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Hydroxamic acid dinuclear complexes of molybdenum(V) and molybdenum(III)

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Summary

Molybdenum(V) and molybdenum(III) complexes [Mo2O3L4] and [Mo2L6] derived from hydroxamic acids (HL) were prepared and identified by Raman, i.r., e.s.r., electronic spectra and analytical data. The low magnetic moments of the dinuclear complexes are due to in part to intramolecular interactions. Electronic spectra and vibrational studies indicate the presence of a Mo2O3 core in the molybdenum(V) complexes. The relative intensities of the, main and satellite peaks in e.s.r. spectra indicate the dinulcear nature of molybdenum(III) hydroxamates.

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References

  1. J. T. Spence, Coord. Chem. Rev., 48, 59 (1983).

    Google Scholar 

  2. R. C. Bray and J. C. Swan, Struct. Bonding (Berlin), 11, 107 (1972).

    Google Scholar 

  3. R. C. Bray in P. D. Boyer (Ed.), The Enzymes XIIB, Academic Press, New York, 1975, p. 300.

    Google Scholar 

  4. P. Forgetand and D. V. der Vartinan, Biochem. Biophys. Acta, 256, 600 (1972).

    Google Scholar 

  5. J. Hase and K. Kobashi, J. Biochem. (Tokyo), 62, 293 (1967).

    Google Scholar 

  6. N. E. Dixon, R. L. Blakely and B. Zerner, Can. J. Biochem., 58, 1323 (1980).

    Google Scholar 

  7. A. Wernar, Berichte der Bunsen Gesselschaften, 41, 1062 (1908).

    Google Scholar 

  8. C. Mussante, Gazz. Chim. Ital, 78, 536 (1948).

    Google Scholar 

  9. A. K. Majumdar and Gayatri Das, Anal. Chim. Acta, 36, 454 (1966).

    Google Scholar 

  10. A. I. Vogel, A Text Book of Quantitative Inorganic Analysis, Longmans, London, 472 (1978).

    Google Scholar 

  11. E. I. Stiefel, Prog. Inorg. Chem., 22, 1 (1977).

    Google Scholar 

  12. T. K. Banerjee, S. K. Bramha and S. P. Bag, Indian J. Chem., 30A, 281 (1991).

    Google Scholar 

  13. T. K. Banerjee, S. K. Bramha and S. P. Bag, Indian J. Chem., in press.

  14. T. K. Banerjee, S. K. Bramha and S. P. Bag, Indian J. Chem., 31A, 202 (1992).

    Google Scholar 

  15. G. J. J. Chen, J. W. Mcdonald, D. C. Bravard and W. E. Newton, Inorg. Chem., 24, 2327 (1985).

    Google Scholar 

  16. F. A. Cotton, D. L. Hunter, L. Ricard and R. Weiss, J. Coord. Chem., 3, 259 (1974).

    Google Scholar 

  17. B. Kamenar, B. Korpar-Colig and M. Penavic, Cryst. Struct. Commun., 11, 1583 (1982).

    Google Scholar 

  18. J. F. Gibson, Electron Spin Resonance, Specialist Periodical Report, Chem. Soc., 1, 162 (1973).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, 700032, Calcutta, India

    Tarun K. Banerjee, Swapan K. Bramha & Saswati P. Bag

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  1. Tarun K. Banerjee
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  2. Swapan K. Bramha
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  3. Saswati P. Bag
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Banerjee, T.K., Bramha, S.K. & Bag, S.P. Hydroxamic acid dinuclear complexes of molybdenum(V) and molybdenum(III). Transition Met Chem 18, 485–488 (1993). https://doi.org/10.1007/BF00136610

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