Abstract
In order to test the chronometer qualities of speculante for the (U + Th)/He dating method, 4He release experiments by stepwise heating of two specularites from the Rimbach mineralization locality in the southern Vosgues (France) have been carried out. The diffusion coefficients define linear Arrhenius plots within a temperature interval of 250 to 830 °C, which is suggestive of volume diffusion. Extrapolation of the diffusion behavior to 20° C yields diffusion coefficients (D20 values) smaller than 10−26 [cm2 s−1] for both hematites with activation energies at 116 [kJ/mole]. The results of our study suggest that specularite is a very helium retentive hematite variety which is capable of quantitatively retaining radiogenic helium over geologic periods of time.
Similar content being viewed by others
References
Ahrens LH (1955) The convergent lead ages of the oldest monazites and uraninites. Geochim Cosmochim Acta 7:294–298
Bähr R (1987) Das (U + Th)/He-System in Hämatit als Chronometer für Mineralisationen. Dr rer nat thesis, Univ of Heidelberg, 245 pp, Heidelberger geow. Abh. Bd 4
Boschmann Käthler W (1986) Uran und Helium in Erzmineralien und die Frage ihrer Datierbarkeit. Dr rer nat thesis, Univ of Heidelberg, 234 pp
Damon PE (1970) A theory of ‘real’ K-Ar clocks. Eclogae Geol Helv 63/1:69–76
Dodson MH (1973) Closure temperature in cooling geochronological and petrological systems. Contrib Mineral Petr 40:259–274
Fanale FP, Kulp JL (1962) The helium method and the age of Cornwall, Pennsylvania magnetite ore. Econ Geol 57:735–746
Fechtig H, Kalbitzer S (1966) The diffusion or organ in potassiumbearing solids. In: Schaeffer OA, Zaehringer J (eds). Potassium Argon Dating: Springer, Berlin Heidelberg New York, pp 68–107
Herr W, Merz E (1955) Zur Bestimmung der Halbwertszeit des 187Re. Z Naturforsch 10a:613–615
Lippolt HJ, Bähr R, Boschmann W (1989) 4He diffusion from ore minerals, especially from hematite. Terra Abstr 1/1:355
Lippolt HJ, Boschmann Käthler W, Arndt H (1982) Helium und Uran in Schwarzwälder Bleiglänzen, ein Datierungsversuch. Oberrhein geol Abh 31:31–46
Lippolt HJ, Gentner W, Wimmenauer W (1963) Alterbestimmung nach der Kalium-Argon-Methode an tertiären Eruptivgesteinen Südwestdeutschlands. Jh Geol Landesamt Baden-Württ 6:507–538
Lippolt HJ, Weigel E (1988) 4He diffusion in 40Ar-retentive minerals. Geochim Cosmochim Acta 52:1449–1458
Novakovic L, Sreckovic A, Dojcilovic J, Napijalo M (1987) Physical properties of hematite near the high temperature magnetic phase transition. High temp-high press 19:437–442
Ramdohr P, Struntz H (1978) Klockmanns Lehrbuch der Mineralogie. Ferdinand Enke, Stuttgart
Rösler HJ (1979) Lehrbuch der Mineralogie. Deutscher Verlag für Grundstoffindustrie, Leipzig
Saito T (1965) The anomalous thermal expansion of hematite at a high temperature. Bull Chem Soc Japan 38:2008–2009
Schnaebele E (1914) Die Mineralgänge des oberen Dollertales und ihre Nebengesteine. Mitt Geol Landesamt Elsaß-Lothringen IX/1:159–272
Segev A, Halicz L, Lang B, Steinitz G (1991) K-Ar dating of manganese minerals from the Eisenbach region, Black Forest, southwest Germany. Schweiz Mineral Petrol Mitt 71:101–114
Staudacher T, Jessberger EK, Dörflinger D, Kiko J (1978) A refined ultra high-vacuum furnace for rare gas analysis. J Phys E Sci Instr 11:781–789
Stokking LB, Tauxe L (1987) Acquisition of chemical remanent magnetization by synthetic iron oxide. Nature 327:610–612
Strutt RJ (1905) On the radioactive minerals. Proc Roy Soc London A76:88–101
Strutt RJ (1910) On the accumulation of helium in geological time II. Proc Roy Soc London A83:96–99
Wernicke RS, Lippolt HJ (1993) Botryoidal hematite from the Schwarzwald (Germany): heterogeneous uranium distributions and their bearing on the helium dating method. Earth Planet Sci Lett 114:287–300
York D, Hasliwec A, Kuybida P, Hanes JA, Hall CH, Kenyon WJ, Spooner ETC, Scott SD (1982) 40Ar/39Ar dating of pyrite. Nature 300:52–53
Author information
Authors and Affiliations
Additional information
Now at Gesellschaft für Anlagen- und Reaktorsicherheit (GRS)mbH, Schwertnergasse 1, D-50667 Köln, Germany
Rights and permissions
About this article
Cite this article
Lippolt, H.J., Wernicke, R.S. & Boschmann, W. 4He diffusion in specular hematite. Phys Chem Minerals 20, 415–418 (1993). https://doi.org/10.1007/BF00203111
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00203111