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Natural zeolites as cation exchangers for environmental protection

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Abstract

This study describes the state-of-the-art with regard to the use of natural zeolites in the protection of the environment. The review is made up of four main sections. The first introduces the possible cation exchange procedures that can be operated at an industrial level, together with the principles on which they are based. The second deals with removal of NH +4 from municipal and industrial wastewater, reporting operational results from the main industrial-scale plants, together with the most significant and recent laboratory data. The third points out the possibilities for use of natural zeolites for removal of heavy metals from water after laboratory experiments. The fourth shows how chemical and structural features make zeolites a very powerful tool for the decontamination of waters containing radionuclides.

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References

  • Albino, V., Cioffi, R., Pansini, M, Colella, C. (1994) Use of lead exchanged zeolite tuff wastes as pozzolanic material. Mater. Eng. 5:289–298

    Google Scholar 

  • Albino, V., Cioffi, R., Colella, C., Pansini, M. (1995a) Disposal of lead-containing sludges in cement matrix. Environ. Technol. 16:147–156

    Google Scholar 

  • Albino, V., Cioffi, R., Pansini, M. (1995b) The role of naturally occurring zeolite-containing materials in the management of toxic sludges: the case of cadmium. Proc. III Convegno Naz. di Scienza e Tecnologia delle Zeoliti, Aiello, R. (ed.) De Rose Montalto, Italy, pp. 269–276

    Google Scholar 

  • Amicarelli, V., Baldassarre, G., Boghetic, G., Liberti, L., Limoni, N. (1988) Use of Italian zeolites for deammoniation of municipal wastewater. Proc. 2nd Int. Conf. on Environment Protection: 2.A-75-82

  • Breck, D.W. (1974) Zeolite molecular sieves. Wiley, New York

    Google Scholar 

  • Bremner, P.R., Schultze, L.E.:(1995) Ability of clinoptilolite-rich tuffs to remove metal cations commonly found in acidic drainage. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420; pp. 397–404. Int. Comm. Nat. Zeol

    Google Scholar 

  • Carland, R.M., Aplan, F.F.:(1988) Stability and ion-exchange capacity of natural sedimentary zeolites in acidic solutions. In: Perspectives in molecular sieve science. ACS Symposium Series 368, Flank, W.H., Whyte, I.E., Jr. (eds.) Maple Press York, PA (USA): pp. 292–305

    Google Scholar 

  • Cassel, A.F., Pressley, T.A., Schuk, W.W., Bishop, D.F. (1972) Physical-chemical nitrogen removal from municipal wastewater. AIChE, Symp. Ser. 68, 124: 56–64

    Google Scholar 

  • Chelishchev, N.F. (1995) Use of natural zeolites at Chernobyl. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420 pp. 525–532. Int. Comm. Nat. Zeol

    Google Scholar 

  • Chmielewska-Horvatova, E., Konecny, J., Bosan, Z. (1992) Ammonia removal from tannery wastewaters by selective ion exchange on Slovak clinoptilolite. Acta Hydrochim. Hydrobiol. 20(5):269–272

    Google Scholar 

  • Ciambelli, P., Corbo, P., Lumare, F., Porcelli, C. (1984) Ammonium ion exchange with phillipsite tuff in relation to aquacultural systems. In: Zeo-agriculture, use of natural zeolites in agriculture and aquaculture, Pond, W.G., Mumpton, F.A. (eds.) Westview Press Boulder, Colorado pp. 245–252

    Google Scholar 

  • Ciambelli, P., Corbo, P., Liberti, L., Lopez, A., Porcelli, C. (1985a) Ammonia removal from municipal water by phillipsite. In: Zeolites: synthesis, structure, technology and application, Hocevar, D.S., Pejovnik, S. (eds.) Elsevier, Amsterdam pp. 539–546

    Google Scholar 

  • Ciambelli, P., Corbo, P., Porcelli, C., Rimoli, A. (1985b) Ammonia removal from wastewater by natural zeolites. I. Ammonium ion exchange properties of an Italian phillipsite tuff. Zeolites 5:184–187

    Google Scholar 

  • Cioffi, R., Marroccoli, M., Pansini, M. (1991) Utilization of chromium exchanged zeolite tuff in the manufacture of blended cements. Proc. I Convegno Naz. di Scienza e Technologia delle Zeoliti, Colella, C. (ed.) De Frede Napoli pp. 101–107

  • Colella, C., Nastro, A., Aiello, R. (1983) Impiego di tufi zeolitici per la rimozione di ammonio da acque reflue. Engineering Materials, Proc. of the 1st National Meeting ASMI 193–198

  • Colella, C., Aiello, R., Nastro, A. (1984) Evaluation of phillipsite tuff for the removal of ammonia from aquacultural wastewaters. In: Zeo-agriculture, use of natural zeolites in agriculture and aquaculture, Pond, W.G., Mumpton, F.A. (eds.) Westview Press Boulder, Colorado, pp. 239–244

    Google Scholar 

  • Collella, C., Aiello, R. (1988) Ammonium removal from tannery sewages by selective ion exchange using natural phillipsite. In: Occurrence, properties and utilization of natural zeolites, Kallò, D., Sherry, H.S. (eds.) Akademiai Kiado, Budapest, pp. 491–500

    Google Scholar 

  • Colella, C., Pansini, M. (1988) Lead removal from wastewaters using chabazite tuff. In: Perspectives in molecular sieve science. ACS Symposium Series 368, Flank, W.H., Whyte, I.E., Jr. (eds.) Maple Press York, PA (USA), pp. 500–510

    Google Scholar 

  • Colella, C. (1995) Use of Italian chabazite and phillipsite for the removal of heavy metals from wastewaters: a review. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420; pp. 363–375. Int. Comm. Nat. Zeol

    Google Scholar 

  • Colella, C., de' Gennaro, M., Langella, A., Pansini, M. (1995) Cadmium removal from wastewater using chabazite and phillipsite. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420; pp. 377–384. Int. Comm. Nat. Zeol

    Google Scholar 

  • Colella, C. (1996) This volume

  • Coffins, E.D., Campbell, D.O., King, L.J., Knauer, J.B. (1982) Water decontamination process improvement tests and considerations. AIChE Symp. Ser. 78(213) 9–15

    Google Scholar 

  • Dyer, A., Keir, D. (1984) Nuclear waste treatment by zeolites. Zeolites 4: 215–217

    Google Scholar 

  • Dyer, A., Kadhim, F.H. (1989) Inorganic ion exchangers for the removal of zirconium, hafnium and niobium radioisotopes from aqueous solutions. J. Radioanal. Nucl. Chem., Articles 131(1) 161–169

    Google Scholar 

  • Dyer, A., Jozefowicz, L.C. (1992) The removal of thorium from aqueous solutions using zeolites. J. Radioanal. Nucl. Chem., Articles 159(1):47–62

    Google Scholar 

  • Dyer, A. (1993) Use of zeolites in treatment of nuclear waste. Analytical Proceedings of the Meeting of the Radiochemical Methods Group, vol. 30, pp. 190–191

    Google Scholar 

  • Eiscnmann, G. (1962) Cation selective glass electrodes and their mode of operation. Biophys. J. 2: 259–323

    Google Scholar 

  • Ha, K.S., Suzuki, M. (1984) Model calculation of chemical regeneration of spent clinoptilolite from ammonium treatment. J. Chem. Eng. Japan 17 (3):297–303

    Google Scholar 

  • Hewitt, C.N., Metcalfe, P.J., Street, R.A. (1991) A method for the sampling and removal of ionic alkyllead compounds from aqueous solutions using ion exchange media. Water Res. 25: 91–94

    Google Scholar 

  • Hlavay, J., Vigh, G., Olaszi, V.. Inczedy, J. (1983) Ammonia and iron removal from drinking water with clinoptilolite tuff. Zeolites 3:188–190

    Google Scholar 

  • Hlozek, P., Lukac, P., Foldesova, M. (1992) Influence of some cations on the sorption ability of modified clinoptilolites. J. Radioanal. Nucl. Chem., Letters 164(2):109–113

    Google Scholar 

  • Huang, C.P., Hao, O.J. (1989) Removal of some heavy metals by mordenite. Environ. Techn. Lett. 10: 863–874

    Google Scholar 

  • Jorgenscn, S.E., Libor, O., Graber, K.L., Barracs, K. (1976) Ammonia removal by use of clinoptilolite. Water Res. 10: 213–224

    Google Scholar 

  • Kallò, D. (1995) Wastewater purification in Hungary using natural zeolites. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420:pp. 341–350. Int. Comm. Nat. Zeol

    Google Scholar 

  • Kanno, T., Mimura, H. (1985) Inorganic ion exchangers and adsorbents for chemical processing in the nuclear fuel cycle. In: Proc. Technical Committee Meeting on Inorganic Ion Exchangers and Adsorbents for Chemical Processing in the Nuclear Fuel Cycle, organized by the International Atomic Energy Agency, Vienna 12-15 June 1984, pp. 237–247

  • Kesraoui-Ouki, S., Cheeseman, C., Perry, R. (1993) Effects of conditioning and treatment of chabazite and clinoptilolite prior to lead and cadmium removal. Environ. Sci. Technol. 27: 1108–1116

    Google Scholar 

  • Klieve, J.R., Semmens, M.J. (1980) An evaluation of pretreatcd natural zeolites for ammonium removal. Water Res. 14: 161–168

    Google Scholar 

  • Koon, J.H., Kaufman, W.J. (1975) Ammonia removal from municipal wastewater by ion exchange. J. Water Pollut. Control Fed. 47(3):448–465

    Google Scholar 

  • Liberti, L.. Boari, G., Passino, R. (1979) Phosphates and ammonia recovery from secondary effluents by selective ion exchange with production of a slow-release-fertilizer. Water Res. 13: 65–73

    Google Scholar 

  • Liberti, L., Boari, G., Petruzzelli, D., Passino, R. (1981) Nutrient removal and recovery from wastewater by ion exchange. Water Res. 15: 337–342

    Google Scholar 

  • Liberti, L., Lopez, A., Amicarelli, V., Boghetic, G. (1995) Ammonium and phosphorus removal from wastewater using clinoptilolite: a review of the RIM-NUT process. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420; pp. 351–362. Int. Comm. Nat. Zeol

    Google Scholar 

  • Loizidou, M., Haralambous, K.J., Loukatos, A., Dimitrakopolou, D. (1992) Natural zeolites and their ion exchange behavior towards chromium. J. Environ. Sci. Health A27(7):1759–1769

    Google Scholar 

  • Lopez, A., Liberti, L. (1991) Zeolites “closed loop” regeneration. Proc. I Convegno Naz. di Scienza e Technologia delle Zeoliti, Colella, C. (ed.) De Frede Napoli, pp. 139–146

  • Loukatos, A., Loizidou, M., Spyrcllis, N. (1993) Ion exchange behaviour of mercury using natural and synthetic zeolites. Fresenius Envir. Bull. 2: 250–255

    Google Scholar 

  • Lukac, P., Hlozek, P., Foldesova, M. (1992) Sorption of 137Cs and 60Co by chemically treated clinoptilolite and mordenite. Geol. Carpathica Series Clays, 2, 43: 125–128

    Google Scholar 

  • Lukac, P., Foldesova, M. (1994) Sorption properties of chemically treated clinoptilolites with respect to Cs and Co. J. Radioanal. Nucl. Chem., Lett., 188 (6):427–437

    Google Scholar 

  • Maliou, E., Malamis, M., Sakellarides, P.O. (1992) Lead and cadmium removal by ion exchange. Water Sci. Technol. 25: 133–138

    Google Scholar 

  • Maliou, E., Loizidou, M., Spyrellis, N. (1994) Uptake of lead and cadmium by clinoptilolite. Sci. Total Environ. 149: 139–144

    Google Scholar 

  • McLaren, J.R., Farquhar, G.J. (1973) Factors affecting ammonia removal by clinoptilolite. Am. Soc. Civ. Eng. 99(4):429–446

    Google Scholar 

  • Mercer, B.W., Ames, L.L., Touhill, C.J., Van Slike, W.J., Dean, R.B. (1970) Ammonia removal from secondary effluents by selective ion exchange. J. Water Pollut. Control Fed. 42(2):R95

    Google Scholar 

  • Mercer, B.W., Ames, L.L. (1976) Zeolite ion exchange in radioactive and municipal wastewater treatment. In: Natural zeolites. Occurrence, properties, uses, Sand, L.B., Mumpton, F.A. (eds.) Pergamon Press Elmsford, pp. 451–462

    Google Scholar 

  • Michaels, A.S. (1952) Simplified method of interpreting kinetic data in fixed-bed ion exchange. Ind. Eng. Chem. 44: 1922–1930

    Google Scholar 

  • Mimura, H., Kanno, T. (1985) Distribution and fixation of cesium and strontium in zeolite A and chabazite. J. Nucl. Sci. Technol. 22:284–291

    Google Scholar 

  • Mimura, H., Ishihara, Y., Akiba, K. (1991) Adsorption behavior of americium on zeolites. J. Nucl. Sci. Technol. 28: 144–151

    Google Scholar 

  • Mimura, H., Akiba, K., Igarashi, H. (1993a) Removal of heat generating nuclides from high-level liquid wastes through mixed zeolite columns. J. Nucl. Sci. Technol. 30: 239–247

    Google Scholar 

  • Mimura, H., Iijima, K., Akiba, K. (1993b) Surface alteration of sintered product of cesium aluminum silicate under hydrothermal conditions. J. Nucl. Sci. Technol. 30: 1145–1152

    Google Scholar 

  • Mimura, H., Akiba, K.. Kavamura, K. (1994a) Separation of heat generating nuclides from high-level liquid wastes through zeolite columns. J. Nucl. Sci. Technol. 31: 463–469

    Google Scholar 

  • Mimura, H., Akiba, K., Igarashi, H. (1994b) Elulion behavior of cesium by using inorganic salt and acid solution. J. Nucl. Sci. Technol. 31: 711–715

    Google Scholar 

  • Mimura, H., Kobayashi, T., Akiba, K. (1994c) Recovery of heat-generating nuclides in eluted solutions. J. Nucl. Sci. Technol. 31:996–998

    Google Scholar 

  • Mimura, H., Kobayashi, T., Akiba, K. (1995) Chromatografic separation of strontium and cesium with mixed zeolite column. J. Nucl. Sci. Technol. 32: 60–67

    Google Scholar 

  • Misaelides, P., Godelitsas, A., Haristos, D., Noli, F., Filippidis, A., Sikalidis, C. (1993) Determination of heavy metal uptake by the sodium form of heulandite using radiochcmical techniques. Geol. Carpathica-Series Clays 44: 115–119

    Google Scholar 

  • Misaelides, P., Godelitsas, A., Charistos, V., Ioannu, D., Charistos, D. (1994) Heavy metal uptake by zeoliferous rocks from Metaxades, Thrace, Greece: an exploratory study. J. Radioanal. Nucl. Chem. 183: 159–166

    Google Scholar 

  • Mumaw, L., Bruin, W., Nightingale, J. (1981) Evaluation of a recirculating freshwater salmon rearing facility using clinoptilolite. J. World Maricul. Soc. 12(1):40–47

    Google Scholar 

  • Murphy, C.B., Hrycyk, O., Gleason, W.T. (1976) Natural zeolites: novel uses and regeneration in wastewater treatment. In: Natural zeolites. Occurrence, properties, uses, Sand, L.B., Mumpton, F.A. (eds.) Pergamon Press Elmsford, pp. 471–478

    Google Scholar 

  • Nastro, A., Colella, C. (1983) Column ion exchange data for ammonium removal water by phillipsite tuff. Ing. Chim. Ital. 19 (5–6):41–45

    Google Scholar 

  • Pansini, M., Colella, C. (1989) Lead pollution control by zeolite. Mat. Eng. l:623–630

    Google Scholar 

  • Pansini, M., Colella, C. (1990) Dynamic data on lead uptake from water by chabazite. Desalination 78: 287–295

    Google Scholar 

  • Pansini, M., Colella, C., de' Gennaro, M. (1991) Chromium removal from water by ion exchange using zeolite. Desalination 83: 145–157

    Google Scholar 

  • Pansini, M., Colella, C. (1991) Optimization of the process of Cr3+ removal from wastewalers by direct addition of natural zeolites. Proc. I Convegno Naz. di Scienza e Tecnologia delle Zeoliti, Colella, C. (ed.) De Frede Napoli, pp. 131–137

  • Pansini, M., Colella, C., de' Gennaro, M., Langella, A. (1992) Natural zeolites in environment preservation: an innovative strategy for chromium removal. In: Proc. 9th International Zeolite Conference, von Ballmoos, R., Higgins, J.B., Treacy, M.M.J. (eds.) Butterworth-Heinemann, Boston, pp. 215–222

    Google Scholar 

  • Pansini, M., Colella, C., Caputo, D., de' Gennaro, M., Langella, A. (1996) Evaluation of phillipsite as cation exchanger in lead removal from water. Micropor. Mater., 5: 357–364

    Google Scholar 

  • Papachristou, P., Haralambous, K.J., Loizidou, M., Spyrellis, N. (1993) Studies on nickel removal from aqueous solutions. J. Environ. Sci. Health A28(1):135–142

    Google Scholar 

  • Patterson, J.W. (1975) Wastewater treatment technology, Ann Arbor Science Publishers, Ann Arbor, MI (USA)

    Google Scholar 

  • Pillay, K.K.S. (1982) Radiation effects on ion exchange materials used in waste managements. AIChE Symp. Ser. 78, 213: 33–40

    Google Scholar 

  • Robinson, S.M., Begovich, J.M., Brown, Jr., C.H., Campbell, D.O., Collins, E.D. (1987) Treatment of radioactive wastewaters by chemical precipitation and ion exchange. AIChE Symp. Ser. 83, 259:52–65

    Google Scholar 

  • Robinson, S.M., Kent, T.E., Arnold, W.D. (1995) Treatment of contaminated wastewater at Oak Ridge national laboratory by zeolites and other ion exchangers. Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420, pp. 579–586. Int. Comm. Nat. Zeol

    Google Scholar 

  • Santiago, I., Worland, V.P., Cazares-Rivera, E., Cadena, F. (1992) Adsorption of hexavalent chromium onto tailored zeolites. 47th Purdue Industrial Waste Conference Proceedings, Lewis Publisher, Inc., Chelsea, Michigan 48118:699–710

    Google Scholar 

  • Semmens, M.J., Wang, M.J., Booth, A.C. (1977) Nitrogen removal by ion exchange: Biological regeneration of clinoptilolite. J. Water Pollut. Control Fed. 49 (12):2431–2444

    Google Scholar 

  • Semmens, M.J., Martin, W.P. (1988) The influence of the pretreatment on the capacity and selectivity of clinoptilolite for metal ions. Water Res. 22: 537–542

    Google Scholar 

  • Sersale, R., Frigione, G. (1983) Utilization of the quarry dust of the Neapolitan yellow tuff for the manufacture of blended cements. Chim. Ind., Rome 65: 479–481

    Google Scholar 

  • Sersale, R., Frigione, G. (1985) Blended cements manufactured with activated zeolitic additions. Chim. Ind., Rome 67: 537–541

    Google Scholar 

  • Sherry, H.S. (1969) The ion exchange properties of zeolites. In: “Ion Exchange; a series of advance”. Marinsky, J.A. (ed.) vol. 2, Marcel Dekker, New York, pp. 89–133

    Google Scholar 

  • Siemens, D.H., Knowlton, D.E., Shupe, M.W. (1982) Three Mile Island zeolite vitrification demonstration program. AIChE Symp. Ser. 78, 213: 41–43

    Google Scholar 

  • Stegemann, J.A., Coté, P.L. (1992) A proposed protocol for evaluation of solidified waste. In: Proc. Cement Industry Solutions to Waste Management, October 1992, Calgary, Piggott, R.W. (ed.) CPCA, Toronto (Canada), pp. 1–12

    Google Scholar 

  • Tsitsishvili, G.V., Andronikashvili, T.G., Kirov, G.N., Filizova, L.D. (1992) Natural zeolites. Ellis Horwood, Chichester, pp. 235–262

    Google Scholar 

  • US Environmental Protection Agency (1986) Test methods for evaluating solid waste, SW-846. Office of solid waste and emergency response, Washington DC

    Google Scholar 

  • Vaniman, D.T., Bish, D.L. (1995) The importance of zeolites in the potential high-level radioactive waste repository at Yucca Mountain, Nevada. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420, pp. 533–546. Int. Comm. Nat. Zeol

    Google Scholar 

  • Wilson, T.E., Riddell, M.D.R. (1975) Studies of the removal of ammonia nitrogen by ion exchange. AIChE Symp. Ser. 71, 151:118–125

    Google Scholar 

  • Zamzow, M.J., Eichbaum, B.R., Sandgren, K.R., Shanka, D.E. (1990) Removal of heavy metals and other cations from wastewaters using zeolites. Sep. Sci. Tech. 25: 1555–1569

    Google Scholar 

  • Zamzow, M.J., Murphy, J.E. (1992) Removal of metal cations from water using zeolites. Sep. Sci. Tech. 27: 1969–1984

    Google Scholar 

  • Zamzow, M.J., Schultze, L.E. (1995) Treatment of acid mine drainage using natural zeolites. Natural Zeolites '93, Ming, D.W., Mumpton, F.A. (eds.) Brockport, New York 14420, pp. 405–413 Int. Comm. Nat. Zeol.

    Google Scholar 

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  1. Dipartimento di Ingegneria dei Materiali e della Produzione, Facoltà di Ingegneria, Université “Federico II” di Napoli, Piazzale Tecchio 80, 80125, Naples, Italy

    M. Pansini

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Pansini, M. Natural zeolites as cation exchangers for environmental protection. Mineral. Deposita 31, 563–575 (1996). https://doi.org/10.1007/BF00196137

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