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Starch-based extruded plastic films and evaluation of their biodegradable properties

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Abstract

Plastic formulations containing up to 40% starch were prepared and blown into thin films using extrusion methods. Extruded films were evaluated for their biodegradability by exposing them to a consortium of starch degrading bacteria in the laboratory for 45 days and in the ‘La Silla’ river located in Monterrey, N.L. Mexico for up to 60 days. Biodegradability was assessed by measuring changes in weight loss and chemical composition of the films using Fourier transform infrared (FTIR) spectroscopy. While little or no degradation was apparent in control films made up of 100% low density polyethylene (LDPE) or 100% poly-(ethylene-co-acrylic acid) (EAA), most of the starch was depleted in starch-containing films exposed in the river. Starch degradation in films exposed to amylolytic bacteria in the laboratory was relatively slower. Also, increasing the amount of EAA from 25% to 50% substantially reduced starch depletion in these films.

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Abbreviations

FTIR:

Fourier transform infrared

LDPE:

low density poly-(ethylene)

EAA:

poly-(ethyleneco-acrylic acid)

SEM:

Scanning electron microscopy

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The mention of firms names or trade products does not imply that they are endorsed or recommended by the U. S. Department of Agriculture over the firms or similar products not mentioned. All programs and services of the U. S. Department of Agriculture are offered on a nondiscriminatory basis without regard to race, color, national origin, religion, sex, marital status, or handicap.

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Arévalo-Niño, K., Sandoval, C.F., Galan, L.J. et al. Starch-based extruded plastic films and evaluation of their biodegradable properties. Biodegradation 7, 231–237 (1996). https://doi.org/10.1007/BF00058182

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