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Chemical and isotopic composition of karstic lakes in Jamaica, West Indies

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Abstract

Lakes in the limestone region of Jamaica exhibit a range of chemical characteristics that reflect varying inputs from precipitation, surface runoff and groundwater, together with the subsequent evolution of the water within the limnic environment. Detailed spatial and temporal sampling was conducted on one lake, Wallywash Great Pond. Chemical data, together with D/H, 18O/16O, 13C/12C and 87Sr/86Sr ratios confirm that the karstic spring waters entering the lake evolve chemically through degassing, mixing with rainfall and runoff, biogenic decalcification (resulting mainly from bicarbonate assimilation by the high biomass of submerged macrophytes), and evaporation. Modern carbonate sedimentation in Wallywash Great Pond is largely of high-Mg calcite. This is consistent with Mg/Ca molar ratios >2 within much of the lake. However, aragonite forms on the adaxial leaf surfaces of Potamogeton spp. This may be explained either as a result of locally elevated Mg concentrations or a high degree of supersaturation favouring very rapid carbonate precipitation. Two small lakes to the north of Wallywash Great Pond show minor influence of the Na-Cl dominated coastal aquifer, suggesting that coastal lakes are sensitive to variations in the boundary between fresh and brackish groundwater caused by changes in climate or sea level. Their 13C/12C ratios are strongly influenced by biogenic CO2 derived from plant respiration or decay.

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Authors and Affiliations

  1. School of Geography, Kingston University, Penrhyn Road, KT1 2EE, Kingston upon Thames, Surrey, UK

    J. A. Holmes

  2. Tropical Palaeoenvironments Research Group, Environmental Change Unit and School of Geography, University of Oxford, Mansfield Road, OX1 3TB, Oxford, UK

    F. A. Street-Perrott

  3. N.E.R.C., Isotope Geosciences Laboratory, Kingsley Dunham Centre, NG12 5GG, Keyworth, Nottingham, UK

    T. H. E. Heaton & D. P. F. Darbyshire

  4. The Wellcome Centre for Medical Science, 210 Euston Road, NW1 2BE, London, UK

    N. C. Davies

  5. Tropical Palaeoenvironments Research Group, School of Geography, University of Oxford, Mansfield Road, OX1 3TB, Oxford, UK

    P. E. Hales

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  3. T. H. E. Heaton
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  4. D. P. F. Darbyshire
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Holmes, J.A., Street-Perrott, F.A., Heaton, T.H.E. et al. Chemical and isotopic composition of karstic lakes in Jamaica, West Indies. Hydrobiologia 312, 121–138 (1995). https://doi.org/10.1007/BF00020768

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  • DOI: https://doi.org/10.1007/BF00020768

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