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Chemical Research in Chinese Universities

, Volume 36, Issue 1, pp 120–126 | Cite as

Nanostructured BiVO4 Derived from Bi-MOF for Enhanced Visible-light Photodegradation

  • Jianfei Chen
  • Xiaoyu Chen
  • Xing Zhang
  • Yao Yuan
  • Ruyi Bi
  • Feifei You
  • Zumin WangEmail author
  • Ranbo YuEmail author
Article
  • 6 Downloads

Abstract

BiVO4, a promising visible-light responding photocatalyst, has aroused extensive research interest because of inexpensiveness and excellent chemical stability. However, its main drawback is the poor photoinduced charge-transfer dynamics. Building nanostructures is an effective way to tackle this problem. Herein, we put forward a new method to prepare nanostructured BiVO4 from Bi-based metal-organic frameworks[Bi-MOF(CAU-17)] precursor. The as-prepared material has a rod-like morphology inherited from the Bi-MOF sacrificial template and consists of small nanoparticle as building blocks. Compared with its counterparts prepared by conventional methods, MOF-derived nanostructured BiVO4 shows better light absorption ability, narrower bandgap, and improved electrical conductivity as well as reduced recombination. Consequently, BiVO4 nanostructure demonstrates high photocatalytic activity under visible light towards the degradation of methylene blue. Methylene blue can be degraded up to 90% within 30 min with a reaction rate constant of 0.058 min−1. Moreover, the cycling stability of the catalyst is excellent to withstand unchanged degradation efficiency for at least 5 cycles.

Keywords

BiVO4 Nanostructure Metal-organic framework Ternary metal oxide Photocatalysis 

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Supplementary material

40242_2020_9080_MOESM1_ESM.pdf (3.3 mb)
Nanostructured BiVO4 derived from Bi-MOF for enhanced visible-light photodegradation

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2020

Authors and Affiliations

  1. 1.Department of Physical Chemistry, School of Metallurgical and Ecological EngineeringUniversity of Science and Technology BeijingBeijingP. R. China
  2. 2.State Key Laboratory of Biochemical Engineering, Institute of Process EngineeringChinese Academy of SciencesBeijingP. R. China
  3. 3.Key Laboratory of Advanced Material Processing & MoldMinistry of Education Zhengzhou UniversityZhengzhouP. R. China

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