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Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D {B5}/{B6} Helical Chains

Abstract

Two new alkaline metal borates containing 1D {B5}/{B6} oxoboron helical chains, namely Na0.5[B5O8(OH)2]0.5[B5O6(OH)2]0.5·0.5H3O(1) and NaKCs[B6O9(OH)3](2) were synthesized under solvothermal conditions. Compound 1 contains the interesting alternative left- and right-handed helical {[B5O8(OH)2][B5O6(OH)2]}2− ({B5}-1 and {B5}-2) 1D chains and compound 2 possesses the similar [B6O11(OH)3]7−({B6}) chains. Their 1D chains are further assembled into 2D layers and 3D supramolecular frameworks through O-H⋯O hydrogen bonds. In addition, the UV cutoff edge of compounds 1 and 2 is both below 190 nm.

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Author information

Correspondence to Guoyu Yang.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21571016, 21831001 and 91122028) and the National Natural Science Foundation of China for Distinguished Young Scholars(No.20725101).

Supporting Information

Electronic supplementary information(ESI) available: spectroscopic data, and crystallographic data. CCDC reference numbers of 1969702 and 1962949. For ESI and crystallographic data in CIF.

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Qiu, Q., Sun, K. & Yang, G. Two New Alkaline Metal Borates with Supramolecular Framework Constructed from 1D {B5}/{B6} Helical Chains. Chem. Res. Chin. Univ. (2020) doi:10.1007/s40242-020-9097-2

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Keywords

  • Alkaline metal borate
  • Solvothermal synthesis
  • Helical chain
  • Supramolecular framework