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Chemical Research in Chinese Universities

, Volume 35, Issue 4, pp 729–734 | Cite as

Synthesis and Properties of Poly(butylene carbonate-co-spirocyclic carbonate)

  • Changliang Zhu
  • Shaoying Liu
  • Qingyin Wang
  • Hua Zhang
  • Gongying WangEmail author
Article
  • 16 Downloads

Abstract

Poly(butylene carbonate)(PBC) has significantly promising applications as a degradable material in the field of polymers, while its poor thermal performance and low crystallization rate are its main defects. To overcome these shortcomings, a series of poly(butylene carbonate-co-spirocyclic carbonate)(PBSC) copolymers were synthesized from diphenyl carbonate, 1,4-butanediol and spiroglycol via two-step polycondensation reactions, using magnesium oxide as a catalyst. Differential scanning calorimetry(DSC) results indicated that the glass transition temperature(Tg) values of PBSC copolymers were enhanced from −19 °C to 56 °C with rising the spiroacetal moiety content. Thermogravimetric analysis(TGA) results showed that the resulting PBSCs have a higher thermal stability than that of poly(butylene carbonate). Wide angle X-ray diffraction(WXRD) patterns were characterized to investigate the crystallization behaviour of PBSCs. Tensile testing demonstrated that copolymerization of spiroacetal moieties into PBC chains imparted PBSC with favourable mechanical performance. Typically, PBSC30 had a tensile modulus of (1735±430) MPa, a tensile strength of (42±5) MPa and an elongation of 504%±36%.

Keywords

Poly(butylene carbonate) Spiroglycol Diphenyl carbonate Thermal property 

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Supplementary material

40242_2019_8355_MOESM1_ESM.pdf (289 kb)
Synthesis and properties of poly(butylene carbonate-co-spirocyclic carbonate)

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2019

Authors and Affiliations

  • Changliang Zhu
    • 1
    • 2
  • Shaoying Liu
    • 1
  • Qingyin Wang
    • 1
  • Hua Zhang
    • 1
  • Gongying Wang
    • 1
    Email author
  1. 1.Chengdu Institute of Organic ChemistryChinese Academy of SciencesChengduP. R. China
  2. 2.National Engineering Laboratory for VOCs Pollution Control Material & TechnologyUniversity of Chinese Academy of SciencesBeijingP. R. China

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