Summary
The reaction of bis(iso-propylxanthato)nickel(II) with 1,2-bis(diphenylphosphino)ethane (dppe) in a 1∶1 molar ratio affords [Ni(S2CO)(dppe)], which, on the basis of its magneto-chemical and spectral properties, has been characterized as a square-planar Ni complex. The complex was one-electron irreversibly oxidized at a potential of 0.673 V versus s.c.e. The crystal and molecular structure of a twinned crystal of the complex has been elucidated, and consists of two crystallographically independent molecules in which each Ni atom is coordinated by two S atoms from the dithiocarbonate ligand and two P atoms from the dppe ligand in an approximately square-planar arrangement.
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References
M. F. Perpiñán, L. Ballester, M. E. Gonzáles-Casso and A. Santos, J. Chem. Soc., Dalton Trans., 281 (1987).
A. A. M. Aly, M. M. Kamal, M. S. El-Meligy and A. I. El-Said, Croat. Chem. Acta, 61, 155 (1988).
A. J. M. Duisenberg, J. Appl. Crystallogr., 25, 92 (1992).
G. M. Sheldrick,(SHELXS-86), Acta Crystallogr., Sect. A, 46, 467 (1990).
G. M. Sheldrick, (SHELXL-93), J. Appl. Cryst., in press.
V. Petříček and K. Malý, SDS, A Program Package for X-Ray Structure Determination, Institute of Physics, Czech Academy of Sciences, Prague, 1988.
Gmelins Handbuch der Anorganischen Chemie, Weinheim, Verlag Chemie, Teil C, Lief. 2, 1969, s. 985.
E. A. Boudreaux and L. N. Mulay, Theory and Applications of Molecular Paramagnetism, Wiley, New York, 1976, p. 226.
A. B. P. Lever, Inorganic Electronic Spectroscopy, Eisevier, Amsterdam, 1968, p. 333.
D. E. C. Carbridge, The Infrared Spectra of Phosphorus Compounds in Topics in Phosphorus Chemistry, Wiley, New York, 1969, Vol. 6, p. 235.
F. Březina and A. Zemek, Acta Univ. Palacki. Olomuc., Fac. Rerum Nat., 73, 5 (1982).
F. Beck, Elektroorganische Chemie, Verlag Chemie, Weinheim, 1974, s. 90.
W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).
Z. Trávniček, R. Pastorek and J. Marek, Collect. Czech. Chem. Commun., 59, 616 (1994).
R. Busby, M. B. Hursthouse, P. S. Jarret, Ch. W. Lehmann, K. M. Abdul Malik and C. Philips, J. Chem. Soc., Dalton Trans., 3767 (1993).
Z. Trávníček and J. Marek, Unpublished work.
R. C. Weast (Ed.), Handbook of Chemistry and Physics, 56th Edit., CRC Press, Cleveland, Ohio, 1975.
I. J. B. Lin, H. W. Chen and J. P., Fackler Jr, Inorg. Chem., 17, 394 (1978).
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Trávníček, Z., Pastorek, R., Šindelář, Z. et al. Investigation of {1,2-bis(diphenylphosphino)ethane-P,P′}-(dithiocarbonato-S,S′)-nickel(II). Transition Met Chem 21, 81–84 (1996). https://doi.org/10.1007/BF00166020
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DOI: https://doi.org/10.1007/BF00166020