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Mechanisms of Late Pleistocene authigenic Fe–Mn-carbonate formation at the Laptev Sea continental slope (Siberian Arctic)

  • Elizaveta LogvinaEmail author
  • Alexeу Krylov
  • Еkaterina Taldenkova
  • Valentina Blinova
  • Vladimir Sapega
  • Andrey Novikhin
  • Heidemarie Kassens
  • Henning A. Bauch
Review Article
  • 103 Downloads

Abstract

Study of the microstructure and isotopic composition of authigenic tubule-shaped carbonate concretions from sediment core PS51/154-11 on the western Laptev Sea continental slope (present water depth 270 m) has allowed for reconstruction of the conditions prevailing during their formation and identification of the mechanisms controlling their genesis. Concretions were collected from the basal sediment unit with an extrapolated age estimate of 16.3–17.6 cal.ka. Crystallization of carbonate tubules occurred at the beginning of the last deglaciation when the site was located in the proximity to the former coastline and the mouths of the Olenek and Anabar-Khatanga rivers in water depths of about 150–170 m. Microprobe analysis showed that the studied carbonate tubules consist of the minerals belonging to the siderite–rhodochrosite isomorphic series. The measured isotopic composition of δ13С and δ18O in the carbonates varies between − 21.0 and − 17.0‰ and between − 9.86 and 1.72‰ VPDB, respectively. The δ18O values in the authigenic carbonates give evidence for the gradual transition from a freshwater affected to modern-like marine sedimentation environment during carbonate crystallization. Water freshening is confirmed by the co-occurrence of authigenic Fe–Mn carbonates and Fe-phosphate vivianite that is a typical mineral of freshwater environments. The dominant source of dissolved inorganic carbon in the pore water was the isotopically light carbon derived from the diagenetic decomposition of organic matter. Two possible scenarios of authigenic carbonates formation are proposed: penetration of freshened ground waters and/or enhanced freshwater influence during short seasonal floods in combination with geochemical processes in a narrow marginal filter zone that was located extremely close to the Laptev Sea continental slope and the studied core site.

Keywords

Authigenic carbonates Carbon and oxygen stable isotopes Early diagenesis Oxidation of organic matter (OM) Laptev Sea Late Pleistocene 

Notes

Acknowledgements

We thank two anonymous reviewers whose comments helped to significantly improve this manuscript. This research is partly supported by the Russian Foundation for Basic Research, project 16-05-00979, and System Laptev Sea: The Transpolar System of the Arctic Ocean (TRANSDRIFT; 03G0833) funded by BMBF. It is also a contribution to the Russian–German joint research project “Changing Arctic Transpolar System” (CATS) funded by the Russian and German ministries for science and education.

Compliance with ethical standards

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.I.S.Gramberg All-Russian Research Institute of Geology and Mineral Resources of the World Ocean (VNIIOkeangeologia)St. PetersburgRussia
  2. 2.Institute of Earth SciencesSt. Petersburg State UniversitySt. PetersburgRussia
  3. 3.Limnological InstituteSiberian Branch of the Russian Academy of SciencesIrkutskRussia
  4. 4.Faculty of GeographyLomonosov Moscow State UniversityMoscowRussia
  5. 5.Faculty of GeologyLomonosov Moscow State UniversityMoscowRussia
  6. 6.Karpinsky All-Russian Geological Research Institute (VSEGEI)St. PetersburgRussia
  7. 7.Arctic and Antarctic Research Institute (AARI)St. PetersburgRussia
  8. 8.Helmholtz-Center for Ocean Research GEOMARKielGermany
  9. 9.Alfred-Wegener Institute Helmholtz-Center for Polar and Marine Research (AWI) c/o GEOMAR Helmholtz-Center for Ocean ResearchKielGermany

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