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Comparison of Hydro- and Biohydrometallurgical Extraction of Metals from Waste Li-Ion Batteries of Cell Phone

  • Bhumika R. Khatri
  • Devayani R. Tipre
  • Shailesh R. DaveEmail author
Research Article
  • 19 Downloads

Abstract

In the present study, the black residual powders of waste Li-ion batteries were treated with citric, malic, and a combination of these acids for chemical extraction of multimetals. Among the treatments, 0.75 M malic + 0.75 M citric acid was found to be better than either 1.5 M citric acid or 1.5 M malic acid for 20 g L−1 pulp density at 90 °C. Bioleaching studies were carried out by Leptospirillum ferriphilum-dominated consortium using the two-step process, which resulted in 1.2–1.8-fold higher metal extractions compared to a one-step process. At optimal pH 2.0, Cu–Zn–Ni solubilization was 85 ± 2%, while Co and Li extractions were 97.2% and 33.96%, respectively, after 2–6 days with 10 g L−1 pulp density. When 9 g L−1 initial ferrous iron concentration was used, Cu–Zn–Ni–Co extractions were 92 ± 7%, whereas Li solubilization attained 37.74% within 2–8 days. Optimization of the bioleaching process resulted in 1.7–2.7-fold increase in metal extractions. Studies at 10, 50, and 100 g L−1 pulp densities showed that metal extraction operational time increased as the pulp density was increased, and the obtained extractions ranged between 83 and 40% for Cu, 93 and 54% for Zn, 91 and 27% in the case of Ni, 99 and 17% Co and Li extractions were 44 and 13%. For the spent medium at 10, 50, and 100 g L−1 pulp densities, Cu extraction ranged between 52 and 33%, Zn extractions between 78 and 39%, Ni extractions between 73 and 25%, Co extractions between 58 and 16%, and Li extractions between 22 and 5% within 4–6 days of reaction time. Presence of the consortium had a beneficial influence on the extraction of all the metals studied.

Keywords

Bioleaching Li-ion battery Iron oxidizers Ferric Metals 

Notes

Acknowledgements

The authors are thankful to the University Grants Commission (UGC), New Delhi, for the Emeritus Fellowship to Prof. S.R Dave. Further, the authors duly acknowledge the financial support from the Department of Biotechnology (DBT), New Delhi.

Compliance with Ethical Standards

Conflict of interest

All the authors declare that we have no conflict of interest.

References

  1. 1.
    Awasthi AK, Zeng X, Li J (2016) Relationship between e-waste recycling and human health in India: a critical review. Environ Sci Pollut Res  https://doi.org/10.1007/s11356-016-6085-7 Google Scholar
  2. 2.
    Ranganathan V (2018) How e-waste management is redefining the process of urban mining. https://electronicsforu.com/technology-trends/tech-focus/e-waste-management-process-urban-mining Accessed October 6, 2018
  3. 3.
    Winslow KM, Laux SJ, Townsend TG (2018) A review on the growing concern and potential management strategies of waste lithium-ion batteries. Resour Conserv Recycl 129:263–277CrossRefGoogle Scholar
  4. 4.
    Kang DHP, Chen M, Ogunseitan OA (2013) Potential environmental and human health impacts of rechargeable lithium batteries in electronic waste. Environ Sci Technol 47:5495–5503CrossRefGoogle Scholar
  5. 5.
    Richa K, Babbitt CW, Gaustad G, Wang X (2014) A future perspective on lithium-ion battery waste from electric vehicles. Resour Conserv Recycl 83:63–76.  https://doi.org/10.1016/j.resconrec.2013.11.008 CrossRefGoogle Scholar
  6. 6.
    Zeng X, Li J (2014) Spent rechargeable lithium batteries in e-waste: composition and its implications. Front Environ Sci Eng 8(5):792–796.  https://doi.org/10.1007/s11783-014-0705-6 CrossRefGoogle Scholar
  7. 7.
    Zeng X, Li J, Liu L (2015) Solving spent lithium-ion battery problems in China: opportunities and challenges. Renew Sust Energ Rev 52:1759–1767CrossRefGoogle Scholar
  8. 8.
    Zhang P, Yokoyama T, Itabashi O, Suzuki T, Inoue K (1998) Hydrometallurgical process for recovery of metal values from spent lithium-ion secondary batteries. Hydrometallurgy 47:259–271CrossRefGoogle Scholar
  9. 9.
    Shin SM, Kim NH, Sohn JS (2005) Development of a metal recovery process from Li-ion battery wastes. Hydrometallurgy 79:172–181CrossRefGoogle Scholar
  10. 10.
    Li L, Ge J, Chen R, Wu F, Chen S, Zhang X (2010) Environmental friendly leaching reagent for cobalt and lithium recovery from spent lithium-ion batteries. Waste Manage 30:2615–2621CrossRefGoogle Scholar
  11. 11.
    Wang J, Chen M, Chen H, Luo T, Xu Z (2012) Leaching study of spent Li-ion batteries. Proc Environ Sci 16:443–450CrossRefGoogle Scholar
  12. 12.
    Li L, Dunn JB, Zhang XX, Gaines L, Chen RJ, Wu F, Amine K (2013) Recovery of metals from spent lithium-ion batteries with organic acids as leaching reagents and environmental assessment. J Power Sources 233:180–189CrossRefGoogle Scholar
  13. 13.
    Kang J, Senanayake G, Sohn J, Shin SM (2009) Recovery of cobalt sulfate from spent lithium-ion batteries by reductive leaching and solvent extraction with Cyanex 272. Hydrometallurgy 100:168–171CrossRefGoogle Scholar
  14. 14.
    Granata G, Moscardini E, Pagnanelli F, Trabucco F, Toro L (2012) Product recovery from Li-ion battery wastes coming from an industrial pre-treatment plant : Lab-scale tests and process simulations. J Power Sources 206:393–401CrossRefGoogle Scholar
  15. 15.
    Shuva AH, Kurny ASW (2013) Hydrometallurgical recovery of value metals from spent lithium-ion batteries. Am J Mater Eng Technol 1:8–12Google Scholar
  16. 16.
    Li L, Lu J, Ren Y, Zhang XX, Chen RJ, Wu F, Amine K (2012) Ascorbic-acid-assisted recovery of cobalt and lithium from spent Li-ion batteries. J Power Sources 218:21–27CrossRefGoogle Scholar
  17. 17.
    Xin B, Zhang D, Zhang X, Xia Y, Wu F, Chen S, Li L (2009) Bioleaching mechanism of Co and Li from spent lithium-ion battery by the mixed culture of acidophilic sulfur-oxidizing and iron-oxidizing bacteria. Bioresour Technol 100:6163–6169CrossRefGoogle Scholar
  18. 18.
    Mishra D, Kim D, Ralph DE, Ahn J, Rhee Y (2008) Bioleaching of metals from spent lithium ion secondary batteries using Acidithiobacillus ferrooxidans. Waste Manage 28:333–338CrossRefGoogle Scholar
  19. 19.
    Velgosová O, Kaduková J, Mražíková A, Blašková A, Petoczová M, Horvathová H, Stofko M (2010) Influence of selected parameters on nickel bioleaching from spent Ni-Cd batteries. Mineralia Slovaca 42:365–368Google Scholar
  20. 20.
    Bajestani MI, Mousavi SM, Shojaosadati SA (2014) Bioleaching of heavy metals from spent household batteries using Acidithiobacillus ferrooxidans: Statistical evaluation and optimization. Sep Purif Technol 132:309–316.  https://doi.org/10.1016/j.seppur.2014.05.023 CrossRefGoogle Scholar
  21. 21.
    Cerruti C, Curutchet G, Donati E (1998) Bio-dissolution of spent nickel-cadmium batteries using Thiobacillus ferrooxidans. J Biotechnol 62:209–219CrossRefGoogle Scholar
  22. 22.
    Zhu N, Zhang L, Li C, Cai C (2003) Recycling of spent nickel-cadmium batteries based on bioleaching process. Waste Manag 23:703–708CrossRefGoogle Scholar
  23. 23.
    Sonoc A, Jeswiet J, Soo VK (2015) Opportunities to improve recycling of automotive lithium-ion batteries. Proc CIRP 29:752–757CrossRefGoogle Scholar
  24. 24.
    Vogel AI (1961) A textbook of quantitative inorganic analysis: including elementary instrumental analysis. ELBS and Longman, LondonGoogle Scholar
  25. 25.
    Shah MB, Tipre DR, Purohit MS, Dave SR (2015) Development of two-step process for enhanced biorecovery of Cu-Zn-Ni from computer printed circuit boards. J Biosci Bioeng 120(2):167–173CrossRefGoogle Scholar
  26. 26.
    Patel BC, Tipre DR, Dave SR (2012) Development of Leptospirillum ferriphilum dominated consortium for ferric iron regeneration and metal bioleaching under extreme stresses. Bioresour Technol 118:483–489CrossRefGoogle Scholar
  27. 27.
    Shah MB, Tipre DR, Dave SR (2014) Chemical and biological processes for multi-metal extraction from waste printed circuit boards of computers and cell phones. Waste Manage Res 32(11):1134–1141CrossRefGoogle Scholar
  28. 28.
    Shuva AH, Kurny AS (2013) Characterization of spent lithium-ion batteries in the process of recovery of value metals. Mater Sci 9(10):389–394Google Scholar
  29. 29.
    Ferreira DA, Prados LMZ, Majuste D, Mansur MB (2008) Hydrometallurgical separation of aluminium, cobalt, copper, and lithium from spent Li-ion batteries. J Power Sources 187:238–246CrossRefGoogle Scholar
  30. 30.
    Peng C, Liu F, Wang Z, Wilson BP, Lundstrӧm M (2019) Selective extraction of lithium (Li) and preparation of battery grade lithium carbonate (Li2CO3) from spent Li-ion batteries in nitrate system. J Power Sour 415:179–188CrossRefGoogle Scholar
  31. 31.
    Altonen M, Peng C, Wilson BP, Lundstrӧm M (2017) Leaching of metals from spent lithium-ion batteries. Recycling 2(20):1–9.  https://doi.org/10.3390/recycling2040020 Google Scholar
  32. 32.
    Wu F, Xu S, Li L, Chen S, Xu G, Xu J (2009) Recovery of valuable metals from anode material of hydrogen-nickel battery. Trans Nonferrous Met Soc China 19:468–473CrossRefGoogle Scholar
  33. 33.
    Khatri BR, Sodha AB, Shah MB, Tipre DR, Dave SR (2018) Chemical and microbial leaching of base metals from obsolete cell-phone printed circuit boards. Sustain Environ Res 28:333–339CrossRefGoogle Scholar
  34. 34.
    Sodha AB, Qureshi SA, Khatri BR, Tipre DR, Dave SR (2017) Enhancement in iron oxidation and multi-metal extraction from waste television printed circuit boards by iron-oxidizing Leptospirillum ferriphillum isolated from coal sample. Waste Biomass Valor.  https://doi.org/10.1007/s12649-017-0082-z Google Scholar
  35. 35.
    Zhu N, Xiang Y, Zhang T, Wu P, Dang Z, Li P, Wu J (2011) Bioleaching of metal concentrates of waste printed circuit boards by mixed culture of acidophilic bacteria. J Hazard Mater 192(2):614–619CrossRefGoogle Scholar
  36. 36.
    Pathak A, Morrison L, Healy MG (2017) Catalytic potential of selected metal ions for bioleaching, and potential techno-economic and environmental issues: A critical review. Bioresour Technol 229:211–221CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  1. 1.Department of Microbiology and Biotechnology, School of SciencesGujarat UniversityAhmedabadIndia
  2. 2.Loyola Centre for Research and Development, XRFAhmedabadIndia

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