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Journal of Advanced Ceramics

, Volume 8, Issue 1, pp 112–120 | Cite as

ZrC–ZrB2–SiC ceramic nanocomposites derived from a novel single-source precursor with high ceramic yield

  • Zhaoju YuEmail author
  • Xuan Lv
  • Shuyi Lai
  • Le Yang
  • Wenjing Lei
  • Xingang LuanEmail author
  • Ralf Riedel
Open Access
Research Article
  • 26 Downloads

Abstract

For the first time, ZrC–ZrB2–SiC ceramic nanocomposites were successfully prepared by a single-source-precursor route, with allylhydridopolycarbosilane (AHPCS), triethylamine borane (TEAB), and bis(cyclopentadienyl) zirconium dichloride (Cp2ZrCl2) as starting materials. The polymer-to-ceramic transformation and thermal behavior of obtained single-source precursor were characterized by means of Fourier transform infrared spectroscopy (FT-IR) and thermal gravimetric analysis (TGA). The results show that the precursor possesses a high ceramic yield about 85% at 1000 °C. The phase composition and microstructure of formed ZrC–ZrB2–SiC ceramics were investigated by means of X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). Meanwhile, the weight loss and chemical composition of the resultant ZrC–ZrB2–SiC nanocomposites were investigated after annealing at high temperature up to 1800 °C. High temperature behavior with respect to decomposition as well as crystallization shows a promising high temperature stability of the formed ZrC–ZrB2–SiC nanocomposites.

Keywords

polymer derived ceramics single-source precursor ceramic nanocomposite 

Notes

Acknowledgements

Zhaoju Yu thanks National Natural Science Foundation of China (No. 51872246), Alexander von Humboldt Foundation, and Creative Research Foundation of Science and Technology on Thermo Structural Composite Materials Laboratory (No. 6142911040114) for financial support. Xingang Luan thanks the National Key R&D Program of China (No. 2017YFB0703200) for financial support.

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© The Author(s) 2019

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Authors and Affiliations

  1. 1.College of MaterialsKey Laboratory of High Performance Ceramic Fibers (Xiamen University), Ministry of EducationXiamenChina
  2. 2.College of MaterialsFujian Key Laboratory of Advanced Materials (Xiamen University)XiamenChina
  3. 3.College of Materials Science and EngineeringHuaqiao UniversityXiamenChina
  4. 4.Science and Technology on Thermostructural Composite Materials LaboratoryNorthwestern Polytechnical UniversityXi’anChina
  5. 5.Technische Universität DarmstadtInstitut für MaterialwißsenschaftDarmstadtGermany

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