Abstract
A 1-D model of the formation and seasonal evolution of Polar Stratospheric Clouds (PSCs) is described. The model considers PSCs of types 1 and 2 in the vertical range from 8 to 30 km and utilizes real temperature data. The micro-physical processes included in the model are the heterogeneous nucleation and condensation (or evaporation), while sedimentation, gas diffusion and vertical wind velocity are the processes responsible for transport. Model simulations have been compared with PSC data obtained by lidar at the South Pole: results for the winter 1990 are discussed. The different contribution of type 1 and type 2 PSCs to the measured backscattering coefficient has been evidenced. In the simulations, layers of NAT particles form when low values of the backscattering coefficient are measured; similarly, ice particles form when sharper and rapidly changeable structures with higher values of the backscattering coefficient are observed. Significant results on the condensation and depletion of HNO3 and H2O are presented. Water vapor profiles measured during winter 1990 are reproduced quite well.
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Adamson, A. W., 1990, Physical Chemistry of Surfaces, 5th edn., Wiley-Interscience, New York.
Arnold, F., Petzoldt, K., and Reimer, E., 1992, On the formation and sedimentation of stratospheric nitric aerosols: implications for polar ozone destruction, Geophys. Res. Lett. 19, 667–680.
Brasseur, G., Hitchman, M. H., Walters, S., Dymek, M., Falise, E., and Pirre, M., 1990, An interactive chemical dynamic radiative 2-dimensional model of the middle atmosphere, J. Geophys. Res. 95, 5639–5655.
Cacciani, M., Fiocco, G., Colagrande, P., Di Girolamo, P., di Sarra, A., and Fuà, D., 1995, Polar Stratospheric Clouds at the South Pole during 1990, J. Geophys. Res. (submitted).
Collins, R. L., Bowman, K. P., and Gardner, C. S., 1993, Polar Stratospheric Clouds at the South Pole 1990: Lidar observations and analysis, J. Geophys. Res. 98, 1001–1010.
Crutzen, P. J. and Arnold, F., 1986, Odd nitrogen incorporation in polar stratospheric clouds: a possible major cause for the springtime ozone decay in Antarctica, Nature 324, 651–655.
Drdla, K. and Turco, R. P., 1991, Denitrification through PSC formation: a 1-D model incorporating temperature oscillations, J. Atmos. Chem. 12, 319–366.
Drdla, K., Turco, R. P., and Elliott, S., 1993, Heterogeneous chemistry on Antarctic Polar Stratospheric Clouds: a microphysical estimate of the extent of chemical processing, J. Geophys. Res. 98, 8965–8981.
Dye, J. E., Baumgardner, D., Gandrud, B. W., Kawa, S. R., Kelly, K. K., Loewenstein, M., Ferry, G. V., Chan, K. R., and Gary, B. L., 1992, Particle size distributions in Arctic polar stratospheric clouds, growth and freezing of sulfuric acid droplets, and implications for clouds formation, J. Geophys. Res. 17, 413–416.
Fahey, D. W., Kelly, K. K., Ferry, G. V., Poole, L. R., Wilson, J. C., Murphy, D. M., Loewenstein, M., and Chan, K. R., 1989, In situ measurements of total reactive nitrogen, total water, and aerosol in a polar stratospheric cloud in the Antarctic, J. Geophys. Res. 94, 299–315.
Fiocco, G., Cacciani, M., Di Girolamo, P., Fuà, D., and De Luisi, J., 1992, Stratospheric clouds at South Pole during 1988: results of Lidar observations and their relationship to temperature, J. Geophys. Res. 97, 5939–5946.
Fuà, D., Cacciani, M., Di Girolamo, P., Fiocco, G., and di Sarra, A., 1992, Stratospheric clouds at South Pole during 1988: their evolution in relation to atmospheric structure and composition, J. Geophys. Res. 97, 5947–5952.
Granier, C. and Brasseur, G., 1991, Ozone and other trace gases in the Arctic and Antarctic regions: three dimensional model simulations, J. Geophys. Res. 96, 2995–3011.
Hamill, P., Kiang, C. S., and Cadle, R. D., 1976, The nucleation of H2SO4 * H2O solution aerosol particles in the stratosphere, J. Atmos. Sci. 34, 150–162.
Hamill, P., Turco, R. P., Kiang, C. S., Toon, O. B., and Whitten, R. C., 1982, An analysis of various nucleation mechanism for sulfate particles in the stratosphere, J. Aerosol. Sci. 13, 561–585.
Hamill, P., Turco, R. P., and Toon, O. B., 1988, On the growth of nitric and sulfuric acid aerosol particles under stratospheric conditions, J. Atmos. Chem. 7, 287–315.
Hamill, P., Toon, O. B., and Turco, R. P., 1990, Aerosol nucleation in the winter Arctic and Antarctic stratosphere, Geophys. Res. Lett. 17, 417–420.
Hanson, D. and Mauersberger, K., 1988, Laboratory studies of the nitric acid trihidrate: implications for the south polar stratosphere, Geophys. Res. Lett. 15, 855–858.
Hofmann, D. J., Rosen, J. M., Harder, J. W., and Hereford, J. V., 1989, Balloon-borne measurements of aerosol, condensation nuclei, and cloud particles in the stratosphere at McMurdo station, Antarctica, during spring of 1987, J. Geophys. Res. 94, 11,253–11,269.
Hofmann, D. J., Oltmans, S. J., and Deshler, T., 1991, Simultaneous balloon borne measurements of stratospheric water vapor and ozone in the polar regions, Geophys. Res. Lett. 18, 1011–1014.
Hofmann, D. J. and Deshler, T., 1991, Stratospheric cloud observations during formation of the Antarctic ozone hole in 1989, J. Geophys. Res. 96, 2897–2912.
Kelly, K. K., Tuck, A. F., Heidt, L. E., Loewenstein, M., Podolske, J. R., Strahan, S. E., and Vedder, J. F., 1990, A comparison of ER-2 measurements of stratospheric water vapor between the 1987 Antarctic and 1989 Arctic Airborne Mission, Geophys. Res. Lett. 17, 465–468.
Kent, G. S., Poole, L. R., and McCormick, M. P., 1986, Characteristic of Arctic polar stratospheric clouds as measured by airborne Lidar, J. Atmos. Sci. 43, 2149.
Larsen, N., 1991, Simulation model for the formation of polar stratospheric clouds, DMI Scientific Report, 91-2.
Marti, J. and Mauersberger, K., 1993, A survey and new measurements of ice vapor pressure at temperatures between 170 K and 250 K, Geophys. Res. Lett. 20, 363–366.
McCormick, M. P., Steele, H. M., Hamill, P., Chu, W. P., and Swissler, T. J., 1982, Polar stratospheric clouds sightings by SAM II, J. Atmos. Sci. 39, 1387–1397.
McCormick, M. P. and Trepte, C. R., 1987, Polar stratospheric optical depth observed between 1978 and 1985, J. Geophys. Res. 92, 4297–4307.
Middlebrook, A. M., Berland, B. S., George, S. M., and Tolbert, M. A., 1994, Real refractive indices of infrared-characterized nitric-acid/ice films: Implications for optical measurements of polar stratospheric clouds, J. Geophys. Res. 99, 25655–25666.
Poole, L. R. and McCormick, M. P., 1988, Polar stratospheric clouds and the Antarctic ozone hole, J. Geophys. Res. 93, 8423–8430.
Pruppacher, H. R. and Klett, J. D., 1980, Microphysics of Clouds and Precipitation, 2nd edn., Reidel Publishing Company, Dordrecht.
Pueschel, R. F., Ferry, G. V., Snetsinger, K. G., Goodman, J., Dye, J. E., Baumgardner, D., and Gandrud, B. W., 1992, A case of type 1 polar stratospheric cloud formation by heterogeneous nucleation, J. Geophys. Res. 97, 8105–8114.
Rizi, V., 1991, Influenza degli aerosol stratosferici sull'ozono ed osservazioni Lidar, Ph.D. Thesis, Università de l'Aquila, Italy.
Rood, B. R., 1987, Numerical advection algorithms and their role in atmospheric transport and chemistry, Rev. Geophys. 25, 71–100.
Rosen, J. M., Kjome, N. T., and Oltmans, S. J., 1991, Balloon borne observations of backscatter, frost point and ozone in polar stratospheric clouds at the South Pole, Geophys. Res. Lett. 18, 171–174.
Schoeberl, M. R. and Hartmann, D. L., 1991, The dynamics of the stratospheric polar vortex and its relation to springtime ozone depletions, Science 251, 46–52.
Solomon, S., 1988, The mystery of the Antarctic ozone hole, Rev. Geophys. 26, 131–148.
Steele, H. M., Hamill, P., McCormick, M. P., and Swissler, T. J., 1983, The formation of polar stratospheric clouds, J. Atmos. Sci. 40, 2055–2067.
Steele, H. M. and Hamill, P., 1981, Effects of temperature and humidity on the growth and optical properties of sulfuric acid-water droplets in the stratosphere, J. Atmos. Sci. 12, 517–528.
Toon, O. B., Hamill, P., Turco, R. P., and Pinto, J., 1986, Condensation of HNO3 and HCl in the winter polar stratosphere, Geophys. Res. Lett. 13, 1284–1287.
Toon, O. B., Turco, R. P., Jordan, J., Goodman, J., and Ferry, G., 1989, Physical processes in polar stratospheric ice clouds, J. Geophys. Res. 94, 11359–11380.
Toon, O. B., Browell, E. V., Kinne, S., and Jordan, J., 1990, An analysis of lidar observations of polar stratospheric clouds, Geophys. Res. Lett. 17, 393–396.
Wofsy, S. C., Gobbi, G. P., Salawitch, R. J., and McElroy, M. B., 1990, Nucleation and growth of HNO3 · H2O particles in the polar stratospheres, J. Atmos. Sci. 47, 16.
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Panegrossi, G., Fuà, D. & Fiocco, G. A 1-D model of the formation and evolution of Polar Stratospheric Clouds. J Atmos Chem 23, 5–35 (1996). https://doi.org/10.1007/BF00058702
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DOI: https://doi.org/10.1007/BF00058702