Summary
The cyclophosphazenerhenium(VII) dioxide N(PPh2N)2-ReO2 (1 mol) reacts with aryl isocyanates, ArNCO (2 mol), in PhMe to yield solid red-brown compounds which are substitution products, or substitution plus addition products, or mixtures of both. The compounds were characterized by elemental analysis, mass, i.r. and n.m.r. spectroscopies.
Similar content being viewed by others
References
H. R. Allcock, Phosphorus-Nitrogen Compounds, Academic Press, New York, 1972.
R. H. Neilson and W. Neilson, Chem. Rev., 88, 625 (1988).
H. R. Allcock, P. P. Greigger, L. J. Wagner and M. Y. Bernheim, Inorg. Chem., 20, 716 (1981).
H. R. Allcock, L. J. Wagner and M. L. Leven, J. Am. Chem. Soc., 105, 1321 (1983).
H. R. Allcock, G. H. Riding and R. R. Whittle, J. Am. Chem. Soc., 106, 5561 (1984).
P. P. Greigger and H. R. Allcock, J. Am. Chem. Soc., 201, 2492 (1979).
H. W. Roesky, Synlett., 651 (1990).
H. W. Roesky, K. V. Katti, U. Seseke, M. Witt, E. Egert, R. Herbst and G. M. Sheldrick, Angew. Chem., 88, 447 (1986).
R. Hasselbring, H. W. Roesky and M. Noltemayer, Angew. Chem., 104, 613 (1992).
H. W. Roesky and M. Lücke, Angew. Chem., 101, 480 (1989).
H. W. Roesky, P. Olms, M. Witt, K. Keller, D. Stalke, T. Henkel and G. M. Sheldrick, J. Chem. Soc., Chem. Commun., 336 (1989).
S. K. Pandey, A. Steiner, H. W. Roesky and D. Stalke, Angew. Chem., 105, 625 (1993).
S. K. Pandey, A. Steiner, H. W. Roesky and D. Stalke, Inorg. Chem., 32, 5444 (1993).
R. Hasselbring, S. K. Pandey, H. W. Roesky and D. Stalke, J. Chem. Soc., Dalton Trans., 3447 (1993).
A. D. Horten and R. R. Schrock, Polyhedron, 7, 1841 (1988).
D. S. Williams, J. T. Anhous, M. H. Schofield, R. R. Schrock and W. M. Davis, J. Am. Chem. Soc., 113, 5480 (1991).
M. H. Schofield, R. R. Schrock and L. Y. Park, Organometallics, 10, 1844 (1991).
H. W. Roesky, D. Hesse, M. Noltemayer and G. M. Sheldrick, Chem. Ber., 124, 757 (1991).
Author information
Authors and Affiliations
Additional information
Dedicated to the late Dr G. Srivastava, Chem. Dept., Rajasthan University, Jaipur, India.
Rights and permissions
About this article
Cite this article
Pandey, S.K. Cyclophosphazenerhenium(VII) imides. Transition Met Chem 20, 365–366 (1995). https://doi.org/10.1007/BF00139130
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00139130