Abstract
The modelling of twins in crystals with strain gradient theories provides interesting problems both in thermodynamics and in the calculus of variations. Here, Dunn and Serrin's thermomechanical theory of interstitial working is used to obtain a variational principle that governs the equilibria of materials with non-convex Helmholtz free energy. In some geometries, this principle reduces to a novel calculus of variations problem; an example is described in which symmetry-related uniform equilibrium states can be connected by nonconstant extremals which realiselocal minima of the free energy. Certain implications of different definitions of local minima are also discussed.
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Maddocks, J.H., Parry, G.P. A model for twinning. J Elasticity 16, 113–133 (1986). https://doi.org/10.1007/BF00043580
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DOI: https://doi.org/10.1007/BF00043580