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Synthesis and properties of cyano-bridged nickel(II)-iron(III) complexes

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Summary

Four kinds of novel CN-bridged NiII-FeIII complexes, [NiLn(NC)Fe(CN)5] −, have been synthesized and characterized by elemental analysis, i.r. and u.v.-vis. spectral analysis, and magnetic moments. The formation of cyanide bridges is evident from the i.r. and u.v.-vis. spectra by the appearance of v(CN) shifts and changes in λ max with respect to the mononuclear parent complex [Fe(CN)6]3−. The magnetic properties indicate the existence of magnetic spin interactions between NiII and FeIII through the cyanide bridge.

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Authors and Affiliations

  1. Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, 210093, Nanjing, P. R. China

    Shuzhong Zhan, Xiaoyuan Chen & Qingjin Meng

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  1. Shuzhong Zhan
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  2. Xiaoyuan Chen
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  3. Qingjin Meng
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Zhan, S., Chen, X. & Meng, Q. Synthesis and properties of cyano-bridged nickel(II)-iron(III) complexes. Transition Met Chem 21, 181–183 (1996). https://doi.org/10.1007/BF00136552

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  • DOI: https://doi.org/10.1007/BF00136552

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