Abstract
Consideration of sources and growth dynamics of aerosols has led to the conclusion that there may be a distribution or variation of chemical composition and physical structure among atmospheric aerosol particles as a function of size, and within a narrow size range as well. A mathematical representation of these particle properties in terms of an additional dimension to the number size distribution is described. Examples of the relevance of this aspect of aerosol characterization for physical and chemical processes in the atmosphere are discussed. A review of the available techniques shows that several methods are available which can and have provided quantitative results on the distribution of particle properties. Examples of data from the literature have been selected and are presented as three-dimensional distributions illustrating the wide range of particle properties which may exist in narrow size intervals. An evaluation of these results reiterates the value of taking the distribution of particle properties in the atmosphere into account for sampling and modeling purposes.
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References
Ahlberg, M. S. and Winchester, J. W., 1978, Dependence of aerosol sulfur particle size on relative humidity, Atmos. Environ. 12, 1631–1632.
Appel, B. R., Kothney, E., Hoffer, E. M., and Wesoloski, J. J., 1980, Sulfate and nitrate data from the California aerosol experiment (ACHEX), Adv. Environ. Sci. Technol. 10, 315–321.
Artaxo, P., Maenhaut, W., Storms, H., and van Grieken, R., 1989, Aerosol characteristics and sources for the Amazon Basin during the wet season (submitted to J. Geophys. Res.).
Ayers, G. P., 1978, Quantitative determination of sulfate in individual aerosol particles, Atmos. Environ. 12, 1613–1621.
Covert, D. S., Waggoner, A. P., Weiss, R. E., Ahlquist, N. C., and Charlson, R. J., 1980, Atmospheric aerosols, humidity, and visibility, in G. M. Hidy, P. K. Mueller, D. Grosiean, B. R. Appel, and J. J. Wosolowski (eds.), The Character and Origin of Smog Aerosols, Wiley, New York, pp. 559–581.
Covert, D. S., Hansson, H.-C., and Heintzenberg, J., 1987, Hygroscopic and thermal properties of aerosols, preprint volume, 1987, Annual Meeting of the American Association for Aerosol Research.
Covert, D. S. and Heintzenberg, J., 1984, Measurements of the degree of internal/external mixing of hygroscopic compounds and soot in atmospheric aerosols, Sci. Total Environ. 36, 347–352.
Covert, D. S., Heintzenberg, J., and Hansson, H.-C., 1990, Electro-optical detection of external mixtures in aerosols, Aerosol Sci. Technol. (in press).
Ferek, R. J., Lazrus, A. L., and Winchester, J. W., 1983, Electron microscopy of acidic aerosols collected over the northeastern United States, Atmos. Environ. 17, 1545–1561.
Finlayson-Pitts, B. J. and Pitts, J. N.Jr., 1986, Atmospheric Chemistry, Wiley-Interscience, New York.
Friedlander, S. K., 1977, Smoke, dust and haze, Wiley, New York, p. 14.
Hänel, G., 1976, The properties of atmospheric aerosol particles as functions of the relative humidity at thermodynamic equilibrium with the surrounding moist air, Adv. Geophys. 19, 74–188.
Heintzenberg, J., 1978, Light scattering parameters of internal and external mixtures of soot and nonabsorbing material in atmospheric aerosols, Proc. Conference on Carbonaceous Particles in the Atmosphere, CONF-7803101, Berkeley, CA. pp. 278–281.
Heintzenberg, J., 1989, Fine particles in the global troposphere, Tellus 41B, 149–160.
Heintzenberg, J. and Covert, D. S., 1987, Chemically resolved submicrometric size distribution and external mixing of the Arctic haze aerosols, Tellus 39B, 374–382.
Jaenicke, R., 1978, Physical properties of atmospheric particulate sulfur compounds, Atmos. Environ. 12, 161–169.
Jensen, J., and Charlson, R., 1984, On the efficiency of nucleation scavenging, Tellus 36B, 367–375.
Junge, C., 1950, Das Wachstum der Kondensationskerne mit der relativen Feuchtigkeit, Annalen der Meteorologie 3, 129–135.
Lodge, J. P., 1986, Chemical identification of individual particles, in K. R. Spurny (ed.), Physical and Chemical Characterization of Individual Airborne Particles, Wiley, Chichester, pp. 116–126.
McMurry, P. H. and Stolzenburg, M. R., 1989, On the sensitivity of particle size to relative humidity for Los Angeles aerosols, Atmos. Environ. 23, 497–507.
Mossop, S. C., 1963, Stratospheric particles at 20 km, Nature 199, 325–326.
Okada, K., 1983, Nature of individual hygroscopic particles in the urban atmosphere, J. Met. Soc. Japan 61, 727–736.
Okada, K., Iwasaka, Y., and Ono, A., 1985, Features of aerosol particles in the remote oceanic atmosphere, Memoirs of the National Institute of Polar Research, Special Issue No. 39, pp. 30–40.
Post, J. E. and Buseck, P. R., 1984, Characterization of individual particles in the Phoenix urban aerosol using electron-beam instruments, Env. Sci. Technol. 18, 35–42.
Pruppacher, H. R. and Klett, J. D., 1978, Microphysics of Clouds and Precipitation, D. Reidel, Dordrecht.
Rader, D. and McMurry, P., 1986, Application of the tandem differential mobility analyzer to studies of droplet growth or evaporation, J. Aerosol. Sci. 17, 771–787.
Rood, M. J., 1985, On the metastability of atmospheric aerosols, PhD Dissertation, University of Washington.
Saucy, D. A., Anderson, J. R., and Buseck, P. R., 1987, Cluster analysis applied to atmospheric aerosol sample from the Norwegian Arctic, Atmos. Environ. 21, 1649–1657.
Seinfeld, J., 1986, Atmospheric Chemistry and Physics of Air Pollution, Wiley, New York.
Stelson, A. W. and Seinfeld, J. H., 1982, Thermodynamic predictions of the water activity, NH4NO3 dissociation constant, density and refractive index for the NH4NO3−(NH4)2SO4−H2O system at 25°C, Atmos. Environ. 16, 2507–2514.
Van Dyck, P., Storms, H., Van Grieken, R., and Maenhaut, W., 1984, Automated quantitative electron microprobe analysis of particulate material, J. Physique Orsay, Fr. C2, 45, 781–784.
Wendling, P., Wendling, R., Renger, W., Covert, D. S., Heintzenberg, J., and Moerl, P., 1985, Calculated radiative effects of Arctic haze during a pollution episode in spring 1983 based groundbased and airborne measurements, Atmos. Environ. 19, 2181–2193.
Winkler, P., 1973, The growth of atmospheric aerosol particles as a function of the relative humidity — II. An improved concept of mixed nuclei, J. Aerosol Sci. 4, 373–387.
Wu, P.-M. and Ono, A., 1988, X-ray spectrometry of individual nitrate-containing particles, J. Met. Soc. Japan 66, 155–165.
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Heintzenberg, J., Covert, D.S. On the distribution of physical and chemical particle properties in the atmospheric aerosol. J Atmos Chem 10, 383–397 (1990). https://doi.org/10.1007/BF00115781
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DOI: https://doi.org/10.1007/BF00115781