Summary
Rhodium(I), iridium(I), palladium(II) and platinum(II) complexes of the phosphinoamide ligands, Ph2PCH2CONHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized by using conductivity data, i.r., 1H and 31P(H) n.m.r. spectral data. Reaction of the ligands with MCl(PPh3)3 and MCl(CO)(PPh3)2 (M = Rh, Ir) in CH2Cl2 under reflux lead to the formation of MCl(PPh3)2 [Ph2PCH2C(O)NHR] and MCl(CO)(PPh3)[Ph2PCH2−C(O)HNR] respectively. The reaction of either K2MCl4 or cis-MCl2(PPh3)2 affords complexes of the type cis-MCl2[Ph2PCH2C(O)NHR]2 (M = Pd, Pt). A similar product results even from the reaction of phosphinoamides with cis-platin. Possible structures are proposed for the complexes based on their physicochemical data
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References
J. P. Kleimann and M. Dubeck, J. Am. Chem. Soc., 85, 1544 (1963).
G. W. Parshall, Acc. Chem. Res., 3, 139 (1970).
A. J. Cheney, B. E. Mann, B. L. Shaw and R. M. Slade, J. Chem. Soc. A, 3833 (1971).
T. Satyanarayana and K. Veera Reddy, Transition Met. Chem., in press.
J. A. Osborn, G. Wilkinson and J. F. Young, J. Chem. Soc., Chem. Commun., 17 (1965).
L. Vaska, Science, 140, 809(1963).
L. Vaska, Acc. Chem. Res., 1, 335 (1968).
C. Y. Hsu, B. T. Leshner and M. Orchin, Inorg. Synth., 19 114 (1979).
F. G. Mann and D. Purdie, J. Chem. Soc., 1549 (1935).
J. C. Bailar Jr. and H. Itatani, Inorg. Chem., 4, 1615 (1965).
L. Malatesta and C. Cariollo, J. Chem. Soc., 2323 (1958).
F. A.Cotton and G.Wilkinson, Advanced Inorganic Chemistry, 3rd Edit,Wiley-Inter Science, 1980.
J. M. Miller, Adv. Inorg. Radio Chem., 4, 133 (1962).
B. Rosenberg, Platinum Metals Rev., 15, 42 (1971).
B. Rosenberg, L. Van Kamp, J. F. Trosko and V. H. Mansour, Nature (Lond.), 222, 385 (1969).
W. G. Geary, Coord. Chem. Rev., 7, 81 (1971).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd Edit. Wiley, New York, 1978.
P. E. Garrou, Chem. Rev., 81, 229 (1981).
M. K. Cooper and J. M. Downes, Inorg. Chem., 17, 880 (1978).
M. Gratson and E. J. Smith, Top. Phosph. Chem., 5 (1967) and references therein.
H. W. Kroto, J. F. Nixon, M. J. Taylor, A.A. Frew and K. W. Muir, Polyhedron, 1, 89 (1982).
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Satyanarayana, T., Reddy, K.V. Platinum group metal functionalized phosphine complexes. Part 2. Phosphinoamide rhodium(I), iridium(I), palladium(II) and platinum(II) complexes. Transition Met Chem 19, 373–378 (1994). https://doi.org/10.1007/BF00139117
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DOI: https://doi.org/10.1007/BF00139117