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Tetrathiomolybdates of nickel

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Summary

The complexes [Ni(en)3]MoS4, [Ni(dien)2]MoS4 and [Ni(phen)2(MoS4)]·2H2O (en = ethylenediamine, dien = diethylenetriamine, phen = 1,10-phenanthroline) were prepared. On the basis of their magnetochemical and spectral properties the compounds can be characterized as octahedral nickel(II) complexes. The complexes were also studied by c.v. Chemical oxidation of [Ni(en)3]MoS4 affords [Ni(en)MoS4]2SO4; this complex has been characterized by i.r. and e.p.r. spectroscopy and by magnetic measurements.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Palacký University, Krizkovxkeho 10, 771 47, Olomouc, Czech Republic

    Frantisek Brezina, Pavel Kopel, Zdenek Sindelar & Richard Pastorek

  2. Institute of Chemistry, University of Wroclaw, 50-383, Wroclaw, Poland

    Jerzy Mrozinski

Authors
  1. Frantisek Brezina
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  2. Pavel Kopel
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  3. Zdenek Sindelar
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  4. Richard Pastorek
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  5. Jerzy Mrozinski
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Brezina, F., Kopel, P., Sindelar, Z. et al. Tetrathiomolybdates of nickel. Transition Met Chem 20, 56–58 (1995). https://doi.org/10.1007/BF00135402

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  • DOI: https://doi.org/10.1007/BF00135402

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