Summary
Several factors which influence the treatment of timber products with vapour phase preservatives such as borate esters are considered. Gas flow rate through the substrate was found to be a significant factor limiting both preservative penetration and its rate of deposition. A theoretical model of the treatment process was developed and tested experimentally to determine the influence of several factors on the retention and distribution of boric acid. Gas flow into the timber product was influenced by permeability, pressure gradient and substrate moisture content. The implications of the findings are considered with regard to the treatment of wood and wood products with gaseous reagents.
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References
Arrhenius, S. 1889: Z. Physik Chem., 4, 226. See Transactions of the Faraday Society., 33, 72 9 1957; Mayer, J. Am. Chem. Soc., 49: 3033, (1927)
Banks, W. B. 1975: Physical factors affecting the flow of gases and liquids through swollen and unswollen softwoods. PhD Thesis, University of London
British Standard BS: 5666 Part 2 1980: British standard method of analysis of wood preservatives and treated timber. Part 2: Qualitative analysis. British Standards Institute, London
Burton, R.; Bergervoet, T.; Nasheri, K.; Vinden, P.; Page, D. 1990: Gaseous preservative treatment of wood. International Research Group on Wood Preservation, Document No IRG/WP3631
Christopher, P. M.; Shilman, A. 1967: Vapour pressure of trialkyl borates. Journal of Chemical Engineering and Data, 12(3): 333–335
Murphy, R.J.; Turner, P. 1989: A novel method for the preservative treatment of wood based on panel products. Wood Sci. Technol. 23: 273–279
Reynolds, O. 1833: An experimental investigation of the circumstances which determine whether motion of water will be direct or sinuous and of the law of resistance in parallel channels. Philosophical Transactions of the Ropyal Society, London
Rowlinson, J. S. 9169: Liquids and mixtures. 2nd Edition, Butterworth and Co. (Publishers) Ltd, London
Steinberg, H.; Hunter, D. 1955: The rate of hydrolysis of organic borates. Internal report, US Borax
Turner, P. 1991: Treatment of timber products with volatile borate esters. PhD Thesis, University of London, 149 pp
Turner, P.; Murphy, R. J. 1987: A novel process for the treatment of manufactured wood based board material. Proceedings of the IUFRO Wood Protection Subject Group Delawana Inn. Honey Harbour, Ontario, Canada, May 16–17, 1987
Turner, P.; Murphy, R. J.; Dickinson, D. J. 1990: Treatment of wood based panel products with volatile borates. Proceedings of the International Research group on wood preservation. Document number IRG/WP/3616, 14 pp
Vinden, P.; Fenton, P.; Nasheri, K. 1985: Options for Accelerated Boron treatment: A practical review of alternatives. The International Research Group on wood preservation. Document number IRG/WP/3329, 21 pp
Williams, A.I. 1968: The Extraction and Determinantion of Dissodium Octoborate in Sitka spruce. Analyst, 93: 111–115
Williams, A. I. 1970: The chemical analysis of Disodium Octoborate in Preserved Sofwoods. Analyst, 95: 498–504
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The authors wish to thank the following for their financial support and interest in this research programme — Rentokil Ltd, Rhone-Poulenc/Manchem Ltd, Forestry Commission, UK and Ireland Particleboard Association (now Panel Products Association), Norbord Highland plc (formerly Highland Forest Products plc), IMPEL
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Turner, P., Murphy, R.J. Treatment of timber products with gaseous borate esters. Wood Sci.Technol. 29, 385–395 (1995). https://doi.org/10.1007/BF00202586
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DOI: https://doi.org/10.1007/BF00202586