Advertisement

Frontiers of Chemistry in China

, Volume 1, Issue 2, pp 193–198 | Cite as

Analysis of the volatile oil from the stem of Acanthopanax Senticosus (Rupr. et Maxim.) harms with several hyphenated methods of chromatography

  • Yu Wanying Email author
  • Zhang Hua 
  • Huang Weidong 
  • Chen Jiping Email author
  • Liang Xinmiao 
Research Article

Abstract

Gas chromatography/quadrupole mass spectrometry (GC/qMS), gas chromatography/Fourier transform infrared spectrometry (GC/FTIR) and gas chromatography/orthogonal acceleration time-of-flight mass spectrometry (GC/oaTOFMS) were applied to analyze the volatile oil from the stem of Acanthopanax Senticosus (Rupr. et Maxim.) Harms. Based on the mass spectra search function of GC/qMS with the aid of the discriminability of the geometrical isomer by GC/FTIR and the ability to determine the accurate mass charge ratio (m/z) by GC/oaTOFMS, 68 GC eluants were identified successfully. Compared with the results obtained by GC/qMS only, the analytical results obtained by these hyphenated methods of gas chromatography are more credible.

Keywords

gas chromatography/quadrupole mass spectrometry gas chromatography/fourier transform infrared spectrometry gas chromatography/orthogonal acceleration time-of-flight mass spectrometry Acanthopanax senticosus (Rupr. et Maxim.) harms volatile oil 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Wu Jinguang, Technology of Modern FTIR and Its Application, Beijing, Scientific and Technical Publishing House, 1994, 187–189Google Scholar
  2. 2.
    Wu Qiao, Qiu Ningying, Ge Zhaoheng, Acta Pharmaceutica Sinica, 1990, 25(1): 44–48Google Scholar
  3. 3.
    Zhong Shan, Feng Zigang, Chinese Journal of Analytical Chemistry, 1995, 23(2): 132–136Google Scholar
  4. 4.
    Liu Mixin, Wang Wei, Spectroscopy and Spectral Analysis, 1996, 16(5): 35–37Google Scholar
  5. 5.
    Fay L. B., Newton A., Simian H., Robert F., Douce D., Hancock P., Green M., Blank I., J. Agric. Food Chem., 2003, 51(9): 2708–2713CrossRefGoogle Scholar
  6. 6.
    Gu Mingsong, Zhang Li, Hu Xuying, Feng Jianlin, Liu Yintang, Xie Jianwei, Journal of Chineses Mass Spectrometry Society, 2004, 25(1): 48–51Google Scholar
  7. 7.
    Yu Wanying, Zhang Hua, Huang Weidong, Chen Jiping, Liang Xinmiao. Talanta, 2005, 65: 172–178Google Scholar
  8. 8.
    Pharmacopoeia of the People’s Republic of China Part 1(Appendix XD). Beijing: Chemical Industry Press, 2000Google Scholar
  9. 9.
    Sadtler Standard Infrared Vapor Phase Spectra, No: 3 539; No: 2 906; No: 134Google Scholar

Copyright information

© Higher Education Press and Springer-Verlag 2006

Authors and Affiliations

  1. 1.Advanced Analytical Center, Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianChina
  2. 2.Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalianChina

Personalised recommendations