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A Comparative Study of Experimental Optimization and Taguchi Design of Co(II) Recovery by Aliquat 336 as Ionic Liquid Carrier

  • Nesrine Sarah Merad
  • Nasr-Eddine BelkhoucheEmail author
Research Article
  • 5 Downloads

Abstract

Experiments of extraction and stripping of cobalt(II) were carried out. The liquid–liquid extraction process was considered, in which the organic phase was constituted of Aliquat 336 extractant that is the quaternary ammonium salt, and oleyl alcohol modifier dissolved in dodecane where the aqueous phase contained the metal ion in a concentrated hydrochloric acid solution. The optimization of Co(II) recovery was determined by optimizing one parameter at the time. Therefore, several experimental parameters such as Aliquat 336 concentration, extraction time, hydrochloric acid concentration, and the initial concentration of metal ion were studied. The cobalt(II) ions were extracted at 62.5% and stripped from the metal-loaded organic phase at 41.0% by distilled water as stripping agent. The mass balances were checked for all the studied parameters with an average deviation percentage of 2%. In fact, the McCabe–Thiele showed six theoretical stages for total recovery of cobalt. The separation tests of Co(II) and Ni(II) were carried out on the basis of the optimal conditions of Co(II) recovery. It showed that the nickel ions were slightly extracted (< 10%) whatever the composition of mixture. A Taguchi design with a L4 orthogonal array was used for the statistical study to determine the influence and the contribution percentage of certain experimental parameters on the Co(II) extraction. Analysis of variance and analysis of means showed a total absence of the uncontrollable factors (noise), in which the chosen model has described our extraction process with accuracy. In fact, only the main effects without interaction of controllable factors (A, B, and C) contribute to the optimal extraction of cobalt as follows: A (50.10%), B (28.33%), and C (21.47%) at levels: 2/2/1 with high signals as 32.07, 28.38 and 25.13, respectively.

Keywords

Liquid–liquid extraction Cobalt(II) Nickel(II) Aliquat 336 L4 Taguchi modeling 

Notes

Acknowledgements

The authors thank the laboratory of Separation and Purification Technologies at the University of Tlemcen, Algeria for their financial support.

Compliance with Ethical Standards

Conflict of interest

The authors state that there are no conflicts of interest to disclose.

References

  1. 1.
    Surucu A, Eyupoglu V, Tutkun O (2012) Selective separation of cobalt and nickel by flat sheet supported liquid membrane using Alamine 300 as carrier. J Ind Eng Chem 18:629–634CrossRefGoogle Scholar
  2. 2.
    Kumbasar RA (2010) Extraction and concentration of cobalt from acidic leach solutions containing Co–Ni by emulsion liquid membrane using TOA as extractant. J Ind Eng Chem 16:448–454CrossRefGoogle Scholar
  3. 3.
    Kumbasar RA, Tutkun O (2008) Separation of cobalt and nickel from acidic leach solutions by emulsion liquid membranes using Alamine 300 (TOA) as a mobile carrier. Desalination 224:201–208CrossRefGoogle Scholar
  4. 4.
    Sadyrbaeva TZh (2015) Separation of cobalt(II) from nickel(II) by a hybrid liquid membrane–electrodialysis process using anion exchange carriers. Desalination 365:167–175CrossRefGoogle Scholar
  5. 5.
    Mubaroka MZ, Hanifa LI (2016) Cobalt and nickel separation in nitric acid solution by solvent extraction using Cyanex 272 and Versatic 10. Proc Chem 19:743–750CrossRefGoogle Scholar
  6. 6.
    Kumbasar RA (2012) Selective extraction of cobalt from strong acidic solutions containing cobalt and nickel through emulsion liquid membrane using TIOA as carrier. J Ind Eng Chem 18:2076–2082CrossRefGoogle Scholar
  7. 7.
    Ipek U (2005) Removal of Ni(II) and Zn(II) from an aqueous solution by reverse osmosis. Desalination 174:161–169CrossRefGoogle Scholar
  8. 8.
    Katsou E, Malamis S, Haralambous KJ, Loizidou M (2010) Use of ultrafiltration membranes and aluminosilicate minerals for nickel removal from industrial wastewater. J Membr Sci 360:234–249CrossRefGoogle Scholar
  9. 9.
    Akbal F, Camci S (2011) Copper, chromium and nickel removal from metal plating wastewater by electrocoagulation. Desalination 269:214–222CrossRefGoogle Scholar
  10. 10.
    Li B, Liu F, Wang J, Ling C, Li L, Hou P et al (2012) Efficient separation and high selectivity for nickel from cobalt-solution by a novel chelating resin: batch, column and competition investigation. Chem Eng J 195–196:31–39CrossRefGoogle Scholar
  11. 11.
    Repo E, Warchol JK, Kurniawan TA, Sillanpaa MET (2010) Adsorption of Co(II) and Ni(II) by EDTA- and/or DTPA-modified chitosan: kinetic and equilibrium modeling. Chem Eng J 161:73–82CrossRefGoogle Scholar
  12. 12.
    Dinu MV, Dragan ES (2010) Evaluation of Cu2+, Co2+ and Ni2+ ions removal from aqueous solution using a novel chitosan/clinoptilolite composite: kinetics and isotherms. Chem Eng J 160:157–163CrossRefGoogle Scholar
  13. 13.
    Panigrahi M, Grabda M, Kozak D, Dorai A, Shibata E, Kawamura J, Nakamura T (2016) Liquid–liquid extraction of neodymium ions from aqueous solutions of NdCl3 by phosphonium-based ionic liquids. Sep Purif Technol 171:263–269CrossRefGoogle Scholar
  14. 14.
    Vernekara PV, Jagdalea YD, Patwardhana AW, Patwardhana AV, Ansarib SA, Mohapatrab PK, Manchandac VK (2013) Transport of cobalt(II) through a hollow fiber supported liquid membrane containing di-(2-ethylhexyl) phosphoric acid (D2EHPA) as the carrier. Chem Eng Res Des 91:141–157CrossRefGoogle Scholar
  15. 15.
    Coll MT, Fortuny A, Kedari CS, Sastre AM (2012) Studies on the extraction of Co(II) and Ni(II) from aqueous chloride solutions using Primene JMT-Cyanex272 ionic liquid extractant. Hydrometallurgy 125–126:24–28CrossRefGoogle Scholar
  16. 16.
    Ritcey GM, Ashbrook AW, Lucas H (1975) Development of solvent extraction process for the separation of cobalt from nickel. CIM Bull 68:111–119Google Scholar
  17. 17.
    Kumbasar RA (2012) Selective transport of cobalt (II) from ammoniacal solutions containing cobalt (II) and nickel (II) by emulsion liquid membranes using 8-hydroxyquinoline. J Ind Eng Chem 18:145–151CrossRefGoogle Scholar
  18. 18.
    Sun X, Ji Y, Zhang L, Chen J (2010) Separation of cobalt and nickel using inner synergistic extraction from bifunctional ionic liquid extractant (Bif-ILE). J Hazard Mater 182:447–452CrossRefGoogle Scholar
  19. 19.
    Parmentier D, Paradis S, Metz SJ, Wiedmer SK, Kroon MC (2016) Continuous process for selective metal extraction with an ionic liquid. Chem Eng Res Des 109:553–560CrossRefGoogle Scholar
  20. 20.
    Zawisza B, Sitko R (2013) Micro-electrodeposition in the presence of ionic liquid for the preconcentration of trace amounts of Fe Co, Ni and Zn from aqueous samples. Spectrochim Acta B 82:60–64CrossRefGoogle Scholar
  21. 21.
    Buachuang D, Ramakul P, Leepipatpiboon N, Pancharoen U (2011) Mass transfer modeling on the separation of tantalum and niobium from dilute hydrofluoric media through a hollow fiber supported liquid membrane. J Alloy Compd 509:9549–9557CrossRefGoogle Scholar
  22. 22.
    Wassink B, Dreisinger D, Howard J (2000) Solvent extraction separation of zinc and cadmium from nickel and cobalt using Aliquat 336, a strong base anion exchanger, in the chloride and thiocyanate forms. Hydrometallurgy 57:235–252CrossRefGoogle Scholar
  23. 23.
    Quijada-Maldonado E, Torres MJ, Romero J (2017) Solvent extraction of molybdenum(VI) from aqueous solution using ionic liquids as diluents. Sep Purif Technol 177:200–206CrossRefGoogle Scholar
  24. 24.
    Blitz-Raith AH, Paimin R, Cattrall RW, Kolev SD (2007) Separation of cobalt(II) from nickel(II) by solid-phase extraction into Aliquat 336 chloride immobilized in poly(vinyl chloride). Talanta 71:419–423CrossRefGoogle Scholar
  25. 25.
    Sudderth RB, Kordosky G (1986) Some practical considerations in the evaluation and selection of solvent extraction reagents. In: Malhotra D, Riggs WF (eds) Chemical reagents in the mineral processing industry. Society for Mining, Metallurgy and Exploration, Colorado, USA, pp 181–196Google Scholar
  26. 26.
    Choia SY, Nguyenb VT, Lee J, Kanga H, Pandeyd BD (2014) Liquid–liquid extraction of Cd(II) from pure and Ni/Cd acidic chloride media using Cyanex 921: a selective treatment of hazardous leachate of spent Ni–Cd batteries. J Hazard Mater 278:258–266CrossRefGoogle Scholar
  27. 27.
    Nayl AA (2010) Extraction and separation of Co(II) and Ni(II) from acidic sulfate solutions using Aliquat 336. J Hazard Mater 173:223–230CrossRefGoogle Scholar
  28. 28.
    Kao HC, Juang RS (2005) Kinetic analysis of non-dispersive solvent extraction of concentrated Co(II) from chloride solutions with Aliquat 336: significance of the knowledge of reaction equilibrium. J Membr Sci 264:104–112CrossRefGoogle Scholar
  29. 29.
    Ferdous W, Manalo A, Aravinthan T (2017) Bond behaviour of composite sandwich panel and epoxy polymermatrix: Taguchi design of experiments and theoretical predictions. Constr Build Mater 145:76–87CrossRefGoogle Scholar
  30. 30.
    Benyahia N, Belkhouche N, Jönsson JA (2014) A comparative study of experimental optimization and response surface methodology of Bi(III) extraction by emulsion organophosphorus liquid membrane. J Environ Chem Eng 2:1756–1766CrossRefGoogle Scholar
  31. 31.
    Liu H, Zhang YM, Huang J, Liu T, Shi QH (2017) Optimization of vanadium (IV) extraction from stone coal leaching solution by emulsion liquid membrane using response surface methodology. Chem Eng Res Des 123:111–119CrossRefGoogle Scholar
  32. 32.
    Mesli M, Belkhouche N (2018) Emulsion ionic liquid membrane for recovery process of lead. Comparative study of experimental and response surface design. Chem Eng Res Des 129:160–169CrossRefGoogle Scholar
  33. 33.
    Taguchi G, Chowdhury S, Wu Y (2005) Taguchi’s quality engineering handbook. Wiley, New YorkGoogle Scholar
  34. 34.
    Nazari A, Khanmohammadi H, Amini M, Hajiallahyari H, Rahimi A (2012) Production geopolymers by Portland cement: designing the main parameters’ effects on compressive strength by Taguchi method. Mater Des 41:43–49CrossRefGoogle Scholar
  35. 35.
    Bose PK, Deb M, Banerjee R, Majumder A (2013) Multi objective optimization of performance parameters of a single cylinder diesel engine running with hydrogen using a Taguchi-fuzzy based approach. Energy 63:375–386CrossRefGoogle Scholar
  36. 36.
    Kaminari NMS, Schultz DR, Ponte MJJS, Ponte HA, Marino CEB, Neto AC (2007) Heavy metals recovery from industrial wastewater using Taguchi method. Chem Eng J126(2–3):139–146CrossRefGoogle Scholar
  37. 37.
    Azadi R, Rostamiyan Y (2015) Experimental and analytical study of buckling strength of new quaternary hybrid nanocomposite using Taguchi method for optimization. Constr Build Mater 88:212–224CrossRefGoogle Scholar
  38. 38.
    Pandey N, Murugesan K, Thomas HR (2017) Optimization of ground heat exchangers for space heating and cooling applications using Taguchi method and utility concept. Appl Energy 190:421–438CrossRefGoogle Scholar
  39. 39.
    Balki MK, Sayin C, Sarıkaya M (2016) Optimization of the operating parameters based on Taguchi method in an SI engine used pure gasoline, ethanol and methanol. Fuel 180:630–637CrossRefGoogle Scholar
  40. 40.
    Liu X, Zhao S, Qin Y, Zhao J, Wan-Nawang WA (2017) A parametric study on the bending accuracy in micro W-bending using Taguchi method. Measurement 100:233–242CrossRefGoogle Scholar
  41. 41.
    Barrado E, Vega M, Pardon R, Grande P, Valle JLD (1996) Optimization of a purification method for metal-containing wastewater by use of a Taguchi experimental design. Water Res 30:2309–2314CrossRefGoogle Scholar
  42. 42.
    Dönmez G, Aksu Z (1999) The effect of copper(II) ions on the growth and bioaccumulation properties of some yeasts. Process Biochem 35:35–142CrossRefGoogle Scholar
  43. 43.
    Mohammadi T, Moheb A, Sadrzadeh M, Razmi A (2004) Separation of copper ions by electrodialysis using Taguchi experimental design. Desalination 169(1):21–31CrossRefGoogle Scholar
  44. 44.
    Chary GHVC, Dastidar MG (2010) Optimization of experimental conditions for recovery of coking coal fines by oil agglomeration technique. Fuel 9:2317–2322CrossRefGoogle Scholar
  45. 45.
    Engin AB, Ozdemir O, Turan M, Turan AZ (2008) Color removal from textile dye bath effluents in a zeolite fixed bed reactor: determination of optimum process conditions using Taguchi method. J Hazard Mater 159:348–353CrossRefGoogle Scholar
  46. 46.
    Sohrabi MR, Jamshidi S, Esmaeilifar A (2012) Cloud point extraction for determination of Diazinon: optimization of the effective parameters using Taguchi method. Chemometr Intell Lab 110(1):49–54CrossRefGoogle Scholar
  47. 47.
    Kumar RS, Sureshkumar K, Velraj R (2015) Optimization of biodiesel production from Manilkara zapota (L.) seed oil using Taguchi method. Fuel 140:90–96CrossRefGoogle Scholar
  48. 48.
    Sarıkaya M, Güllü A (2014) Taguchi design and response surface methodology based analysis of machining parameters in CNC turning under MQL. J Clean Prod 65:604–616CrossRefGoogle Scholar
  49. 49.
    Pundir R, Chary GHVC, Dastidar MG (2018) Application of Taguchi method for optimizing the process parameters for the removal of copper and nickel by growing Aspergillus sp. Water Resour and Ind 20:83–92CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  1. 1.Laboratory of Separation and Purification Technologies, Faculty of Sciences, Department of ChemistryUniversity of TlemcenTlemcenAlgeria

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