Summary
The complexes K[Pt(l-aze)Cl2, [Pt(l-aze)2] and [Pd(l-aze)2] (l-aze = l-azetidine-2-carboxylate) were prepared. X-ray structures show that [Pt(l-aze)2] and [Pd(l-aze)2] are isomorphous, having a planar tetragonal geometry with a trans configuration around the Pt and Pd atoms. Slight puckerings of the MN(1)N(11)O(11) chelate ring (M = Pt or Pd) and the azetidine ring were observed. The circular dichroism (c.d.) spectra of the complexes in aqueous solution agree with the structures found in the solid state as far as the hexadecant rule is concerned, giving, for the trans configuration of [M(l-ia)2] (where ia = imino acid), the profile of the c.d. signs for the three predominant d-d transitions as: +,-,-. I.r., conductivity and n.m.r. measurements are also reported and are in accord with the proposed structures.
Similar content being viewed by others
References
L. Fowden, Advan. Enzym., 29, 89 (1967).
L. Fowden, J. Exp. Botany, 14, 387 (1963).
L. Fowden and M. H. Richard, Biochim. Biophys. Acta, 71, 459 (1963).
D. J. Cummings, V. A. Chapman, S. S. DeLong and L. Mondale, J. Virol., 1, 193 (1967).
F. D. Collins and W. K. Roberts, J. Virol., 10, 969 (1972).
W. D. Klohs, R. W. Steinkampt, M. S. Wicha, A. E. Mertus, J. B. Tunac and W. R. Leopold, J. Natl. Canc. Inst., 75, 353 (1985).
K. Freund and H. Frye, Inorg. Nucl. Chem. Lett., 7, 107 (1971).
C. Lin and B. E. Douglas, J. Coord. Chem., 2, 117 (1972).
C. R. White and M. D. Joesten, J. Coord. Chem., 6, 53 (1976).
R. Kramer, K. Polborn, H. Wanjek, I. Zahn and W. Beck, Chem. Ber., 123, 767 (1990).
H. M. Berman, E. L. McGandy, J. W. Burgner and K. L. VanEtten, J. Am. Chem. Soc., 91, 6177 (1969).
F. Inagaki, S. Takahashi, M. Tasumi and T. Miyazawa, Bull. Chem. Soc. Japan, 48, 853 and 1590 (1975).
D. Kovala-Demertzi, M. Demertzis and J. M. Tsangaris, Bull. Soc. Chim. Fr., 558 (1986).
T. A. Kabanos, A. D. Keramidas, D. Mentzafos, U. Russo, A. Terzis and J. M. Tsangaris, J. Chem. Soc., Dalton Trans., 2729 (1992).
J. S. Coe and J. R. Lyons, J. Chem. Soc. (A), 829 (1971).
G. M. Sheldrick, SHELXS-86: Structure Solving Program, University of Gottingen, Germany, 1986.
G. M. Sheldrick, SHELX-76: Program for Crystal Structure Determination, University of Cambridge, England, 1976.
O. P. Slyudkin, L. Kh. Minacheva, G. A. Fedorova, V. G. Sakharova, T. S. Khodashova and M. A. Porai-Koshits, Koord. Khim., 11, 963 (1985).
K. Kh. Minacheva, O. P. Slyudkin, M. A. Porai-Koshits and T. S. Khodashova, Koord. Khim., 8, 557 (1982).
T. Ito, F. Marumo and Y. Saito, Acta Crystallogr., B27, 1062 (1971).
S. Sinh, V. M. Padmanabhan, R. P. Patel, T. N. Ranganathan and G. S. Rao, Current Sci., 51, 330 (1982).
A. McL. Mathieson and H. K. Welsh, Acta Crystallogr., 5, 599 (1952).
H. M. Haendler, Acta Crystallogr., C41, 690 (1985).
J. N. Brown, R. J. Majeste, L. D. Chung and L. M. Trefonas, Cryst. Struct. Commun., 6, 65 (1977).
A. W. Herlinger and Th. Veach Long, J. Am. Chem. Soc., 92, 6481 (1970).
G. B. Deacon, F. Huber and R. J. Phillips, Inorg. Chim. Acta, 104, 41 (1985).
A. Garoufis, R. Haran, M. Pasdeleup, J. P. Laussac and N. Hadjiliadis, J. Inorg. Biochem., 31, 65 (1987).
D. M. Adams, Metal-Ligand and Related Vibrations, Edward Arnold, London 1968, p. 281.
Yu, S. Varshavskii, E. N. In'kova and A. A. Grinberg, Russ. J. Inorg. Chem., 8, 1394 (1963).
A. Rosenberg, Acta Chem. Scand., 10, 840 (1956).
D. M. Adams, J. Chatt, J. M. Davidson and J. Geratt, J. Chem. Soc., 2189 (1963); D. M. Adams, J. Chatt, J. Geratt and A. D. Westland, J. Chem. Soc., 734 (1964).
O. P. Slyudkin, M. A. Kerzhentsev, O. N. Adrianova and L. M. Volstein, Koord. Khim., 2, 1396 (1976).
E. W. Wilson and R. B. Martin, Inorg. Chem., 9, 528 (1970).
J. M. Tsangaris and R. B. Martin, J. Am. Chem. Soc., 92, 4255 (1970).
J. M. Tsangaris, E. Voureka and D. Kovala-Demertzi, Acta Chim. Hung., 128, 213 (1991).
O. P. Slyudkin, R. D. Gillard, M. A. Kerzhentsev, O. N. Adrianova and L. M. Volstein, Koord. Khim., 3, 1575, (1977).
Y. Saito, Inorganic Molecular Dissymmetry, Springer Verlag, Berlin, 1979, p. 150.
C. R. White and M. D. Joesten, J. Coord. Chem., 6, 53 (1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Voureka, E., Tsangaris, J.M., Terzis, A. et al. Coordination complexes of l-azetidine-2-carboxylic acid with platinum(II) and palladium(II). Transition Met Chem 21, 244–249 (1996). https://doi.org/10.1007/BF00165976
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00165976