Reversible multiplexing for optical information recording, erasing, and reading-out in photochromic BaMgSiO4:Bi3+ luminescence ceramics

基于光致变色效应的BaMgSiO4:Bi3+陶瓷的发光性质调控及信息的可逆写入、 擦除和读出研究

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Optical data storage technology has many advantages over the traditional solid-state and magnetic storage technology, such as low cost, multi-dimensional storage, and rewritable capability. Therefore, the optical data storage technology has been in increasing demand for optical storage media. Herein, the photochromic and photoluminescence properties of BaMgSiO4:Bi3+ ceramics were investigated. The BaMgSiO4:Bi3+ ceramics showed reversible photochromism from gray to pink upon alternating the 254 nm ultraviolet light and 532 nm laser irradiation. This is caused by the electron trapping and de-trapping in the oxygen vacancies of the BaMgSiO4:Bi3+ host. This reversible behavior of photochromism was applied to fabricate different patterns on the surface of the BaMgSiO4:Bi3+ ceramics, which exhibited the reversible dual-mode optical information recording and erasing abilities. The photoluminescence reversible modulation of the BaMgSiO4:Bi3+ ceramics was obtained through the photochromic phenomenon. This modification behavior of luminescence could be applied to read-out the recording information in the BaMgSiO4:Bi3+ ceramics. The coloration and bleaching of BaMgSiO4:Bi3+ ceramics were dependent on the time of light stimulation, which facilitated multiplexing encoding. This photoluminescence and photochromism multiplexing of the BaMgSiO4:Bi3+ ceramics enhanced the optical data storage capability.


光存储技术与传统固态存储和磁存储相比有许多优点, 如成本低、 可重复性存储. 因此, 光存储的需求正在持续增长. 本文研究了铋掺杂的硅酸镁钡陶瓷的光致变色及光致发光现象. 在紫外线(254 nm)和532 nm激光交替辐照下, 实现了陶瓷在灰色与粉红色之间的可逆转变. 研究证实MgSiO4:Bi3+陶瓷的可逆光致变色来源于基质中的氧空位陷阱对电子的俘获和释放. 基于可逆光致变色效应在陶瓷表面制作不同颜色的图案, 实现了光信号的双模式存储和擦除. 同时, 在光致变色过程中实现了光致发光的可逆调控; 通过这种可逆的发光调控行为, 实现存储信息的读出; 此外, 变色和漂白的程度与光照射时间有关, 因此可实现多通路编码存储, 有望提高光存储容量.


  1. 1

    Tu M, Reinsch H, Rodríguez-Hermida S, et al. Reversible optical writing and data storage in an anthracene-loaded metal-organic framework. Angew Chem Int Ed, 2019, 58: 2423–2427

  2. 2

    Gu M, Zhang Q, Lamon S. Nanomaterials for optical data storage. Nat Rev Mater, 2016, 1: 16070

  3. 3

    Parthenopoulos DA, Rentzepis PM. Three-dimensional optical storage memory. Science, 1989, 245: 843–845

  4. 4

    Gu M, Li X, Cao Y. Optical storage arrays: a perspective for future big data storage. Light Sci Appl, 2014, 3: e177

  5. 5

    Riesen N, Pan X, Badek K, et al. Towards rewritable multilevel optical data storage in single nanocrystals. Opt Express, 2018, 26: 12266

  6. 6

    Zuo Y, Xu X, Tao X, et al. A novel information storage and visual expression device based on mechanoluminescence. J Mater Chem C, 2019, 7: 4020–4025

  7. 7

    Betzig E, Trautman JK, Wolfe R, et al. Near-field magneto-optics and high density data storage. Appl Phys Lett, 1992, 61: 142–144

  8. 8

    Li L, Gattass RR, Gershgoren E, et al. Achieving lambda/20 resolution by one-color initiation and deactivation of polymerization. Science, 2009, 324: 910–913

  9. 9

    Li W, Zhuang Y, Zheng P, et al. Tailoring trap depth and emission wavelength in Y3Al5−xGaxO12:Ce3+,V3+ phosphor-in-glass films for optical information storage. ACS Appl Mater Interfaces, 2018, 10: 27150–27159

  10. 10

    Zhuang Y, Wang L, Lv Y, et al. Optical data storage and multicolor emission readout on flexible films using deep-trap persistent luminescence materials. Adv Funct Mater, 2018, 28: 1705769

  11. 11

    Long Z, Wen Y, Zhou J, et al. No-interference reading for optical information storage and ultra-multiple anti-counterfeiting applications by designing targeted recombination in charge carrier trapping phosphors. Adv Opt Mater, 2019, 7: 1900006

  12. 12

    Lin S, Lin H, Huang Q, et al. Optical storage: A photostimulated BaSi2O5:Eu2+,Nd3+ phosphor-in-glass for erasable-rewritable optical storage medium. Laser Photonics Rev, 2019, 13: 1970022

  13. 13

    Zhang Q, Zhang Y, Sun H, et al. Tunable luminescence contrast of Na0.5Bi4.5Ti4O15:Re (Re = Sm, Pr, Er) photochromics by controlling the excitation energy of luminescent centers. ACS Appl Mater Interfaces, 2016, 8: 34581–34589

  14. 14

    Ruan J, Yang Z, Huang A, et al. Thermomchromic reaction-induced reversible upconversion emission modulation for switching devices and tunable upconversion emission based on defect engineering of WO3:Yb3+,Er3+ phosphor. ACS Appl Mater Interfaces, 2018, 10: 14941–14947

  15. 15

    Zhang Q, Sun H, Wang X, et al. Reversible luminescence modulation upon photochromic reactions in rare-earth doped ferroelectric oxides by in situ photoluminescence spectroscopy. ACS Appl Mater Interfaces, 2015, 7: 25289–25297

  16. 16

    Pardo R, Zayat M, Levy D. Photochromic organic-inorganic hybrid materials. Chem Soc Rev, 2011, 40: 672

  17. 17

    Zhang J, Zou Q, Tian H. Photochromic materials: more than meets the eye. Adv Mater, 2013, 25: 378–399

  18. 18

    Yonezaki Y, Takei S. Photochromism and emission-color change in Ba3MgSi2O8-based phosphors. J Lumin, 2016, 173: 237–242

  19. 19

    Jin Y, Hu Y, Fu Y, et al. Reversible colorless-cyan photochromism in Eu2+-doped Sr3YNa(PO4)3F powders. J Mater Chem C, 2015, 3: 9435–9443

  20. 20

    Suzuki K, Ubukata T, Yokoyama Y. Dual-mode fluorescence switching of photochromic bisthiazolylcoumarin. Chem Commun, 2012, 48: 765–767

  21. 21

    Li M, Yang Z, Ren Y, et al. Reversible modulated upconversion luminescence of MoO3:Yb3+,Er3+ thermochromic phosphor for switching devices. Inorg Chem, 2019, 58: 6950–6958

  22. 22

    Hou Y, Du J, Hou J, et al. Rewritable optical data storage based on mechanochromic fluorescence materials with aggregation-induced emission. Dyes Pigments, 2019, 160: 830–838

  23. 23

    Zhang Y, Luo L, Li K, et al. Up-conversion luminescence switching of (K0.5Na0.5)0.995Er0.005NbO3 ferroelectric ceramic based on photo-chromic reaction. Ceramics Int, 2018, 44: 1086–1090

  24. 24

    Li P, Yang X, Maß TWW, et al. Reversible optical switching of highly confined phonon-polaritons with an ultrathin phase-change material. Nat Mater, 2016, 15: 870–875

  25. 25

    Qin B, Chen H, Liang H, et al. Reversible photoswitchable fluorescence in thin films of inorganic nanoparticle and polyoxometalate assemblies. J Am Chem Soc, 2010, 132: 2886–2888

  26. 26

    Zhang Q, Yue S, Sun H, et al. Nondestructive up-conversion readout in Er/Yb co-doped Na0.5Bi2.5Nb2O9-based optical storage materials for optical data storage device applications. J Mater Chem C, 2017, 5: 3838–3847

  27. 27

    Ouyang X, Xu Y, Feng Z, et al. Polychromatic and polarized multilevel optical data storage. Nanoscale, 2019, 11: 2447–2452

  28. 28

    Zijlstra P, Chon JWM, Gu M. Five-dimensional optical recording mediated by surface plasmons in gold nanorods. Nature, 2009, 459: 410–413

  29. 29

    Ren H, Li X, Zhang Q, et al. On-chip noninterference angular momentum multiplexing of broadband light. Science, 2016, 352: 805–809

  30. 30

    Li C, Yan H, Zhang GF, et al. Photocontrolled intramolecular charge/energy transfer and fluorescence switching of tetraphenylethene-dithienylethene-perylenemonoimide triad with donor-bridge-acceptor structure. Chem Asian J, 2014, 9: 104–109

  31. 31

    Ko CC, Yam VWW. Coordination compounds with photochromic ligands: Ready tunability and visible light-sensitized photochromism. Acc Chem Res, 2018, 51: 149–159

  32. 32

    Bisoyi HK, Li Q. Light-driven liquid crystalline materials: from photo-induced phase transitions and property modulations to applications. Chem Rev, 2016, 116: 15089–15166

  33. 33

    Rameshbabu K, Zou L, Kim C, et al. Self-organized photochromic dithienylcyclopentene organogels. J Mater Chem, 2011, 21: 15673

  34. 34

    Tian H, Chen B, Tu HY, et al. Novel bisthienylethene-based photochromic tetraazaporphyrin with photoregulating luminescence. Adv Mater, 2002, 14: 918

  35. 35

    Denekamp C, Feringa BL. Optically active diarylethenes for multimode photoswitching between liquid-crystalline phases. Adv Mater, 1998, 10: 1080–1082

  36. 36

    Irie M. Diarylethenes for memories and switches. Chem Rev, 2000, 100: 1685–1716

  37. 37

    Mamiya J, Kuriyama A, Yokota N, et al. Photomobile polymer materials: Photoresponsive behavior of cross-linked liquid-crystalline polymers with mesomorphic diarylethenes. Chem Eur J, 2015, 21: 3174–3177

  38. 38

    Wang J, Gao Y, Zhang J, et al. Invisible photochromism and optical anti-counterfeiting based on D-A type inverse diarylethene. J Mater Chem C, 2017, 5: 4571–4577

  39. 39

    Jin Y, Hu Y, Yuan L, et al. Multifunctional near-infrared emitting Cr3+-doped Mg4Ga8Ge2O20 particles with long persistent and photostimulated persistent luminescence, and photochromic properties. J Mater Chem C, 2016, 4: 6614–6625

  40. 40

    Yamase T. Photo- and electrochromism of polyoxometalates and related materials. Chem Rev, 1998, 98: 307–326

  41. 41

    Sun H, Liu J, Wang X, et al. (K,Na)NbO3 ferroelectrics: a new class of solid-state photochromic materials with reversible luminescence switching behavior. J Mater Chem C, 2017, 5: 9080–9087

  42. 42

    Zhang JC, Qin QS, Yu MH, et al. Up-conversion photostimulated luminescence of Mg2SnO4 for optical storage. Chin Phys Lett, 2011, 28: 027802

  43. 43

    Kamimura S, Yamada H, Xu CN. Purple photochromism in Sr2SnO4:Eu3+ with layered perovskite-related structure. Appl Phys Lett, 2013, 102: 031110

  44. 44

    Zhang Y, Luo L, Li K, et al. Reversible up-conversion luminescence modulation based on UV-VIS light-controlled photochromism in Er3+ doped Sr2SnO4. J Mater Chem C, 2018, 6: 13148–13156

  45. 45

    Wang S, Fan W, Liu Z, et al. Advances on tungsten oxide based photochromic materials: Strategies to improve their photochromic properties. J Mater Chem C, 2018, 6: 191–212

  46. 46

    Mellerup SK, Wang S. Isomerization and rearrangement of boriranes: from chemical rarities to functional materials. Sci China Mater, 2018, 61: 1249–1256

  47. 47

    Nishio S, Kakihana M. Evidence for visible light photochromism of V2O5. Chem Mater, 2002, 14: 3730–3733

  48. 48

    Li K, Luo L, Zhang Y, et al. The upconversion luminescence modulation and its enhancement in Er3+-doped Na0.5Bi0.5TiO3 based on photochromic reaction. J Am Ceram Soc, 2018, 101: 5640–5650

  49. 49

    Yang F, Jia B, Wei T, et al. Reversible regulation of upconversion luminescence in new photochromic ferroelectric materials: Bi4−xErxTi3O12 ceramics. Inorg Chem Front, 2019, 6: 2756–2766

  50. 50

    Wales DJ, Cao Q, Kastner K, et al. 3D-printable photochromic molecular materials for reversible information storage. Adv Mater, 2018, 30: 1800159

  51. 51

    Veber A, Cicconi MR, Puri A, et al. Optical properties and bismuth redox in Bi-doped high-silica Al-Si glasses. J Phys Chem C, 2018, 122: 19777–19792

  52. 52

    Tsiumra V, Zhyshkovych A, Malyi T, et al. Localized exciton luminescence in YVO4:Bi3+. Optical Mater, 2019, 89: 480–487

  53. 53

    Zhou S, Jiang N, Zhu B, et al. Multifunctional bismuth-doped nanoporous silica glass: From blue-green, orange, red, and white light sources to ultra-broadband infrared amplifiers. Adv Funct Mater, 2008, 18: 1407–1413

  54. 54

    Huang A, Yang Z, Yu C, et al. Near-infrared quantum cutting luminescence and energy transfer mechanism of Ba2Y(BO3)2Cl: Bi3+, Yb3+ phosphors. IEEE Photonics J, 2018, 10: 1–7

  55. 55

    Vtyurina DN, Eistrikh-Geller PA, Kuz’micheva GM, et al. Influence of monovalent Bi+ doping on real composition, point defects, and photoluminescence in TlCdCl3 and TlCdI3 single crystals. Sci China Mater, 2017, 60: 1253–1263

  56. 56

    Wang D, Liu W, Zhang Z. Emission tuning studies in BaMgSiO4: RE (RE = Eu2+, Sr2+) for white LEDs. Mater Chem Phys, 2018, 207: 479–488

  57. 57

    Zhang G, Zhao L, Fan F, et al. Near UV-pumped yellow-emitting Ca3TeO6:Dy3+ phosphor for white light-emitting diodes. Spectro-Chim Acta Part A-Mol Biomol Spectr, 2019, 223: 117343

  58. 58

    Ren Y, Yang Z, Li M, et al. Reversible upconversion luminescence modification based on photochromism in BaMgSiO4:Yb3+,Tb3+ ceramics for anti-counterfeiting applications. Adv Opt Mater, 2019, 7: 1900213

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This work was supported by the National Natural Science Foundation of China (51762029, 11674137) and the Applied Basic Research Key Program of Yunnan Province (2018FA026).

Author information

Author contributions Yang Z and Yu J supervised the project. Ren Y designed and performed the experiments. Qiu J, Wang Y, Li M, Song Z, Ullah A, and Khan I participated in analyzing and interpreting the data. All authors contributed to the general discussion.

Correspondence to Zhengwen Yang 杨正文 or Jie Yu 余杰.

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Conflict of interest The authors declare that they have no conflict of interest.

Additional information

Youtao Ren is currently pursuing his Master’s degree from Kunming University of Science and Technology under the supervision of Prof. Zhengwen Yang. His current work focuses on the fabrication of photochromic ceramics for optical storage applications.

Zhengwen Yang is currently a professor of the College of Materials Science and Engineering in Kunming University of Science and Technology. He received his Bachelor’s degree in 2002, Master’s degree in 2005 from Jilin University, and his PhD degree from Tsinghua University in 2009. His research interests are the modification and enhancement of the up-conversion luminescence.

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Ren, Y., Yang, Z., Wang, Y. et al. Reversible multiplexing for optical information recording, erasing, and reading-out in photochromic BaMgSiO4:Bi3+ luminescence ceramics. Sci. China Mater. (2020) doi:10.1007/s40843-019-1230-4

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  • BaMgSiO4:Bi3+ ceramic
  • photochromism
  • photoluminescence
  • reversible modification