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Journal of Sustainable Metallurgy

, Volume 5, Issue 4, pp 474–481 | Cite as

Recovery of Laminar LiCoO2 Materials from Spent Mobile Phone Batteries by High-Temperature Calcination

  • Sayed M. BadawyEmail author
  • Abd ElAziz A. Nayl
Research Article
  • 48 Downloads

Abstract

Sustainable recovery of laminar LiCoO2 materials from spent mobile phone batteries by high-temperature calcination was studied. Graphite powders were removed from the anode when the copper thin foil was attacked. Spent LiCoO2 and aluminum thin foil on the cathode were separated by pulverization and sieving. Spent cathodic materials were calcined at 900 °C to remove impurities and recover the laminar structure of LiCoO2. The structure and morphology of the recovered active materials were studied by X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray. The laminar structure of the recovered LiCoO2 was found to be a favorable feature for the Li+ intercalation/deintercalation. Electrochemical properties of the recovered LiCoO2 electrode during the galvanostatic charge/discharge processes were tested by cyclic voltammetry. The recovered LiCoO2 electrode shows a reversibility and a specific capacitance of 14.0 F/g (at 50 mV/s) indicating that it exhibits favorable properties for use as pseudocapacitor. It is found comparatively that the present process is a more environment-friendly and a lower-cost recycling method, and hence more feasible for industrial applications than the other reported processes.

Keywords

Recovery Cathode LiCoO2 Spent lithium batteries Electrochemical 

Notes

Compliance with Ethical Standards

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

References

  1. 1.
    Badawy SM, Nayl AA, El Khashab RA, El-Khateeb MA (2014) Cobalt separation from waste mobile phone batteries using selective precipitation and chelating resin. J Mater Cycles Waste Manag 16:739–746CrossRefGoogle Scholar
  2. 2.
    Jha MK, Kumari A, Jha AK, Kumar V et al (2013) Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone. Waste Manage 33:1890–1897CrossRefGoogle Scholar
  3. 3.
    Li J, Shi P, Wang Z, Chen Y, Chang C (2009) A combined recovery process of metals in spent lithium-ion batteries. Chemosphere 77:1132–1136CrossRefGoogle Scholar
  4. 4.
    Zhang T, He Y, Wang F, Ge L et al (2014) Chemical and process mineralogical characterizations of spent lithium-ion batteries: an approach by multi-analytical techniques. Waste Manage 34:1051–1058CrossRefGoogle Scholar
  5. 5.
    Zhou X, He W, Li G, Zhang X (2010) Recycling of electrode materials from spent lithium-ion batteries. In: 4th international conference on bioinformatics and biomedical engineering (iCBBE), 18–20 June 2010, pp 1–4Google Scholar
  6. 6.
    Bankole OE, Gong C, Lei L (2013) Battery recycling technologies: recycling waste lithium ion batteries with the impact on the environment in-view. J Environ Ecol 4(1):14–28CrossRefGoogle Scholar
  7. 7.
    Shu-guang Z, Wen-zhi H, Guang-ming L et al (2012) Recovery of Co and Li from spent lithium-ion batteries by combination method of acid leaching and chemical precipitation. Trans Nonferrous Met Soc China 22:2274–2281CrossRefGoogle Scholar
  8. 8.
    Lu M, Zhang H, Wang B, Zheng X, Dai C (2013) The Re-synthesis of LiCoO2 from spent lithium ion batteries separated by vacuum-assisted heat-treating method. Int J Electrochem Sci 8:8201–8209Google Scholar
  9. 9.
    Li J, Zhao R, He X, Liu H (2009) Preparation of LiCoO2 cathode materials from spent lithium–ion batteries. Ionics 15:111–113CrossRefGoogle Scholar
  10. 10.
    Zhang Z, He W, Li G et al (2014) Recovery of lithium cobalt oxide material from the cathode of spent lithium-ion batteries. ECS Electrochem Lett 3(6):A58–A61CrossRefGoogle Scholar
  11. 11.
    Badawy SM (2016) Synthesis of high-quality graphene oxide from spent mobile phone batteries. Environ Progress Sustain Energy 35(5):1485–1491CrossRefGoogle Scholar
  12. 12.
    Shaw S (2012) Increasing demand for high purity natural graphite in new applications. In: Natural & synthetic graphite: global industry markets & outlook, 8th edn.Google Scholar
  13. 13.
    Zhang X, Xie Y, Lin X, Li H, Cao H (2013) An overview on the processes and technologies for recycling cathodic active materials from spent lithium-ion batteries. J Mater Cycles Waste Manag 15:420–430CrossRefGoogle Scholar
  14. 14.
    Meshram P, Abhilash Pandey BD, Mankhand TR, Deveci H (2016) Acid baking of spent lithium ion batteries for selective recovery of major metals: a two-step process. J Ind Eng Chem 43:117–126CrossRefGoogle Scholar
  15. 15.
    Paulino JF, Busnardo NG, Afonso JC (2008) Recovery of valuable elements from spent Li-batteries. J Hazard Mater 150:843–849CrossRefGoogle Scholar
  16. 16.
    Chen X, Guo C, Ma H, Li J et al (2018) Organic reductants based leaching: a sustainable process for the recovery of valuable metals from spent lithium ion batteries. Waste Manage 75:459–468CrossRefGoogle Scholar
  17. 17.
    Wang D, Zhang X, Chen H, Sun J (2018) Separation of Li and Co from the active mass of spent Li-ion batteries by selective sulfating roasting with sodium bisulfate and water leaching. Miner Eng 126:28–35CrossRefGoogle Scholar
  18. 18.
    Chen X, Cao L, Kang D et al (2019) Recovery of valuable metals from mixed types of spent lithium ion batteries. Part II: selective extraction of lithium. Waste Manage 80:198–210CrossRefGoogle Scholar
  19. 19.
    Nie H, Xu L, Song D et al (2015) LiCoO2: recycling from spent batteries and regeneration with solid state synthesis. Green Chem 17:1276–1280CrossRefGoogle Scholar
  20. 20.
    Zhang Z, He W, Li G et al (2014) Ultrasound-assisted hydrothermal renovation of LiCoO2 from the cathode of spent lithium-ion batteries. Int J Electrochem Sci 9:3691–3700Google Scholar
  21. 21.
    Lu M, Zhang H, Wang B et al (2013) The Re-synthesis of LiCoO2 from spent lithium ion batteries separated by vacuum-assisted heat-treating method. Int J Electrochem Sci 8:8201–8209Google Scholar
  22. 22.
    Chen X, Luo C, Zhang J et al (2015) Sustainable recovery of metals from spent lithium-ion batteries: a green process. ACS Sustain Chem Eng 3(12):3104–3113CrossRefGoogle Scholar
  23. 23.
    Jinhui L, Shengwen Z, Daoling X, Hao C (2009) Synthesis and electrochemical performances of LiCoO2 recycled from the incisors bound of Li-ion batteries. Rare Met 28(4):328–332CrossRefGoogle Scholar
  24. 24.
    Chen X, Kang D, Cao L et al (2019) Separation and recovery of valuable metals from spent lithium ion batteries: simultaneous recovery of Li and Co in a single step. Sep Purif Technol 210:690–697CrossRefGoogle Scholar
  25. 25.
    Zhou X, He W, Li G et al (2010) Recycling of electrode materials from spent lithium-ion batteries. In: 4th international conference on bioinformatics and biomedical engineering (iCBBE), pp 18–20Google Scholar
  26. 26.
    Vasilchina H, Aleksandrova A, Momchilov A et al (2005) Proceedings of the international workshop “portable and emergency energy sources—from materials to systems” pp 16–22, Primorsko, BulgariaGoogle Scholar
  27. 27.
    Kwon NH (2013) The effect of carbon morphology on the LiCoO2 cathode of lithium ion batteries. Solid State Sci 2:59–65CrossRefGoogle Scholar
  28. 28.
    Li L, RenJie C, XiaoXiao Z et al (2012) Preparation and electrochemical properties of re-synthesized LiCoO2 from spent lithium-ion batteries. Chin Sci Bull 57(32):4188–4194CrossRefGoogle Scholar
  29. 29.
    Zhang Z, He W, Li G et al (2015) Renovation of LiCoO2 crystal structure from spent lithium ion batteries by ultrasonic hydrothermal reaction. Res Chem Intermed 41:3367–3373CrossRefGoogle Scholar
  30. 30.
    Song D, Wang X, Nie H et al (2014) Heat treatment of LiCoO2 recovered from cathode scraps with solvent method. J Power Sources 249:137–141CrossRefGoogle Scholar
  31. 31.
    Cao J, Hu G, Peng Z et al (2015) Polypyrrole-coated LiCoO2 nanocomposite with enhanced electrochemical properties at high voltage for lithium-ion batteries. J Power Sources 281:49–55CrossRefGoogle Scholar
  32. 32.
    Kellerman DG, Karelina VV, Vadim S et al (2002) Investigation of thermal stability of LiCoO2 and Li1-xCoO2. Chem Sustain Dev 10:721–726Google Scholar
  33. 33.
    Antolini E, Ferretti M (1995) Synthesis and thermal stability of LiCoO2. J Solid State Chem 117:1–7CrossRefGoogle Scholar
  34. 34.
    Habibi A, Jalaly M, Rahmanifard R, Ghorbanzadeh M et al (2018) The effect of calcination conditions on the crystal growth and battery performance of nanocrystalline Li(Ni1/3Co1/3Mn1/3)O2 as a cathode material for Li-ion batteries. New J Chem 42:19026–19033CrossRefGoogle Scholar
  35. 35.
    Kong J, Zhou F, Wang C et al (2013) Effects of Li source and calcination temperature on the electrochemical properties of LiNi0.5Co0.2Mn0.3O2 lithium-ion cathode materials. J Alloy Compd 554:221–226CrossRefGoogle Scholar
  36. 36.
    Zeng X, Li J, Singh N (2014) Recycling of spent lithium-ion battery: a critical review. Crit Rev Environ Sci Technol 44:1129–1165CrossRefGoogle Scholar
  37. 37.
    Xu Y, Dong Y, Han X et al (2015) Application for simply recovered LiCoO2 material: as a high performance candidate for supercapacitor in aqueous system. ACS Sustain Chem Eng 3(10):2435–2442CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  1. 1.National Center for Clinical and Environmental Toxicology, Faculty of MedicineCairo UniversityCairoEgypt
  2. 2.Hot Labs CentreAtomic Energy AuthorityCairoEgypt

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