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Chemical Research in Chinese Universities

, Volume 34, Issue 5, pp 723–726 | Cite as

(3,3)-Connected Three-dimentional Supramolecular Metal Organic Polyhedral Based on Nanometresized Ligand with Magnetism Properties

  • Xiaojing Zhou
  • Lili Liu
  • Xishi Tai
  • Hui Zhang
Article
  • 13 Downloads

Abstract

A three-dimentinal metal organic framework [Co2(L)Cl(DMF)2(H2O)](DMF)3(H2O)3 based on the nano-metresized ligand 4,4′,4″-[1,3,5-benzenetriyltris(carbonylimino)]trisbenzoic acid was synthesized, and characterized by means of single-crystal X-ray diffraction, elemental analysis, infrared spectroscopy, thermogravimetry analysis and magnetism. This obtained structure can be considered to be constructed from 2D layer, which displays the topology of hbc based on Co2(COO)3 secondary building unit, and further to be linked into a 3D supramolecular architecture by N—H···O hydrogen bonds. The magnetism of the complex was carried out, which shows ferromagnetic exchange interactions.

Keywords

Co complex C3-Symmetric ligand Ferromagnetic 

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References

  1. [1]
    Yu J. M., Xie L. H., Li J. R., Ma Y. G., Seminario J. M., Balbuena P. B., Chem. Rev., 2017, 117(14), 9674CrossRefPubMedGoogle Scholar
  2. [2]
    Li J. R., Sculley J. L., Zhou H. C., Chem. Rev., 2012, 112(2), 869CrossRefPubMedGoogle Scholar
  3. [3]
    Li B. Y., Zhang Y. M., Ma D. X., Li L., Li G. H., Li G. D., Shi Z., Feng S. H., Chem. Commum, 2012, 49(48), 6151CrossRefGoogle Scholar
  4. [4]
    Ma D. X., Li B. Y., Zhou X. J., Zhou Q., Liu, K., Zeng G., Li G. H., Shi Z., Feng S. H., Chem. Commum, 2013, 79(49), 8964CrossRefGoogle Scholar
  5. [5]
    Lu W. G., Wei Z. W., Gu Z. Y., Liu T. F., Park J., Tian J., Zhang M. W., Zhang Q., Gentle T., Bosch M., Zhou H. C., Chem. Soc. Rev., 2014, 43, 5561CrossRefPubMedGoogle Scholar
  6. [6]
    Han Y., Li J. R., Xie Y. B, Guo G. H, Chem. Soc. Rev., 2014, 43, 5952CrossRefPubMedGoogle Scholar
  7. [7]
    Zheng B. H., Bai. J. F., Duan J. G., J. Am. Chem. Soc., 2011, 4(133), 748CrossRefGoogle Scholar
  8. [8]
    Hasegawa S., Horike S., Matsuda R., Furukawa S., Mochizuki K., Kinoshita Y., Kitagawa S., J. Am. Chem. Soc., 2007, 129, 2607CrossRefPubMedGoogle Scholar
  9. [9]
    Hu D. X., Kluger R., Org. Biomol. Chem., 2008, 6, 151CrossRefPubMedGoogle Scholar
  10. [10]
    Wang J. C., Ding F. W., Ma J. P., Liu Q. K., Cheng G. Y., Dong Y. B., Inorg. Chem., 2015, 54, 10865CrossRefPubMedGoogle Scholar
  11. [11]
    Zhou J. H., Li J. J., Li J., Ren G. Y., Ren Y. H., Ma H. X., Chem. Res. Chinese Universities, 2017, 33(6), 864CrossRefGoogle Scholar
  12. [12]
    Jeong S., Kim D., Park. J., Chem. Mater., 2017, 9(29), 3899CrossRefGoogle Scholar
  13. [13]
    Akintola O., Hornig D., Buchholz A., Dalt. Trans., 2017, 25(46), 8037CrossRefGoogle Scholar

Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.College of Chemical & Chemical Engineering and Enviromental EngineeringWeifang UniversityWeifangP. R. China

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