Facile Preparation of Zirconia Nanostructures by New Method: Nano-Scale Zirconium(IV) Coordination Supramolecular Compound as Precursor

Research Paper

Abstract

In this investigation, zirconia (ZrO2) nanopowders have been synthesized through the decomposition of a nano-structured zirconium(IV) coordination supramolecular compound, (pydaH)2[Zr(pydc)3]·5H2O (1), where [pyda.H]+ = 2,6-diaminopyridinium, and [pydc]2− = 2,6-pyridinedicarboxylate, as a new precursor. The compound 1 has been synthesized by sonochemical method and characterized by field emission scanning electron microscope (FESEM), X-ray powder diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and elemental analyses. The sizes of the nanostructures were approximately 50 nm. The thermal stability of compound 1 has been studied by thermal gravimetric (TG) and differential thermal analyses (DTA). The XRD pattern of the residue obtained from thermal decomposition of compound 1 under argon and air atmospheres provided two different kinds of crystal systems of zirconia, tetragonal (t) and mixture of monoclinic (m) and tetragonal (t) with particles size about 35 and 28 nm, respectively. This study, demonstrates that the supramolecular compounds may be suitable precursors for the simple one-pot preparation of nano-scale metal oxide materials with different and interesting morphologies.

Keywords

Zirconia nanostructures Zr(IV) complex Crystal system Sonochemical method Thermal analyses 

Notes

Acknowledgments

Authors are grateful to Iranian national science foundation (INSF) and Iranian Research Organization for Science and Technology (IROST) and Nanotechnology Initiative Council for their unending effort to provide financial support to undertake this work.

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Copyright information

© Shiraz University 2016

Authors and Affiliations

  1. 1.Department of Chemical TechnologiesIranian Research Organization for Science and Technology (IROST)TehranIran

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