Summary
The reactions of methyl-2-amino-4-diethylamino thieno-[2,3-d]pyrimidine 6-carboxylate, methyl-2-amino-4-ethyl-phenylamine thieno-[2,3-d]pyrimidine-6-carboxylate) and methyl-2-amino, 4-morpholino-thieno-[2,3-d]pyrimidine-6-carboxylate with NiII and CoII halides produced complexes of the general formula ML2X2 (where L is thieno pyrimidine and X is Cl or Br). The complexes were characterized by elemental analyses, conductivity and magnetic susceptibility measurements and spectroscopy. All of the complexes were found to have pseudotetrahedral structures with the metal coordinated through the N(1) site of the thieno-[2,3-d]-pyrimidine.
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References
B. R. Baker, R. E. Shamb, J. P. Joseph, F. J. McEroy and J. H. Williams, J. Org. Chem., 18, 138 (1953).
B. Roth, J. Med. Chem., 12, 227 (1969).
A. Rosowsky, M. Chaykowsky, K. K. N. Chen, M. Lin and E. J. Modest, J. Med. Chem., 16, 185 (1973).
M. Chaykovsky, M. Lim A. Rosowsky and E. J. Modest, J. Med. Chem., 16, 188 (1973).
A. Rosowsky, K. K. N. Chen and M. Lin, J. Med. Chem., 16, 191 (1973).
J. Clark, M. S. Shahhet, D. Korakas and G. Varvounis, J. Heterocycl. Chem., 30, 1065 (1993).
C. J. Shishoo, M. B. Devani, M. D. Karvekar, G. V. Ullas, S. Ananthan, V. S. Bhadti, R. B. Patel and T. P. Gandhi, Ind. J. Chem., 21B, 666 (1982).
D. L. Temple, J. P. Yevich, R. R. Covington, C. A. Hanning, R. J. Seidehamel, H. K. Mackey and M. J. Bartek, J. Med Chem., 22, 505 (1979).
P. Tsiveriotis, J. P. Laussac, F. Dahan and D. Hadjiliadis, manuscript in preparation.
I. Yakovidis, G. Varvounis and N. Hadjiliadis, Inorg. Chim. Acta, 151, 165 (1988).
W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).
M. Louloudi, D. Kovala-Demertzi and N. Hadjiliadis, Bull. Soc. Chim. Belg., 97, 91 (1988).
B. N. Figgis and J. Lewis, Progr. Inorg. Chem., 6, 37 (1964).
D. De Filippo and C. Preti, J. Chem. Soc. (A), 1904 (1970).
M. Louloudi and N. Hadjiliadis, J. Chem. Soc., Dalton Trans., 1635 (1991).
G. Marcotrigiano, L. Menabue and G. C. Pellacani, Inorg. Chim. Acta, 26, 57 (1978).
J. D. Ortego, D. P. Waters and C. S. Steele, J. Inorg. Nucl. Chem., 36, 751 (1974).
M. Plytzanopoulos, G. Pneumatikakis, N. Hadjiliadis and D. Katakis, J. Inorg. Nucl. Chem., 39, 965 (1977).
N. Hadjiliadis and T. Theophanides, Can. J. Spectrosc., 22, 51 (1977).
J. Bradbury, K. P. Forest, R. H. Nuttall and D. W. A. Sharp, Spectrochim. Acta, 23A, 2701 (1967).
A. Iakovidis, N. Hadjiliadis, J. F. Britten, I. S. Butler, F. Schwarz and B. Lippert, Inorg. Chim. Acta, 184, 209 (1991).
A. B. P. Lever, Inorganic Electronic Spectroscopy, 3rd Edit., Elsevier, Amsterdam (1968).
D. Kovala-Demertzi, J. Tsangaris and N. Hadjiliadis, Transition Met. Chem., 8, 140 (1983).
D. H. Brown, K. P. Forrest, R. H. Nuttall and D. W. A. Sharp, J. Chem. Soc. (A), 2146 (1968).
M. Mohan, A. Kumar, M. Kumar and N. K. Jha, Inorg. Chim. Acta, 136, 65 (1987).
B. B. Garrett, V. L. Goedken and J. B. Quagliano, J. Am. Chem. Soc., 92, 489 (1970).
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Tsiveriotis, P., Varvounis, G., Papadimitriou, C. et al. Nickel(II) and cobalt(II) complexes of 2,4-diaminothieno[2,3-d]-pyrimidines. Transition Met Chem 19, 335–339 (1994). https://doi.org/10.1007/BF00139107
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DOI: https://doi.org/10.1007/BF00139107