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Chemical Research in Chinese Universities

, Volume 34, Issue 5, pp 839–843 | Cite as

Four Coordination Polymers Assembled with a New Biscarboxyl-functionalized Schiff Base Ligand

  • Dawei Kang
  • Jingjing Xie
  • Yingying Liu
  • Jianfang Ma
Article
  • 24 Downloads

Abstract

Based on a new biscarboxyl-functionalized Schiff base ligand 1,2-cyclohexanediamino-N,N′-bis[3-methoxyl-5-(p-carboxyl-phenylazo)] salicylidene(H4L), four polymers, [(CH3)2NH2]2·[Mn3(L)2(H2O)4]·2DMF(CP1), [Fe2(L)(H2O)(DMF)](CP2), [(CH3)2NH2]·[Cu(HL)]·H2O(CP3) and [Ni2(L)(teta)]·2DMF·H2O(CP4), have been synthesized(teta=5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane). In CP1, both of the internal [N2O2] pocket and the external carboxylate groups of L4– anion are ligated by Mn2+ ions, and the structure displays a layer. In CP2, the Fe2+ cations are linked by L4– anions to form a binuclear double chain. CP3 displays a [Cu2(HL)2] dimer. In CP4, the Ni2+ ions are connected by L4– anions to form a chain. The structures are further linked by hydrogen bonds to form 2D or 3D supramolecular architectures, respectively. CP1 exhibits adsorption ability to three organic dyes.

Keywords

Coordination polymer Schiff base Carboxylic acid Dye adsorption 

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Supplementary material

40242_2018_8030_MOESM1_ESM.pdf (402 kb)
Four coordination polymers assembled with a new biscarboxyl-functionalized Schiff base ligand

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Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Key Laboratory of Polyoxometalate Science, Department of ChemistryNortheast Normal UniversityChangchunP. R. China
  2. 2.Inner Mongolia Key Lab of Chemistry of Natural Products and Synthesis of Functional Molecules, College of Chemistry and Chemical EngineeringInner Mongolia University for the NationalitiesTongliaoP. R. China

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