Abstract
Time resolved mass spectroscopy of the emissions accompanying the fracture of calcite (rhombohedral CaCO3) show that the principle volatile product, CO2, is released in bursts milliseconds after the fracture event. Similar measurements during the abrasion of calcite and during low temperature thermal decomposition of pulverized calcite show similar CO2 bursts. We argue that the observed bursts reflect localized decomposition of the calcite during the relaxation of reversible plastic deformation created by fracture and abrasion. This implies that mechanical, non-thermal processes play an important role in producing the observed decomposition products.
Similar content being viewed by others
References
Anuradha P, Bhagavan Raju IVK (1986) Plastic flow in CaCO3 and NaNO3. Phys Status Solidi A 95:113–119
Armstrong RW, Coffey CS, Elban WL (1982) Adiabatic heating at a dislocation pile-up avalanche. Acta Metall 30:2111–2116
Baer DR, Blanchard DL, Engelhard MH, Zachara JM (1991) The interaction of water and Mn with surfaces of CaCO3: an XPS study. Surf Interface Anal 17:25–30
Barber DJ, Wenk H-R (1979) Deformation twinning in calcite, dolomite, and other rhombohedral carbonates. Phys Chem Minerals 5:141–165
Burns SJ, Webb WW (1966) Plastic deformation during cleavage of LiF. Trans Metal Soc AIME 236:1165–1174
Darroudi T, Searcy AW (1981) Effect of CO2 pressure on the rate of decomposition of calcite. J Phys Chem 85:3971–3974
Dickinson JT, Jensen LC, McKay MR, Freund F (1986) Emission of atoms and molecules due to fracture of single crystal MgO. J Vac Sci Technol A 4:1648–1652
Dickinson JT, Jensen LC, McKay MR (1987) Neutral molecule emission from the fracture of crystalline MgO. J Vac Sci Technol A 5:1162–1168
Dickinson JT, Jensen LC, Langford SC, Hirth JP (1991a) Atomic and molecular emission following fracture of alkali halides: A dislocation driven process. J Mater Res 6:112–125
Dickinson JT, Jensen LC, Langford SC (1991 b) Atomic and molecular emission accompanying fracture of single-crystal Ge: a dislocation driven process. Phys Rev Lett 66:2120–2123
Dickinson JT, Jensen LC, Langford SC (1991a) Translation energy of alkali emission accompanying fracture of NaCl. (manuscript in preparation)
Donaldson EE, Dickinson JT, Battacharya SK (1988) Production and properties of ejecta released by fracture of materials. J Adhes 25:281–302
Forwood CT, Lawn BR (1966) Plastic deformation patterns on cleavage surfaces of lithium fluoride. Philos Mag 13:595–602
Fox PG, Soria-Ruiz J (1970) Fracture-induced thermal decomposition in brittle crystalline solids. Proc R Soc London 317:79–90
Gilman JJ, Knudsen C, Walsh WP (1958) Cleavage cracks and dislocations in LiF crystals. J Appl Phys 29:601–607
Kaga H, Gilman JJ (1969) Twinning and detwinning in calcite. J Appl Phys 40:3196–3207
Lange MA, Ahrens TJ (1986) Shock-induced CO2 loss from CaCO3: Implications for early planetary atmospheres. Earth Planet Sci Lett 77:409–418
Langford SC, Dickinson JT (1989) The emission of particles and photons from the fracture of minerals and inorganic materials. In: Coyne LM, Blake D, McKeever S (eds) Structures and active sites of minerals, ACS Symposium Series No. 415. American Chemical Society, Washington, D.C. pp 224–244
Lawn BR, Dabbs TP, Fairbanks CJ (1983) Kinetics of shear-activated crack initiation in soda-lime glass. J Mater Sci 18:2785–2797
Mathison JP, Langford SC, Dickinson JT (1989) Concerning the post-emission of electrons from cleavage surfaces of single crystal LiF. J Appl Phys 65:1923–1928
Searcy AW, Beruto D (1976) Kinetics of endothermic decomposition reactions. I. Steady state chemical steps. J Phys Chem 80:425–429
Stipp SL, Hochella MF Jr (1991) Structure and bonding environments at the calcite surface as observed with X-ray photoelectron spectroscopy (XPS) and low energy electron diffraction (LEED). Geochim Cosmochim Acta 55:1723–1736
Suzuki H, Kamada K (1966) Plastic deformation on the fracture surfaces of germanium crystals cloven at room temperature. J Phys Soc Jpn 21:571–578
Swain MV, Lawn BR, Burns SJ (1974) Cleavage step deformation in brittle solids. J Mater Sci 9:175–183
Thomas JM, Renshaw GD (1967) Influence of dislocations on the thermal decomposition of calcium carbonate. J Chem Soc A 1967:2058–2061
Upakaev FX (1990) Vliyanie temperaturi i defektnosti monokristallov kaltsita na skorost ix destruktsii b noske treshchini. In: XI Bsesoyoznii simpozium po mexanoxemii i mexanoemissii tvepdix tel. Akademiya Nauk SSSR, Moskva, pp 8–10
Yoo KC, Rosemeier RG, Elban WL, Armstrong RW (1984) X-ray topography evidence for energy dissipation at indentation cracks in MgO crystals. J Mater Sci Lett 3:560–562
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dickinson, J.T., Jensen, L.C., Langford, S.C. et al. CO2 emission accompanying the fracture of calcite. Phys Chem Minerals 18, 320–325 (1991). https://doi.org/10.1007/BF00200189
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00200189