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Adsorption of Crystal Violet and Methylene Blue on Azolla and Fig Leaves Modified with Magnetite Iron Oxide Nanoparticles

  • Nina Alizadeh
  • Shahab Shariati
  • Naereh Besharati
Research paper

Abstract

This study was focused on the adsorption of Crystal violet and Methylene blue as cationic dyes on the surface of magnetite nanoparticles loaded Fig leaves (MNLFL) and magnetite nanoparticles loaded Azolla (MNLA) as natural cheap sources of adsorbents. MNLFL and MNLA were prepared with chemical precipitation method and they were characterized with Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. Different parameters affecting the dyes removal efficiency such as contact time, pH of solution, and amount of adsorbents were optimized. Dyes adsorption process was studied from both kinetic and equilibrium point. The kinetic of adsorption was tested for pseudo-first-order, pseudo-second-order, intraparticle diffusion, and Elovich models. At optimum conditions, the sorption of the Crystal violet and Methylene blue on the surface of MNLFL and MNLA adsorbents was best described by a pseudo-second-order kinetic model. Equilibrium data were fitted better to the Langmuir isotherm more than Freundlich and Temkin isotherm. The synthesized sorbent showed complete Crystal violet removal with sorption capacity equal to 53.47 mg g−1 for MNLFL and 30.21 mg g−1 for MNLA and complete Methylene blue removal with sorption capacity equal to 61.72 mg g−1 for MNLFL and 25 mg g−1 for MNLA, respectively. The results showed that MNLFL and MNLA can be used as efficient adsorbents for removal of Crystal violet and Methylene blue from aqueous solutions.

Keywords

Crystal violet Methylene blue Fig leave Azolla Magnetic nanoparticles 

Abbreviations

MNLFL

Magnetite nanoparticles loaded Fig leave

MNLA

Magnetite nanoparticles loaded Azolla

CV

Crystal violet

MB

Methylene blue

List of symbols

qe

Equilibrium dye concentration on the adsorbent

Ce

Equilibrium dye concentration in the solution

qmax

Monolayer capacity of the adsorbent

KL

Langmuir constant

KF

Freundlich constant

N

Degree of nonlinearity of adsorption

Notes

Acknowledgements

The author would like to acknowledge University of Guilan and Dr Nina Alizadeh and Dr Shahab Shariati at the Azad University of Rasht.

Compliance with Ethical Standards

Conflict of interest

No competing financial interests exist.

References

  1. Akinola LK, Umar AM (2015) Adsorption of crystal violet onto adsorbents derived from agricultural wastes: kinetic and equilibrium studies. J Appl Sci Environ Manag 19:279–288Google Scholar
  2. Ali I, Gupta VK (2007) Advances in water treatment by adsorption technology. Nat Protoc 1:2661–2667CrossRefGoogle Scholar
  3. Alsenani G (2013) Studies on adsorption of crystal violet dye from aqueous solution onto calligonum comosum leaf powder. J Am Sci 9:8Google Scholar
  4. Annadurai G, Juang RS, Lee DJ (2002) Asorption of heavy metals from water using banana and orang peels. J Hazard Mater 92:263–274CrossRefGoogle Scholar
  5. Belloa OS, Ahmada MA, Ahmada N (2012) Adsorptive features of banana (Musa paradisiaca) stalk-based activated carbon for malachite green dye removal. Chem Ecol 28:153–167CrossRefGoogle Scholar
  6. Benaïssa H (2009) Removal of cadmium Ions by sorption from aqeous solutions using low cost materials. In: 13th International water technology conference IWTC Hurghada Egypt 13Google Scholar
  7. Bhatnagar A, Jain AK (2005) A comparative adsorption study with different industrial wastes as adsorbents for the removal of cationic dyes from water. J Colloid Interface Sci 281:49–55CrossRefGoogle Scholar
  8. Bulut Y, Aydin H (2006) Study of methylene blue adsorption on wheat shell. Desalination 194:25–267CrossRefGoogle Scholar
  9. Bulut Y, Gozubenli NN, Aydin H (2007) Equilibrium and kinetics studies for adsorption of direct blue 71 from aqueous solution by wheat shells. J Hazard Mater 144:300–336CrossRefGoogle Scholar
  10. Chakraborty S, Chowdhury S, Saha PD (2011) Adsorption of crystal violet from aqueous solution onto NaOH-modified rice husk. J Carbohydr Polym 86:1533–1541CrossRefGoogle Scholar
  11. Chen CC, Liao HJ, Cheng CY, Yen CY, Chung YC (2007) Biodegradation of crystal violet by Pseudomonas putida. Biotechnol Lett 29:391–396CrossRefGoogle Scholar
  12. Franca AS, Oliveira LS, Ferreira ME (2009) Kinetics and equilibrium studies of methylene blue adsorption by spent coffee grounds. Desalination 249:267–272CrossRefGoogle Scholar
  13. Gong R, Li M, Yang C, Sun Y, Chen J (2005) Isotherm and kinetics study of biosorption of cationic dye on to banana peel. J Hazard Mater 121:247–250CrossRefGoogle Scholar
  14. Gupta VK, Nayak A (2012) Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe2O3 nanoparticles. J Chem Eng 180:81–90CrossRefGoogle Scholar
  15. Gupta VK, Carrott PJM, Ribeiro Carrott MML, Suhas (2009) Low cost adsorbents: growing approach to wastewater treatment a review. Crit Rev Environ Sci Technol 39:783–842CrossRefGoogle Scholar
  16. Han R, Wang Y, Han P, Shi J, Yang J, Lu Y (2006) Removal of methylene blue from aqueous solution by chaff in batch mode. J Hazard Mater 137:550–557CrossRefGoogle Scholar
  17. Huang CH, Chang KP, Ou HD, Chiang YC, Wang CF (2011) Adsorption of cationic dyes onto mesoporous silica. Microporous Mesoporous Mater 141:102–109CrossRefGoogle Scholar
  18. Kumar R, Ahmad R (2011) Studies on adsorption of crystal violet dye from aqueous solution on to skin almonds. Desalination 26:112–118CrossRefGoogle Scholar
  19. Liu Y, Sun X, Li B (2010) Adsorption of Hg2+ and cd2+ by ethylenediamine modified peanut shell. J Carbohydr Polym 81:335–339CrossRefGoogle Scholar
  20. Madrakian T, Afkhaami A, Ahmadi M (2012) Adsorption and kinetic studies of seven different organic dyes on to magnetite nanoparticles loaded tea waste and removal of them from waste water samples. Spectrochim Acta Mol Biomol Spect 99:102–109CrossRefGoogle Scholar
  21. Mittal A, Kurup L, Mittal J (2007) Freundlich and Langmuir adsorption isotherms and kinetics for the removal of tartrazine from aqueous solutions using hen feathers. J Hazard Mater 146:243–248CrossRefGoogle Scholar
  22. Moeinpour F, Alimoradi A, Kazemi M (2014) Efficient removal of Eriochrome black-T from aqueous solution using NiFe2O4 magnetic nanoparticles. J Environ Health Sci Eng 12:112CrossRefGoogle Scholar
  23. Ncibi MC, Mahjoub B, Seffen M (2007) Sumac leaves as a novel low cost adsorbent for removal of basic dye from aqueous solution. J Hazard Mater 139:280–285CrossRefGoogle Scholar
  24. Oliveira LCA, Rios RV, Fabris JD, Sapag K, Garg VK, Lago RM (2003) Clay–iron oxide magnetic composites for the adsorption of contaminants in water. Appl Clay Sci 22:169–177CrossRefGoogle Scholar
  25. Oliveira LS, Franca AS, Alves TM, Rocha SDF (2008) Evaluation of untreated coffee husks as potential biosorbents for treatment of dye contaminated waters. J Hazard Mater 155:507–512CrossRefGoogle Scholar
  26. Ovaisi F, Nikazar M, Razagi MH (2012) Methods of synthesis and modification of magnetic iron oxide nanoparticles for heavy metals from aqueous solutions. In: National conference about planning of environmental protectionGoogle Scholar
  27. Padmesh TV, Vijayaraghavan K, Sekaran G, Velan M (2005) Batch and column studies on biosorption of acid dyes on fresh water macro alga Azolla filiculoides. J Hazard Mater 125:121–129CrossRefGoogle Scholar
  28. Parsons S (2004) Advanced oxidation processes for water and wastewater. IWA Publishing, LondonGoogle Scholar
  29. Patil S, Deshmukh V, Renukdas S, Patel N (2011) Kinetics of adsorption of crystal violet from aqueous solutions using different natural materials. Int J Environ Sci 1:1116Google Scholar
  30. Pavan FA, Lima EC, Dias SLP, Mazzocato AC (2008) Methylene blue biosorption from aqueous solutions by yellow passion fruit waste. J Hazard Mater 150:703–712CrossRefGoogle Scholar
  31. Robinson T, Chandran B, Nigam P (2002) Removal of dyes from a synthetic textile dye effluent by biosorption on apple pomace and wheat straw. Water Res 36:2824–2830CrossRefGoogle Scholar
  32. Safarik I, Safarikova M (2010) Magnetic fluid modified peanut husks as an adsorbent for organic dyes removal. Phys Proc 9:274–278CrossRefGoogle Scholar
  33. Safarik I, Lunackova P, Mosiniewicz-Szablewska E, Weyda F, Safarikova M (2007) Adsorption of water-soluble organic dyes on ferrofluid modified sawdust. Holzforschung 61:247–253CrossRefGoogle Scholar
  34. Safarik I, Horska K, Svobodova B, Safarikova M (2012) Magnetically modified spent coffee grounds for dyes removal. Eur Food Res Technol 234:345–350CrossRefGoogle Scholar
  35. Serpil O, Fikret K (2006) Utilization of powdered waste sludge (PWS) for removal of textile dyestuffs from wastewater by adsorption. Environ Manag 81:307–314Google Scholar
  36. Shariati S, Faraji M, Yamini Y, Rajabi A (2011) Fe3O4 magnetic nanoparticles modified with sodium dodecyl sulfate for removal of safranin O dye from aqueous solutions. Desalination 270:160–165CrossRefGoogle Scholar
  37. Shariati S, Khabazipour M, Safa F (2016) Synthesis and application of amine functionalized silica mesoporous magnetite nanoparticles for removal of chromium (VI) from aqueous solutions. J Porous Mater 1:11Google Scholar
  38. Singh KP, Gupta S, Singh AK, Sinha S (2011) Optimizing adsorption of crystal violet dye from water. J Hazard Mater 186:1462–1473CrossRefGoogle Scholar
  39. Sulak MT, Demirbas E, Kobya M (2006) Removal of astrazon yellow 7GL from aqueous solutions by adsorption onto wheat bran. Bioresour Technol 98:2590–2598CrossRefGoogle Scholar
  40. Vadivelan V, Kumar KV (2005) Equilibrium, kinetics, mechanism and process design for the sorption of methyleneblue on to rice husk. J Colloid Interface Sci 286:90–100CrossRefGoogle Scholar
  41. Yang N, Zhu S, Zhang D, Xu S (2008) Synthesis and properties of magnetic Fe3O4 activated carbon nanocomposite particles for dye removal. Mater Lett 62:645–647CrossRefGoogle Scholar
  42. Zhang G, Bao Y (2011) Adsorption characteristics of Methylene blue on to activated carbon by salix psammophila. Energy Proc 16:1141Google Scholar

Copyright information

© University of Tehran 2017

Authors and Affiliations

  • Nina Alizadeh
    • 1
  • Shahab Shariati
    • 2
  • Naereh Besharati
    • 1
  1. 1.Department of ChemistryUniversity of GuilanRashtIran
  2. 2.Department of ChemistryRasht Branch, Islamic Azad UniversityRashtIran

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