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Microscale study of frictional properties of graphene in ultra high vacuum

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Abstract

We report on the frictional properties of epitaxial graphene on SiC in ultra high vacuum. Measurements have been performed using a microtribometer in the load regime of 0.5 to 1 mN. We observed that a ruby sphere sliding against graphene results in very low friction coefficients ranging from 0.02 to 0.05. The friction and also the stability of the graphene layer is higher than that under similar conditions in ambient conditions. The friction shows a load dependence. Finally it was found that graphene masks the frictional anisotropy which was observed on the SiC surface.

References

  1. [1]

    Donnet C, Erdemir A. Solid lubricant coatings: Recent developments and future trends. Tribol Lett 17(3): 389–397 (2004)

  2. [2]

    Ludema K C. In Friction, Wear, Lubrication: A Textbook in Tribology. Florida (US): CRC Press, Inc, 1993: 69–155.

  3. [3]

    Lancaster J K. A review of the influence of environmental humidity and water on friction, lubrication and wear. Tribol Int 23(6): 371–389 (1990)

  4. [4]

    Savage R H. Graphite lubrication. J Appl Phys 19: 1–10 (1948)

  5. [5]

    Fusaro R L. Lubrication of space systems. Lubr Eng 3: 182–194 (1995)

  6. [6]

    Singer I L. Solid lubrication processes. Fundamentals of friction: Macroscopic and microscopic processes. NATO ASI Series 220: 237–261 (1992)

  7. [7]

    Stoyanov P, Strauss H W, Chromik R R. Scaling effects between micro- and macro-tribology for a Ti-MoS2 coating. Wear 274275: 149–161 (2012)

  8. [8]

    Geim A K, Novoselov K S. The rise of graphene. Nat Mater 6: 183–191 (2007)

  9. [9]

    Yu M-F, Lourie O, Dyer M J, Moloni K, Kell T F, Ruoff R S. Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load. Science 287(5453): 637–640 (2000)

  10. [10]

    Lee C G, Wei X D, Kysar J W, Hone J. Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887): 385–388 (2008)

  11. [11]

    Gao Y W, Hao P. Mechanical properties of monolayer graphene under tensile and compressive loading. Physica E 41(8): 1561–1566 (2009)

  12. [12]

    Lee C, Wei X, Li Q, Carpick R, Kysar J W, Hone J. Elastic and frictional properties of graphene. Physica Status Solidi B 246(11–12): 2562–2567 (2009)

  13. [13]

    Schwarz U D, Zworner O, Koster P, Wiesendanger R. Quantitative analysis of the frictional properties of solid materials at low loads. Phys Rev B 56: 6987–6996 (1997)

  14. [14]

    Filleter T, Bennewitz R. Structural and frictional properties of graphene films on SiC (0001) studied by atomic force microscopy. Phys Rev B 81: 155412 (2010)

  15. [15]

    Kim K, Lee H J, Lee C, Lee S K, Jang H, Ahn J H, Kim J H, Lee H J. Chemical vapor deposition-grown graphene: The thinnest solid lubricant. ACS Nano 5: 5107–5114 (2011)

  16. [16]

    Lee C, Li Q, Kalb W, Liu X, Berger H, Carpick R W, Hone J. Frictional characteristics of atomically thin sheets. Science 328: 76–80 (2010)

  17. [17]

    Berman D, Erdemir A, Sumant A V. Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54: 454–459 (2013)

  18. [18]

    Berman D, Erdemir A, Sumant A V. Reduced wear and friction enabled by graphene layers on sliding steel surfaces in dry nitrogen. Carbon 59: 167–175 (2013)

  19. [19]

    Filleter T, McChesney J L, Bostwick A, Rotenberg E, Emtsev K V, Seyller T H, Horn K, Bennewitz R. Friction and dissipation in epitaxial graphene films. Phys Rev Lett 102: 086102 (2009)

  20. [20]

    Washizu H, Kajita S, Tohyama M, Ohmori T, Nishino N, Teranishi H, Suzuki A. Mechanism of ultra low friction of multilayer graphene studied by coarse-grained molecular simulation. Faraday Discuss 156: 279–291 (2012)

  21. [21]

    Marchetto D, Held C, Hausen F, Wählisch F, Dienwiebel M, Bennewitz R. Friction and wear on single-layer epitaxial graphene in multi-asperity contacts. Tribol Lett 48: 77–82 (2012)

  22. [22]

    Marchetto D, Benzig R, Korres S, Dienwiebel M. Design and testing of an ultra high vacuum microtribometer. Tribology-Materials, Surfaces & Interfaces 6: 95–101 (2012)

  23. [23]

    Emtsev K V, Bostwick A, Horn K, Jobst J, Kellogg G, Ley L, McChesney J L, Ohta T, Reshanov S A, Röhrl J, Rotenberg E, Schmid A K, Waldmann D, Weber H B, Seyller T. Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide. Nat Mater 8: 203–207 (2009)

  24. [24]

    Lauffer P, Emtsev K V, Graupner R, Seyller T, Ley L, Reshanov S A, Weber H B. Atomic and electronic structure of few-layer graphene on SiC (0001) studied with scanning tunneling microscopy and spectroscopy. Phys Rev B 77: 155426 (2008)

  25. [25]

    Wählisch F, Hoth J, Held C, Seyller T, Bennewitz R. Friction and atomic-layer-scale wear of graphitic lubricants on SiC (0001) in dry sliding. Wear 300(1–2): 78–81 (2013)

  26. [26]

    Moras G, Pastewka L, Walter M, Schnagl J, Gumbsch P, Moseler M. Progressive shortening of sp-hybridized carbon chains through oxygen-induced cleavage. J Phys Chem C 115(50): 24653–24661 (2011)

  27. [27]

    Klemenz A, Pastewka L, Balakrishna S G, Caron A, Bennewitz R, Moseler M. Atomic scale mechanisms of friction reduction and wear protection by graphene. Nano Lett 14(12): 7145–7152 (2014)

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Author information

Correspondence to Martin Dienwiebel.

Additional information

This article is published with open access at Springerlink.com

Diego MARCHETTO. He is a researcher and obtained his master degree and PhD degree in physics in 2003 and 2010 from University of Modena and Reggio Emilia (Italy). He worked with Dr. Martin Dienwiebel as a post doctoral fellow at Fraunhofer Institute in Germany from 2009–2014. Presently he works as researcher at the University of Modena and Reggio Emilia (Italy). Currently his research areas include tribology of graphene, microscale friction and lubrication at low temperature. He has participated in many research projects and has published more than 10 papers on international journals.

Tim FESER. He obtained his master degree and PhD degree in mechanical engineering at the Karlsruhe Institute of Technology in 2009 and 2013. He is presently working at BASF SE, Ludwigshafen, Germany.

Martin DIENWIEBEL. He is an assistant professor and obtained his master degree in physics in 1997 from Bonn University, Germany, and received his PhD degree in 2003 from Leiden University, The Netherlands. During this period he was working as visiting scientist at the Tokyo Institute of Technology, Japan. From 2003–2007 he worked at the Tribology and Research department of IAVF Antriebstechnik AG, Germany. In 2008 he received an Emmy-Noether fellowship of the Deutsche Forschungsgemeinschaft. Presently he is working as group leader at Fraunhofer Institute of Technology and Karlsruhe Institute of Technology. His research interests are in the area of superlow friction, running-in, superlubricity, analytical and nano-scale processes of tribological interfaces.

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Marchetto, D., Feser, T. & Dienwiebel, M. Microscale study of frictional properties of graphene in ultra high vacuum. Friction 3, 161–169 (2015). https://doi.org/10.1007/s40544-015-0080-8

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Keywords

  • graphene
  • SiC
  • friction
  • vacuum
  • microtribology
  • anisotropy