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Chemical Research in Chinese Universities

, Volume 34, Issue 5, pp 700–704 | Cite as

Crystal Structure and Photoluminescence Properties of Two Barium(II) MOFs

  • Kai Li
  • Kunhuan He
  • Quanwen Li
  • Bin Xia
  • Qinglun Wang
  • Yinghui Zhang
Article
  • 26 Downloads

Abstract

In this article, two Ba(II) metal-organic frameworks(MOFs), {[Ba(BPS)(H2O)2]·H2O}n(1) and [Ba(BPS)(H2O)2]n(2)(H2BPS=4,4′-bibenzoic acid-2,2′-sulfone), were synthesized and characterized. X-Ray crystal structural analyses reveal that compounds 1 and 2 have different structures, which is probably related to different coordination modes of ligand in compounds 1 and 2. It is remarkable that compounds 1 and 2 both show excellent thermal stability. The solid-state emission spectra reveal that compounds 1 and 2 both present strong luminescence emission bands at room temperature.

Keywords

Metal-organic framework Coordination mode Thermal stability Solid-state emission spectrum Barium(II) 

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Kai Li
    • 1
  • Kunhuan He
    • 2
  • Quanwen Li
    • 2
  • Bin Xia
    • 2
  • Qinglun Wang
    • 2
  • Yinghui Zhang
    • 1
  1. 1.Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, School of Materials Science and EngineeringNankai UniversityTianjinP. R. China
  2. 2.Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), College of ChemistryNankai UniversityTianjinP. R. China

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