Searching for Acidity or the Case of the Missing Chlorine: An Option for a Global Closed Loop Alkalinity–Acidity Cycle for Bauxite Residue Neutralization Based on HCl from PVC Recycling
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The Bayer process depends on the large-scale use of caustic soda (NaOH)—produced at > 60 million tons/year from NaCl by the chlor-alkali process—and is thus one of the major consumers of the alkalinity generated by the latter. A part of this alkalinity then ultimately ends up in the bauxite residue from the Bayer process, arguably constituting one of the main chemical, technical, and environmental challenges for a valorization or long-term safe disposal and remediation of this material. By stoichiometric and chemical necessity, the complementary acidity resides in the Cl2 gas is also produced in the chlor-alkali process and is thus latent in the chlorinated compounds—notably polyvinyl chloride (PVC) and chlorinated solvents, such as dichloromethane or 1,1,1,-trichloroethane. Recapturing and recycling Cl2 from these uses in the form of hydrochloric acid (HCl) by means of a controlled thermal decomposition of the chlorinated hydrocarbons could—in principle—serve as a source of Brønsted acidity for the neutralization of bauxite residue (Red Mud) thereby transforming it into a nonhazardous material of much lower environmental concern limited to its NaCl content. This could establish a closed alkalinity–acidity cycle on a global scale while simultaneously addressing the end-of-life fate of environmentally persistent PVC that otherwise either is deposited in landfills or can end up in the oceans in form of dispersed microplastics.
KeywordsBauxite residue Polyvinylchloride (PVC) Neutralization Recycling Synergistic co-processing
The author thanks Dr. Jenny Cox (at the Dept. of Chem., Univ. of Guelph) for helpful suggestions.
Compliance with Ethical Standards
Conflict of interest
The author declares no Conflict of Interest with any of the stake holders and industries mentioned in this article.
- 3.Dean JA (1992) Lange’s handbook of chemistry. McGraw-Hill, TorontoGoogle Scholar
- 15.Schmittinger P, Florkiewicz T, Curlin LC, Lüke B, Scannell R, Navin T, Zelfel E, Bartsch R (2000) in “Chlorine”; Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co, KGaAGoogle Scholar
- 16.Kurt C, Bittner J (2000) in “Sodium Hydroxide”; Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co, KGaAGoogle Scholar
- 18.Fischer I, Schmitt WF, Porth H-C, Allsopp MW, Vianello G (2000) in “Poly(Vinyl Chloride)”; Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co, KGaAGoogle Scholar
- 19.Dreher E-L, Beutel KK, Myers JD, Lübbe T, Krieger S, Pottenger LH (2000) in “Chloroethanes and Chloroethylenes”; Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co, KGaAGoogle Scholar
- 20.Rossberg M, Lendle W, Pfleiderer G, Tögel A, Torkelson TR, Beutel KK (2000) in “Chloromethanes”; Ullmann’s encyclopedia of industrial chemistry. Wiley-VCH Verlag GmbH & Co, KGaAGoogle Scholar
- 21.Data from http://www.essentialchemicalindustry.org/chemicals/chlorine.html. Accessed January 2018
- 22.Excluding, of course the still unknown and difficult to assess long-term ecological effects of this material when considered under a “true cost accounting” approachGoogle Scholar
- 25.Agency USEP (2014) Facts an figures about materials, waste and recycling—advancing sustainable materials management: facts and figures report. https://www.epa.gov/sites/production/files/2016-11/documents/2014_smmfactsheet_508.pdf; (https://cen.acs.org/environment/sustainability/Periodic-graphics-plastic-recycled/96/i17)
- 29.Environex (2017) PVC and fire. http://envorinex.com/
- 30.http://www.stabilisers.eu/lead-replacement/. Accessed June 2018