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Synthesis, stepwise instability constants and oxidation of bis-[bromazepan]CuI perchlorate by molecular oxygen in dimethyl sulphoxide

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Summary

The oxidation with molecular oxygen of the cuprous salt, Cu(MeCN)4ClO4, and of bis(bromazepan)CuI perchlorate complex in the presence of different concentrations of the complexing agent bromazepan in DMSO was studied and the formation constants of the complex were calculated from the kinetic data. For comparative purposes the formation constants were also determined spectrophotometrically.

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Authors and Affiliations

  1. Facultad de Ciencias Físicas y Matemáticas, Universidad de Chile, Casilla 2777, Santiago, Chile

    Walter Zamudio & Ruth Baraona

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  1. Walter Zamudio
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  2. Ruth Baraona
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Zamudio, W., Baraona, R. Synthesis, stepwise instability constants and oxidation of bis-[bromazepan]CuI perchlorate by molecular oxygen in dimethyl sulphoxide. Transition Met Chem 18, 489–492 (1993). https://doi.org/10.1007/BF00136611

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  • DOI: https://doi.org/10.1007/BF00136611

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