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A thiol-amine mixture for metal oxide towards device quality metal chalcogenides

  • Tong Zhang (张童)
  • Lijian Zhang (张立建)
  • Yiwei Yin (尹奕炜)
  • Chenhui Jiang (江晨辉)
  • Shi’ang Li (李诗昂)
  • Changfei Zhu (朱长飞)
  • Tao Chen (陈涛)
Letter
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一种硫醇/胺方法将金属氧化物转换为器件级金属硫属化物

摘要

利用分子前驱体溶液制备金属硫属化物薄膜在器件领域具有广泛的应用前景. 本文利用巯基乙醇和乙醇胺这种新型硫醇/胺溶剂, 溶解很多价格便宜的金属氧化物和氢氧化物, 如Cu2O, ZnO, SnO, In(OH)3, GeO2, Cd(OH)2, MnO, PbO, Bi2O3, Sb2O3. 通过添加硫脲和硒粉作为硫源和硒源后可以制得相应的二元金属硫化物、 硒化物. 此方法还可用来制备纯物相的带隙可调的三元CuSbSe2−xSx和四元Cu2 ZnSnSe4. 我们用这种方法合成的Sb2S3平面异质结太阳电池光电转化效率可高达到4.39%. 这项研究提供了一种制备二元、 三元、 四元器件级金属硫属化物薄膜的普适性方法.

Notes

Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities (WK2060140023, WK2060140022, CX3430000001 and WK2060140024), the Major/Innovative Program of Development Foundation of Hefei Center for Physical Science and Technology (2016FXZY003), and the National Natural Science Foundation of China (GG2060140085 and CX2310000097).

Supplementary material

40843_2018_9376_MOESM1_ESM.pdf (3.4 mb)
A thiol-amine mixture for metal oxide towards device quality metal chalcogenides

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Copyright information

© Science in China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Tong Zhang (张童)
    • 1
  • Lijian Zhang (张立建)
    • 1
  • Yiwei Yin (尹奕炜)
    • 1
  • Chenhui Jiang (江晨辉)
    • 1
  • Shi’ang Li (李诗昂)
    • 1
  • Changfei Zhu (朱长飞)
    • 1
  • Tao Chen (陈涛)
    • 1
  1. 1.CAS Key Laboratory of Materials for Energy Conversion, Department of Materials Science and EngineeringUniversity of Science and Technology of ChinaHefeiChina

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