Advertisement

Electrochemical Studies on New Pyridazinium Derivatives as Corrosion Inhibitors of Carbon Steel in Acidic Medium

  • F. El Hajjaji
  • R. Salim
  • M. Messali
  • B. Hammouti
  • D. S. Chauhan
  • S. M. Almutairi
  • M. A. QuraishiEmail author
Article
  • 18 Downloads

Abstract

Two pyridazine derivatives “1-decylpyridazin-1-ium iodide” (DPI) and “1-tetradecylpyridazin-1-ium iodide” (TPI) were synthesized and investigated as corrosion inhibitors for carbon steel in HCl (1 M) solution. In order to evaluate the anticorrosion activity of these compounds, the electrochemical impedance spectroscopy was performed at different concentrations and at various temperatures (303–333 K). The collected results showed that DPI and TPI reached a value of 86.7% and 88.6% at 10−3 M, respectively (303 K). The decrease of the double-layer capacitance for TPI became more remarkable with increase in temperature. The adsorption of both inhibitors on mild steel surface obeyed the Langmuir adsorption isotherm. An inhibition efficiency of 97.6% was obtained at the optimum concentration (10−3 M) following an immersion period of 12 h. The quantum chemical calculations based on DFT method supported the experimentally obtained results.

Keywords

Pyridazinium Ionic liquids Impedance Langmuir isotherm Adsorption Immersion time 

References

  1. 1.
    Rani BESA, Basu BBJ (2012) Green inhibitors for corrosion protection of metals and alloys: an overview. Int J Corros 2012:15Google Scholar
  2. 2.
    Zarrok H, Oudda H, El Midaoui A, Zarrouk A, Hammouti B, Touhami ME, Attayibat A, Radi S, Touzani R (2012) Some new bipyrazole derivatives as corrosion inhibitors for C38 steel in acidic medium. Res Chem Intermed 38:2051CrossRefGoogle Scholar
  3. 3.
    Hmamou DB, Salghi R, Zarrouk A, Zarrok H, Hammouti B, Al-Deyab SS, ElAssyry A, Benchat N, Bouachrine M (2013) Electrochemical and gravimetric evaluation of 7-methyl-2-phenylimidazo[1,2-á]pyridine of carbon steel corrosion in phosphoric acid solution. Int J Electrochem Sci 8:11526Google Scholar
  4. 4.
    Shahabi S, Norouzi P, Ganjali MR (2015) Theoretical and electrochemical study of carbon steel corrosion inhibition in the presence of two synthesized schiff base inhibitors: application of fast fourier transform continuous cyclic voltammetry to study the adsorption behavior. Int J Electrochem Sci 10:2646Google Scholar
  5. 5.
    Banua VRN, Rajendran S, Kumaran SS (2016) Investigation of the inhibitive effect of Tween 20 self-assembling nanofilms on corrosion of carbon steel. J Alloy Compd 675:139CrossRefGoogle Scholar
  6. 6.
    Bouzidi D, Kertit S, Hammouti B, Brighli M (1997) Someaminoacids and aminoesters as non-toxic inhibitors for the corrosion of iron in 0.5 M H2SO4. J Electrochem Soc India 46:23Google Scholar
  7. 7.
    Ghazoui A, Zarrouk A, Benchat N, Salghi R, Assouag M, El Hezzat M, Guenbour A, Hammouti B (2014) New possibility of mild steel corrosion inhibition by organic heterocyclic compound. J Chem Pharm Res 6:704Google Scholar
  8. 8.
    Swathi NP, Alva VDP, Samshuddin S (2017) A Review on 1,2,4-triazole derivatives as corrosion inhibitors. J Bio Tribo Corros 3:42CrossRefGoogle Scholar
  9. 9.
    Zarrouk A, Hammouti B, Zarrok H, Bouachrine M, Khaled KF, Al-Deyab SS (2012) Corrosion inhibition of copper in nitric acid solutions using a new triazole derivative. Int J Electrochem Sci 7:89Google Scholar
  10. 10.
    Nahle A, El-Hajjaji F, Ghazoui A, Benchat NE, Taleb M, Saddik R, Elaatiaoui A, Koudad M, Hammouti B (2018) Effect of substituted methyl group by phenyl group in pyridazine ring on the corrosion inhibition of mild steel in 1.0 M HCl. Anti-Corros Methods Mater 65:87CrossRefGoogle Scholar
  11. 11.
    Bouoidina A, Chaouch M, Abdellaoui A, Lahkimi A, Hammouti B, El-Hajjaji F, Taleb M, NahleA (2017) Essential oil of “Foeniculumvulgare”: antioxidant and corrosion inhibitor on mild steel immersed in hydrochloric medium. Anti-Corros Methods Mater 64:563CrossRefGoogle Scholar
  12. 12.
    Mousavi M, Mohammadalizadeh M, Khosravan A (2011)Theoretical investigation of corrosion inhibition effect of imidazole and its derivatives on mild steel using cluster model. Corros Sci 53:3086CrossRefGoogle Scholar
  13. 13.
    Abdallah M, Megahed HE, Sobhi M (2010) Ni2+ cation and imidazole as corrosion inhibitors for carbon steel in sulfuric acid solutions. Monatsh Chem 141:1287CrossRefGoogle Scholar
  14. 14.
    Benabdellah M, Yahyi A, Dafali A, Aouniti A, Hammouti B, Ettouhami A (2011) Corrosion inhibition of steel in molar HCl by triphenyltin2–thiophene carboxylate. Arab J Chem 4:243CrossRefGoogle Scholar
  15. 15.
    ElBakri Y, Boudalia M, Echihi S, Harmaoui A, Sebhaoui J, Elmsellem H, Ali AB, Ramli Y, Guenbour A, Bellaouchou A, Essassi EM (2017) Performance and theoretical study on corrosion inhibition of new triazolopyrimidine derivative for carbon steel in hydrochloric acid. J Mater Environ Sci 8:378Google Scholar
  16. 16.
    Agi A, Junin R, Zakariah MI (2018) Effect of temperature and acid concentration on rhizophoramucronata tannin as a corrosion inhibitor. J Bio Tribo Corros 4:5CrossRefGoogle Scholar
  17. 17.
    Yadav M, Behera D, Kumar S (2014) Experimental and theoretical investigation on adsorption and corrosion inhibition properties of imidazopyridine derivatives on mild steel in hydrochloric acid solution. Surf Interface Anal 46:640CrossRefGoogle Scholar
  18. 18.
    Verma C, Ebenso EE, Quraishi MA (2017) Ionic liquids as green and sustainable corrosion inhibitors for metals and alloys: an overview. J Mol Liq 233:403CrossRefGoogle Scholar
  19. 19.
    Liu JF, Jiang GB, Chi YG, Cai YQ, Zhou QX, Hu JT (2003) Use of ionic liquids for liquid-phase microextraction of polycyclic aromatic hydrocarbons. Anal Chem 75:5870CrossRefGoogle Scholar
  20. 20.
    Ibrahim MA, Messali M (2011) Ionic liquid [BMPy]Br as an effective additives during Zinc electrodeposition from aqueous sulphate bath. Prod Finish 2:14Google Scholar
  21. 21.
    Ue M, Takeda M, Toriumi A, Kominato A, Hagiwara R, Ito Y (2003) Application of low-viscosity ionic liquid to the electrolyte of double-layer capacitors. J Electrochem Soc 150:499CrossRefGoogle Scholar
  22. 22.
    Brennecke JF, Maginn E (2001) Ionic liquids: innovative fluids for chemical processing. AIChE J 47:2384CrossRefGoogle Scholar
  23. 23.
    Messali M (2011) A green microwave-assisted synthesis, characterization and comparative study of new pyridazinium-based ionic liquids derivatives towards corrosion of mild steel in in acidic environment. J Mater Environ Sci 2:174Google Scholar
  24. 24.
    El-Hajjaji F, Messali M, Aljuhani A, Aouad MR, Hammouti B, Belghiti ME, Chauhan DS, Quraishi MA (2018) Pyridazinium-based ionic liquids as novel and green corrosion inhibitors of carbon steel in acid medium: electrochemical and molecular dynamics simulation studies. J Mol Liq 249:997CrossRefGoogle Scholar
  25. 25.
    Zarrouk A, Messali M, Zarrok H, Salghi R, Ali A, Hammouti B, Al-Deyab S, Bentiss F(2012) Synthesis, characterization and comparative study of new functionalized imidazolium-based ionic liquids derivatives towards corrosion of C38 steel in molar hydrochloric acid. Int J Electrochem Sci 7:6998Google Scholar
  26. 26.
    Lopez DA, Simison SN, de Sanchez SR(2003) The influence of steel microstructure on CO2 corrosion: EIS studies on the inhibition efficiency of benzimidazole. Electrochim Acta 48:845CrossRefGoogle Scholar
  27. 27.
    Pearson RG (1988) Absolute electronegativity and hardness: application to inorganic chemistry. Inorg Chem 27:734CrossRefGoogle Scholar
  28. 28.
    Zarrouk A, Messali M, Aouad M, Zarrok H, Salghi R, Hammouti B, Chetouani A, Al-Deyab S (2012) Some new ionic liquids derivatives: synthesis, characterization and comparative study towards corrosion of C-steel in acidic media. J Chem Pharm Res 4:3427Google Scholar
  29. 29.
    Al-Ghamdi AF, Messali M, Ahmed SA (2011) Electrochemical studies of new pyridazinium-based ionic liquid and its determination in different detergents. J Mater Environ Sci 2:215Google Scholar
  30. 30.
    Messali M (2014) An efficient and green sonochemical synthesis of some new eco-friendly functionalized ionic liquids. Arab J Chem 7:63CrossRefGoogle Scholar
  31. 31.
    Ghazoui A, Benchat N, El-Hajjaji F, Taleb M, Rais Z, Saddik R, Elaatiaoui A, Hammouti B (2017) The study of the effect of ethyl (6-methyl-3-oxopyridazin-2-yl) acetate on mild steel corrosion in 1 M HCl. J Alloys Compd 693:510CrossRefGoogle Scholar
  32. 32.
    Solmaz R (2014) Investigation of adsorption and corrosion inhibition of mild steel in hydrochloric acid solution by 5-(4-dimethylaminobenzylydene. Rhodanine Corros Sci 79:169CrossRefGoogle Scholar
  33. 33.
    Bousskri A, Anejjar A, Messali M, Salghi R, Benali O, Karzazi Y, Jodeh S, Zougagh M, Ebenso EE, Hammouti B (2015) Corrosion inhibition of carbon steel in aggressive acidic media with 1-(2-(4-chlorophenyl)-2-oxoethyl)pyridazinium bromide. J Mol Liq 211:1000CrossRefGoogle Scholar
  34. 34.
    El-Hajjaji F, Belghiti ME, Hammouti B, Jodeh S, Hamec O, Lgaz H, Salghi R(2018) Adsorption and corrosion inhibition effect of 2-mercaptobenzimidazole (surfactant) on a carbon steel surface in an acidic medium: experimental and monte carlo simulations. Portugaliae Electrochim Acta 36:197CrossRefGoogle Scholar
  35. 35.
    Bousskri A, Anejjar A, Salghi R, Jodeh S, Touzani R, Bazzi L, Lgaz H (2016) Corrosion control of carbon steel in hydrochloric acid by new eco-friendly picolinium-based ionic liquids derivative: electrochemical and synergistic studies. J Mater Environ Sci 7:4269Google Scholar
  36. 36.
    Si˘gircik G, T¨uken T, Erbil M (2016) Assessment of the inhibition efficiency of 3,4-diaminobenzonitrile against the corrosion of steel. Corros Sci 102:437CrossRefGoogle Scholar
  37. 37.
    Popova A, Christov M (2006) Evaluation of impedance measurements on mild steel corrosion in acid media in the presence of heterocyclic compounds. Corros Sci 48:3208CrossRefGoogle Scholar
  38. 38.
    Yadav DK, Chauhan DS, Ahamad I, Quraishi MA (2013) Electrochemical behavior of steel/acid interface: adsorption and inhibition effect of oligomeric aniline. RSC Adv 3:632CrossRefGoogle Scholar
  39. 39.
    Jafari H, Sayin K, Mohsenifar F (2017) Measuring adsorption behavior and corrosion inhibition of trans and cis of di-(3-hydroxybenzaldehyde)-1,2-diaminocyclohexane. J Bio Tribo Corros 3:48CrossRefGoogle Scholar
  40. 40.
    Finley HF, Hackerman N (1960) Effect of adsorption of polar organic compounds on the reactivity of steel. J Electrochem Soc 107:259CrossRefGoogle Scholar
  41. 41.
    Hayaoui M, Drissi M, Fahim M, Salim R, Rais Z, Mouffarih S, Baba MF, El Hajjaji F, Zarrouk A, Taleb M (2017) Benzenamine derivative as corrosion inhibitor of carbon steel in hydrochloric acid solution: Electrochemical and theoretical studies. J Mater Environ Sci 8:1877Google Scholar
  42. 42.
    ElOuasif L, Merimi I, Zarrok H, Elghoul M, Achour R, Guenbour M, Oudda H, El-Hajjaji F, Hammouti B (2016) Synthesis and inhibition study of carbon steel corrosion in hydrochloric acid of a new surfactant derived from 2-mercaptobenzimidazole. J Mater Environ Sci 7:2718Google Scholar
  43. 43.
    Ghazoui A, Benchat N, El-Hajjaji F, Taleb M, Rais Z, Saddik R, Elaatiaoui A, Hammouti B (2017) The study of the effect of ethyl (6-methyl-3-oxopyridazin-2-yl) acetate on mild steel corrosion in 1 M HCl. J Alloy Compd 693:510CrossRefGoogle Scholar
  44. 44.
    Verma CB, Quraishi MA, Ebenso EE (2014) Application of some oligopolymers as effective corrosion inhibitors for mild steel in 1 M HCl: gravimetric, thermodynamic and electrochemical analysis. Int J Electrochem Sci 9:5507Google Scholar
  45. 45.
    Gupta NK, Haque J, Salghi R (2018) Spiro [indoline-3,4′-pyrano[2,3-c]pyrazole] derivatives as novel class of green corrosion inhibitors for mild steel in hydrochloric acid medium: theoretical and experimental approach. J Bio Tribo Corros 4:16CrossRefGoogle Scholar
  46. 46.
    Verma C, Reddy MJ, Quraishi MA (2014) Microwave assisted eco-friendly synthesis of chalcones using 2, 4-dihydroxy ace-tophenone and aldehydes as corrosion inhibitors for mild steel in 1 M HCl. Anal Bioanal Electrochem 6:321Google Scholar
  47. 47.
    Ahamad I, Prasad R, Quraishi MA (2010) Adsorption and inhibitive properties of some new Mannich bases of Isatin derivatives on corrosion of mild steel in acidic media. Corros Sci 52:1472CrossRefGoogle Scholar
  48. 48.
    Abd El-Lateef HM (2015) Experimental and computational investigation on the corrosion inhibition characteristics of mild steel by some novel synthesized imines in hydrochloric acid solutions. Corros Sci 92:104CrossRefGoogle Scholar
  49. 49.
    Hamani H, Douadi T, Daoud D, Al-Noaimi M, Rikkouh RA, Chafaa S (2017) 1-(4-Nitrophenylo-imino)-1-(phenylhydrazono)-propan-2-one as corrosion inhibitor for mild steel in 1 M HCl solution: weight loss, electrochemical, thermodynamic and quantum chemical studies. J Electroanal Chem 801:425CrossRefGoogle Scholar
  50. 50.
    Salim R, Elaatiaoui A, Benchat N, Ech-Chihbi E, Rais Z, Oudda H, El Hajjaji F, ElAoufir Y, Taleb M (2017) Corrosion behavior of a smart inhibitor in hydrochloric acid molar: experimental and theoretical studies. J Mater Environ Sci 8:3747Google Scholar
  51. 51.
    Verma C, Quraishi MA, Ebenso EE (2018) A green and sustainable approach for mild steel acidic corrosion inhibition using leaves extract: experimental and DFT studies. J Bio Tribo Corros 4:33CrossRefGoogle Scholar
  52. 52.
    Elhousni L, Galai M, El Kamraoui FZ, Dkhireche N, Touhami ME, Touir R, Chebabe D, Sfaira M, Zarrouk A (2016) Study of sodium gluconate and cetyltrimethyl ammonium bromide as inhibitor for copper in Moroccan industrial cooling water systems. J Mater Environ Sci 7:2513Google Scholar
  53. 53.
    Ech-Chihbi E, Belghiti ME, Salim R, Oudda H, Taleb M, Benchat N, Hammouti B, El-Hajjaji F (2017) Experimental and computational studies on the inhibition performance of the organic compound “2-phenylimidazo [1,2-a]pyrimidine-3-carbaldehyde” against the corrosion of carbon steel in 1.0 M HCl solution. Surf Interfaces 9:206CrossRefGoogle Scholar
  54. 54.
    Motsie EM, Lukman OO, Abolanle SA, Sasikumar Y, Mwadham MK, Eno EE (2015) Adsorption, thermodynamic and quantum chemical studies of 1-hexyl-3-methylimidazolium based ionic liquids as corrosion inhibitors for mild steel in HCl. Materials 8:3607CrossRefGoogle Scholar
  55. 55.
    Sasikumar Y, Adekunle AS, Olasunkanmi LO, Bahadur I, Baskar R, Kabanda MM, Obot IB, Ebenso EE (2015) Experimental, quantum chemical and Monte Carlo simulation studies on the corrosion inhibition of some alkyl imidazolium ionic liquids containing tetrafluoroborate anion on mild steel in acidic medium. J Mol Liq 211:105CrossRefGoogle Scholar
  56. 56.
    Chauhan DS, Ansari KR, Sorour AA, Quraishi MA, Lgaz H, Salghi R (2018) Thiosemicarbazide and thiocarbohydrazide functionalized chitosan as ecofriendly corrosion inhibitors for carbon steel in hydrochloric acid solution. Int J Biol Macromol 107:1747CrossRefGoogle Scholar
  57. 57.
    Srivastava V, Chauhan DS, Joshi PG (2018) PEG-functionalized chitosan: a biological macromolecule as a novel corrosion inhibitor. Chem Select 3:1990Google Scholar
  58. 58.
    Zheng X, Zhang S, Li W, Gong M, Yin L (2015) Experimental and theoretical studies of two imidazolium-based ionic liquids as inhibitors for mild steel in sulfuric acid solution. Corros Sci 95:168CrossRefGoogle Scholar
  59. 59.
    Haque J, Srivastava V, Chauhan DS, Lgaz H, Quraishi MA (2018) Microwave-induced synthesis of chitosan Schiff bases and their application as novel and green corrosion inhibitors: experimental and theoretical approach. ACS Omega 3:5654CrossRefGoogle Scholar
  60. 60.
    Dohare P, Chauhan DS, Sorour AA, Quraishi MA (2017) DFT and experimental studies on the inhibition potentials of expired Tramadol drug on mild steel corrosion in hydrochloric acid. Mater Discov 9:30CrossRefGoogle Scholar

Copyright information

© Springer Nature Switzerland AG 2018

Authors and Affiliations

  • F. El Hajjaji
    • 1
  • R. Salim
    • 1
    • 2
  • M. Messali
    • 3
  • B. Hammouti
    • 4
  • D. S. Chauhan
    • 5
  • S. M. Almutairi
    • 6
  • M. A. Quraishi
    • 5
    Email author
  1. 1.Laboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of SciencesUniversity sidi Mohamed Ben AbdellahFezMorocco
  2. 2.Laboratory of Separation Processes, Faculty of ScienceUniversity Ibn TofailKenitraMorocco
  3. 3.Chemistry Department, Faculty of SciencesTaibah UniversityAl-Madinah Al-MounawaraSaudi Arabia
  4. 4.LCAE-URAC 18, Faculty of ScienceFirst Mohammed UniversityOujdaMorocco
  5. 5.Center of Research Excellence in Corrosion, Research InstituteKing Fahd University of Petroleum and MineralsDhahranSaudi Arabia
  6. 6.King Abdulaziz City for Science and TechnologyRiyadhSaudi Arabia

Personalised recommendations