Abstract
The concentrations of7Be,210Pb and major ions have been measured in acrosol and snow samples collected near Summit, Greenland (72°20′N, 38°45′W) in the summers of 1989 and 1990. Comparison to previous results from free tropospheric sampling of the North American Arctic indicates that some acrosol-associated species are as much as 50% depleted in near surface air over the Greenland Ice Sheet. It is shown that local atmospheric processes, particularly isolation of air masses beneath a near surface inversion, can exert dominant influence on the chemistry of surface-level air. These findings illustrate the extreme caution that must be taken if the results of surface-based atmospheric sampling are to be used to examine the relationship between the chemistry of the atmosphere and snow falling from it.
Depth profiles of7Be in the surface layers of the snowpack near Summit suggest that up to half of the annual accumulation of snow may occur in the two to three month late spring-early summer period. If this is generally true for the Summit region, previous regional studies of snow chemistry that assumed linear dependence of age on depth to convert depth profiles to time series will have to be reassesed. However, spatial heterogeneity of near surface snow chemistry, that is currently not well understood, makes interpretation of the7Be profiles tentative at present.
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References
Borys, R. D., 1983, Snow crystal riming and arctic snowpack chemical composition, inPrecipitation Scavenging, Dry Deposition, and Resuspension, vol. 2, Proceedings of the Fourth International Conference, Santa Monica, California, 29 November–3 December, 1982, 1281–1288.
Brock C. A., L. F. Radke, J. H. Lyons and P. V. Hobbs, 1989, Arctic hazes in summer over Greenland and the North American Arctic. I: Incidence and origin.J. Atmos. Chem. 9, 129–148.
Canuel E. A., C. S. Martens, and L. K. Benninger, 1990. Seasonal variations in7Be activity in sediments of Cape Lookout Bight, North Carolina,Geochim. Cosmochim. Acta. 54, 237–245.
Davidson C. I., S. Santhanam, R. C. Fortmann and M. P. Olson, 1985. Atmospheric transport and deposition of trace elements onto the Greenland Ice Sheet.Atmos. Environ.,19, 2065–2081.
Davidson C. I., R. E. Honrath, J. B. Kadane, R. S. Tsay, P. A. Mayewski, W. B. Lyons and N. Z. Heidam, 1987. The seavenging of atmospheric sulfate by Arctic snow,Atmos. Environ.,21, 871–882.
Davidson C. I., J. R. Harrington, M. J. Stephenson, M. J. Small, F. P. Boscoe and R. E. Gandley, 1989. Seasonal variations in sulfate, nitrate, and chloride in the Greenland Ice Sheet: Relation to atmospheric concentrations,Atmos. Environ.,23, 2483–2494.
Dick A. L., and D. A. Peel, 1985. Trace elements in Antarctic air and snowfall.Annals Glaciol.,7, 12–19.
Dibb J. E., 1990. Beryllium-7 and Lead-210 in the atmosphere and surface snow over the Greenland Ice Sheet in the summer of 1989.J. Geophys. Res.,95, 22407–22415.
Dibb J. E., and D. L. Rice, 1989. Temporal and spatial distribution of beryllium-7 in the sediments of Chesapeake Bay.Est. Coast. Shelf Sci.,28, 395–406.
Dibb, J. E., and J.-L. Jaffrezo, in review, Beryllium-7 and Lead-210 in acrosol and snow in the Dye 3 gas, acrosol and snow sampling program, submitted to Atmospheric Environment for inclusion in the special issue on AGASP 3 and DGASP.
Dibb, J. E., R. W. Talbot, and G. L. Gregory, in review,7Be and210Pb in the western hemisphere Arctic atmosphere: Observations from three recent aircraft-based sampling programs, submitted to J. Geophys. Res. for inclusion in the special issue on NASA GTE ABLE 3A.
Fenn R. W., H. E. Gerber, and D. Wasshausen, 1963. Measurements of the sulphur and ammonium component of the Arctic acrsol of the Greenland Icecap.J. Atmos. Sci. 20, 466–468.
Hodge S. M., D. L. Wright, J. A. Bradley, R. W. Jacobel, N. Skou, and B. Vaughn, 1990. Determination of the surface and bed topography in central Greenland.J. Glaciol. 36, 17–30.
Hogan A. W., S. C. Barnard, K. Kebschull, R. Townsend and J. A. Samson, 1984. Acrosol variation in the western hemisphere Arctic,J. Acrosol Sci.,15, 13–33.
IGBP. 1990, The International Geosphere-Biosphere Programme: A study of global change (IGBP) of the International Council of Scientific Unions (ICSU), Report number 12.
Lambert, G., B. Ardouin and A. Mesbah-Bendezu, 1983, Atmosphere to snow transfers in Antarctica, inPrecipitation Scavenging, Dry Deposition, and Resuspension, vol. 2, Proceedings of the Fourth International Conference, Santa Monica, California, 29 November-3 December, 1982, 1289–1300.
Legrand M. R., and R. J. Delmas, 1988. Formation of HCl in the Antarctic atmosphere.J. Geophys. Res.,93, 7153–7168.
Mickle R. E., J. W. Bottenheim, W. R. Leaitch and W. Evans, 1989. Boundary layer ozone depletion during AGASP-II,Atmos. Environ. 23, 2443–2449.
Ng A., and C. C. Patterson, 1981. Natural concentration of lead in ancient Arctic and Antarctic ice.Geochim. Cosmochim. Acta. 45, 2109–2121.
Oltmans S. J., R. C. Schnell, P. J. Sheridan, R. E. Peterson, S.-M. Li, J. W. Winchester, P. P. Tans, W. T. Sturges, J. D. Kahl and L. A. Barric, 1989. Seasonal surface ozone and filterable bromine relationship in the high Arctic.Atmos. Environ. 23, 2431–2441.
Peel D. A., and E. W. Wolff, 1982. Recent variations in heavy metal concentrations in air and firn from the Antarctic Peninsula.Annals Glaciol.,3, 255–259.
Rahn K. A., and R. J. McCaffrey, 1979. Compositional differences between Arctic acrosol and snow.Nature,280, 479–480.
Rama, 1963. Atmospheric circulation from observations of natural radioactivity.J. Geophys. Res. 68, 3861–3866.
Rice D. L., 1986. Early diagenesis in bioadvective sediments: Relationships between the diagenesis of beryllium-7, sediment reworking rates, and the abundance of conveyor-belt deposit-feeders,J. Mar. Res.,44, 149–184.
Sanak J., G. Lambert and B. Ardouin, 1985. Measurement of stratosphere-to-troposphere exchange in Antarctica by using short-lived cosmonuclides.Tellus,37B, 109–115.
Talbot R. W., R. C. Harriss, E. V. Browell, G. L. Grefory, D. I. Sebacher, and S. M. Beck, 1986, Distribution and geochemistry of acrosols in the tropical North Atlantic troposphere: relationship to Saharan dust.J. Geophys. Res.,91, 5173–5182.
Talbot, R. W., A. S. Vijgen and R. C. Harriss, in press, Soluble species in the Arctic summer troposphere: Acidic gases, acrosols and precipitation, will appear in J. Geophys. Res.
Wagenbach D., U. Görlach, K. Moser and K. O. Münnich, 1988. Coastal Antarctic acrosol: the seasonal pattern of its chemical composition and radionuclide content.Tellus,40B, 426–436.
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Dibb, J.E., Jaffrezo, J.L. & Legrand, M. Initial findings of recent investigations of air-snow relationships in the summit region of the Greenland ice sheet. J Atmos Chem 14, 167–180 (1992). https://doi.org/10.1007/BF00115232
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DOI: https://doi.org/10.1007/BF00115232