y magnesita de Asturreta (Eugui, Navarra). Bol. R. Soc. Esp. Hist. Nat. 66–1:319–337 (1968)

    Google Scholar 

  • Gomez de Llarena, J.: Contribución al estudio de la génesis de los carbonatos sedimentarios (II III). Bol. R. Soc. Esp. Hist. Nat., 67–70, 111–112, 153–169 (1969, 1972)

  • Gonzalez López, J.M.: Mineralogía y mineralogénesis del yacimiento de magnesita de Asturreta (Navarra). Tesis doct. Uni. Zaragoza (Spain) Unpublished (1976)

  • Gonzalez López, J.M., Arrese, F.: Mineralogía y Mineralogénesis del yacimiento de magnesita de Asturreta (Navarra). Estudios geol. 33:35–44 (1977)

    Google Scholar 

  • Gonzalez López, J.M., Fernandez Nieto, C., Arrese, F., Medina, J.A.: Estudio cristaloquímico de los carbonatos del yacimiento de Eugui. Bol. Geol. Min., 89–2:164–170 (1978)

    Google Scholar 

  • Heddebaut, C.: Etudes géologiques dans les massifs paléozoiques basques. Thése Univ. Sci. Lille (France). pp. 263 (1973)

    Google Scholar 

  • Ingerson, E.: Liquid inclusions in geologic thermometry. Am. Mineral. 32/7–8:375–388 (1947)

    Google Scholar 

  • Itaya, T.: Carbonaceous material in pelitic schist of the Sambagawa metamorphic belt in central Shikoku, Japan, Lithos, 14:215–224 (1981)

    Google Scholar 

  • Johannes, W.: Zur Entstehung von Magnesitvorkommen. N. Jb. Min. Abh. 113:274–325 (1970)

    Google Scholar 

  • Kralik, M.: Verbreitung und Genese der Magnesitlagerstätte von Eugui (Asturreta) W Pyrenäen, Spanien. Unveröff. Diss. Univ. Wien. pp 179 (1977)

  • Kralik, M., Hoefs, J.: Die Isotopenzusammensetzung der Karbonate in der Magnesitlagerstätte Eugui (Westpyrenäen). TMPM Tsch. Min. Petro. Mitt. 25:185–193 (1978)

    Google Scholar 

  • Krausse, H.F.: Übersicht über die tektonischen Formungen und Strukturen in den Spanischen Westpyrenäen. N: Jb. Geol. Paläont. Abh. 142/1:1–29 (1973)

    Google Scholar 

  • Kubler, B.: La cristallinité de l'illite et les zones tout à fait superieures du métamorphisme. In: Etages tectoniques. A la Baconniére, Neuchatel (Suisse) 105–121 (1967)

  • Kubler, B., Pitton, J.L., Heroux, Y., Charrollais, J., Weidmann, M.: Sur le pouvoir reflecteur de la vitrinite dans quelques roches du Jura, de la Molasse et des Nappes Prealpines, Helvetique et Penniques. Eclogae Geol. Helvetiae 72:347–373 (1979)

    Google Scholar 

  • Landis, C.A.: Graphitization of dispersed carbonaceous material in metamorphic rocks. Contr. Mineral. Petr. 30:34–43 (1971)

    Google Scholar 

  • Leguey, A., Arrese, F., Rodriguez, J.: Estudio mineralógico del yacimiento de magnesita de Asturreta (Navarra). Bol. R. Soc. Esp. Hist. Nat. 65:241–262 (1967)

    Google Scholar 

  • Lotze, F.: Referencias de Gomez de Llerena. Geol. Paläont. 1:(3): 334–336 (1955)

    Google Scholar 

  • Meixner, H.: Sobre los cristales de magnesita y dolomita de Asturreta (Valle alto del Arga, Navarra). Inst. “Lucas Mallada”. Pub. Extra 7–2:141–152 (1953)

    Google Scholar 

  • Meixner, H.: Verdreifachte Achsenbilder an den Magnesit Kristallen von Asturreta in Spanien. Tsch. Min. Petr. Mitt. 4:1–4 (1954)

    Google Scholar 

  • Müller, J.: Sur la superposition des deformations dans les Pyrénées occidentales. C. R. Ac. Sci. (Paris). Sér. D-265:400–402 (1967)

  • Murray, R.C.: Hydrocarbon fluid inclusions in quartz. Am. Assoc. Petrol. Geol. Bull. 41:950–957 (1957)

    Google Scholar 

  • Petraschek, W.E., Kralik, M., Ranzenbacher, A.: The strata-bound magnesite deposit of Eugui Asturreta in the Spanish Pyrénées. In: Time and Strata Bound Ore Deposits, D.D. Klemm and H.J. Schneider, Ed., pp. 254–259, Berlin-Heidelberg-New York: Springer 1977

    Google Scholar 

  • Pilger, A.: Zur Genese der Magnesite in den Westpyrenäen. Zt. Geol. Ges. Bd. 111:198–208 (1959)

    Google Scholar 

  • Pilger, A.: Dévonien supérieur, Carbonifére inférieur et Namurien avec la magnésite d'Eugui au Sud Ouest du massif d'Aldudes Quinto Real dans les Pyrénées Occidentales espagnoles. Pirineos (C.S.-I.C.) 111:129–145 (1974)

    Google Scholar 

  • Poty, B., Leroy, J., Jachimowicz, L.: Un nouvel appareil pour la mesure des températures sous le microscope: l'installation de microthermométric Chiaxmeca. Boll. Soc. Fr. Minéral. Cristall. 99:182–186 (1976)

    Google Scholar 

  • Quemeneur, J.M.: Les gisement de magnésite du Pays Basque: Cadre géoligique et sédimentologique; génese de la magnésite en milieu sédimentaire. Diss. Univ. Paris VI, Unpublished, pp. 249 (1974)

  • Ragot, J.P.: Evolution du degré d'organisation des particules carbonées disséminées dans les roches. Bull. Centre Rech. Pau-SNPA, 10:221–25 (1976)

    Google Scholar 

  • Robert, P.: The optical evolution of kerogen and geothermal histories applied to oil and gas exploration. In: Insoluble organic matter from sedimentary rocks, B. Durang, Ed., pp. 385–414, Paris: Technicep (1980)

    Google Scholar 

  • Sassi, F.P., Scolari, A.: The b 0 value of the potassic white micas as a barometric indicator in low-grade metamorphism of pelitic schists. Contr. Mineral. Petrol. 45:143–152 (1974)

    Google Scholar 

  • Schroll, E.: Geochemical indicator parameters of lead-zinc ore deposits in carbonate rocks. In: Syngenesis and Epigenesis in the Formation of Mineral Deposits. Wauschkuhn, A., et al., Ed., pp. 294–305, Berlin-Heidelberg-New York: Springer 1984

    Google Scholar 

  • Siegel, W.: Reflections on the origin of sparry magnesite deposits. In: Syngenesis and Epigenesis in the Formation of Mineral Deposits. A. Wauschkuhn et al., Ed., pp. 177–182. Berlin-Heidelberg-New York: Springer 1984

    Google Scholar 

  • Stach, E., Mackowsky, M.T., Teichmüller, M., Taylor, G.H., Chandra, D., Teichmüller, R.: Coal Petrology, pp. 535, Berlin-Stuttgart: Gebrüder Borntraeger 1982

    Google Scholar 

  • Tagiri, M.: A measurement of the graphitizing degree by the X-ray powder diffractometer. J. Japan Assoc. Min. Petr. Econ. Geol. 345–352 (1981)

  • Touray, J.C., Barlier, J.: Liquid and gaseous hydrocarbon inclusions in quartz monocrystals from “Terres Noires” and “Flysch a Helminthoides” (French Alpes). Fortsch. Mineral. Spec. Issue. 52:419–426 (1975)

    Google Scholar 

  • Valdiya, K.S.: Origin of the magnesite deposits of southern Pithoragar, Himalaya, India. Econ. Geol. 8 (1968)

  • Velde, B.: Phengite micas: synthesis, stability and natural occurrence. Am. J. Sci. 263:886–913 (1965)

    Google Scholar 

  • Velde, B., Hower, J.: Petrological significance of illite polymorphism in Paleozoic sedimentary rocks. Am. Mineral. 48:1249–1254 (1963)

    Google Scholar 

  • Wassojewitsch, N.B., Kortschagina, I.I., Loparin, N.W., Tschernikov, K.A.: Die Hauptphase der Erdölbildung. Z. Angew. Geol. Dtsch. 15–12:611–621 (1969)

    Google Scholar 

  • Weaver, C.E., Broekstra, B.R.: Illite mica. In: Shale Slate Metamorphism in Southern Appalachiens, C.E. Weaver et al., pp. 67–199, Amsterdam: Elsevier 1984

    Google Scholar 

  • Wirth, M.: Zur Gliederung des höheren Paläozoikums (Givet Namur) im Gebiet Quinto Real (Westpyrenäen) mit Hilfe von Conodonten. N. Jb. Geol. Paläont. 127–2:179–244 (1967)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Velasco, F., Pesquera, A., Arce, R. et al. A contribution to the ore genesis of the magnesite deposit of Eugui, Navarra (Spain). Mineral. Deposita 22, 33–41 (1987). https://doi.org/10.1007/BF00204241

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00204241

Keywords

Navigation