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Tetrachloroaurate(III) oxidation of thallium(I)

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Summary

The complementary reaction between TlI and AuCl sup−inf4 was studied in a 3.0 mol dm−3 HCl medium. The active species of oxidant and reductant were found to be HAuCl4 and TlCl sup−inf2 , respectively. A mechanism involving these reactive species is proposed, in agreement with the results obtained.

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References

  1. G. S. Gokavi and J. R. Raju, Polyhedron, 6, 1721 (1987).

    Google Scholar 

  2. G. S. Gokavi and J. R. Raju, Int. J. Chem. Kinetics, 20, 365, (1988).

    Google Scholar 

  3. B. G. Ankumwar, M. D. Bhand and G. S. Gokavi, Transition Met. Chem., 18, 361 (1993).

    Google Scholar 

  4. F. A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 3rd Edit., Wiley Eastern Limited, New Delhi, 1987, p. 280.

    Google Scholar 

  5. S. R. Sagi, G. S. Prakasa Raju and K. V. Ramana, Talanta, 22, 93 (1975).

    Google Scholar 

  6. R. L. Rich and H. Taube, J. Phys. Chem., 58, 6 (1954).

    Google Scholar 

  7. A. Peloso, Coord. Chem. Rev., 16, 95 (1975).

    Google Scholar 

  8. V. P. Kazakov, A. I. Matveeva, A. M. Erenburg and B. I. Peshchevitskii, Russ. J. Inorg. Chem., 10, 563 (1965).

    Google Scholar 

  9. A. G. Lee, The Chemistry of Thallium, Elsevier, New York, 1971, p. 29.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Shivaji University, 416 004, Kolhapur, India

    Anna N. Gidd, Madhukar D. Bhand & Gavisiddappa S. Gokavi

Authors
  1. Anna N. Gidd
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  2. Madhukar D. Bhand
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  3. Gavisiddappa S. Gokavi
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Gidd, A.N., Bhand, M.D. & Gokavi, G.S. Tetrachloroaurate(III) oxidation of thallium(I). Transition Met Chem 20, 367–368 (1995). https://doi.org/10.1007/BF00139131

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  • DOI: https://doi.org/10.1007/BF00139131

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