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Journal of the Australian Ceramic Society

, Volume 55, Issue 1, pp 25–36 | Cite as

Synthesis, morphology, structural, and rheological studies of Fe0.01Al0.5La.0.01Zn0.98O-based polyaniline composite materials

  • M. SohailEmail author
  • M. Saleem Khan
  • Muhammad Omer
  • Ihsan Ullah Marwat
  • Noor Saeed Khattak
  • Sana Ullah Khan
  • Zakir Ullah
  • Sami Ur Rahman
Research
  • 24 Downloads

Abstract

In the present study, mixed-metal ceramic Fe0.01Al0.5La.0.01Zn0.98O particles and their composites with polyaniline (PANI) were prepared via sol-gel and in situ free-radical polymerization techniques, respectively. Particles and composite formation was confirmed by FT-IR spectroscopy. SEM studies showed the Fe0.01Al0.5La.0.01Zn0.98O particle’s homogeneous dispersion in the polymer matrix. Ceramic particles were found to be in microdimensions. XRD analysis confirmed crystallite size in the range from 22 to 28 nm. Extensive rheological characterization was performed to check the durability of the materials for possible applications. Flow-curve tests suggested that the prepared materials are non-Newtonian (shear thinning) in nature. Increasing temperature have no appreciable effect on the viscosity which confirmed the mechanical stability of the materials. Based on frequency sweep test findings, the mechanical rigidity of the polymer has been enhanced (G′ = 2 × 102−5.22 × 103 Pa) by the introduction of ceramic particles. Conversely, creep compliance has been decreased considerably.

Keywords

PANI composite XRD Rheology 

Notes

Acknowledgements

Mr. Majid Khan and Mr. Muhammad Irfan are also acknowledged for their support during the completion of this project.

Funding information

The authors are thankful to the National Centre of Excellence in Physical Chemistry, University of Peshawar for financial support and to the University of Swat for providing a place to conduct this research work.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Australian Ceramic Society 2018

Authors and Affiliations

  • M. Sohail
    • 1
    Email author
  • M. Saleem Khan
    • 2
  • Muhammad Omer
    • 1
  • Ihsan Ullah Marwat
    • 1
  • Noor Saeed Khattak
    • 3
  • Sana Ullah Khan
    • 4
  • Zakir Ullah
    • 5
  • Sami Ur Rahman
    • 2
  1. 1.Institute of Chemical SciencesUniversity of SwatMingoraPakistan
  2. 2.National Center of Excellence in Physical ChemistryUniversity of PeshawarPeshawarPakistan
  3. 3.Center for Material SciencesIslamia College UniversityPeshawarPakistan
  4. 4.Department of ChemistryWomen University SwabiSwabiPakistan
  5. 5.Department of PhysicsUniversity of MalakandLower DirPakistan

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