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A novel trinuclear nickel(II) complex with a Schiff base derived from m-phenylenediamine and diacetyl monoxime

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Summary

A tetradentate Schiff base derived from diacetyl monoxime and m-phenylenediamine (H2mphdao2) reacts in MeOH with NiI2 to form the trinuclear complex Ni3(mphdao2)2I2, which was characterized by elemental and thermal analyses, and i.r. and u.v.-vis. spectroscopies. The magnetic properties have been investigated in the 4.2–300 K range.

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Palaeký University, Křížkovského 10, 771 47, Olomouc, Czech Republic

    František Březina, Zdeněk Smékal, Zdeněk Šindelář & Richard Pastorek

  2. Institute of Chemistry, University of Wroclaw, 50-383, Wroclaw, Poland

    Jerzy Mroziňski

Authors
  1. František Březina
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  2. Zdeněk Smékal
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  3. Zdeněk Šindelář
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  4. Richard Pastorek
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  5. Jerzy Mroziňski
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Březina, F., Smékal, Z., Šindelář, Z. et al. A novel trinuclear nickel(II) complex with a Schiff base derived from m-phenylenediamine and diacetyl monoxime. Transition Met Chem 21, 287–288 (1996). https://doi.org/10.1007/BF00165985

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  • DOI: https://doi.org/10.1007/BF00165985

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