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Chemical Research in Chinese Universities

, Volume 35, Issue 2, pp 285–291 | Cite as

Production of Bio-hydrogen Using Bio-oil as a Potential Biomass-derived Renewable Feedstock

  • Junxu Liu
  • Lijuan Zhu
  • Shengfei Wang
  • Yulan Wang
  • Yuting He
  • Quanxin LiEmail author
Article
  • 4 Downloads

Abstract

The bio-oil derived from pyrolysis of straw can be selectively converted into high-purity hydrogen by coupling three steps: (i) steam reforming(SR) of different bio-oils, (ii) water-gas shift(WGS), and (iii) the removal of CO2. The catalytic SR reaction over the NiLaTiAl catalyst, coupled with a low-temperature WGS reaction with the CuZnAl catalyst, promoted the conversion of various oxygen-containing organic compounds in the bio-oil into hydrogen and carbon dioxide. Under the optimized condition, light bio-oil achieved the highest conversion(99.8%, molar fraction), with a high hydrogen yield of 16.4%(mass fraction) and a H2 purity of 99.94%(volume fraction). The carbon deposition on the NiLaTiAl catalyst was the main factor caused catalyst deactivation. Production of hydrogen from different bio-oil model compounds was also investigated in detail.

Keywords

Bio-oil High-purity hydrogen Integrated catalytic process Oxygenated organic compound 

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Supplementary material

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2019

Authors and Affiliations

  • Junxu Liu
    • 1
  • Lijuan Zhu
    • 1
  • Shengfei Wang
    • 1
  • Yulan Wang
    • 1
  • Yuting He
    • 1
  • Quanxin Li
    • 1
    Email author
  1. 1.Key Laboratory of Urban Pollutant Conversion of Chinese Academy of Sciences, Anhui Key Laboratory of Biomass Clean Energy, Department of Chemical PhysicsUniversity of Science & Technology of ChinaHefeiP. R. China

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